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11.
公开(公告)号:DE3663047D1
公开(公告)日:1989-06-01
申请号:DE3663047
申请日:1986-07-07
Applicant: BASF AG
Inventor: FIKENTSCHER ROLF DR , HEIMANN SIGISMUND DR , MERTENS HEINRICH DR , SCHNEIDER SIEGFRIED , VESCIA MICHELE DR
Abstract: Dyeings with reactive dyes on cellulose fiber materials are after-treated with an aqueous solution of a condensate which is obtainable by reacting (a) bisbenzylpiperzine with (b) ethylene chloride, an epihalohydrin, propylene chloride, 1,3-dichloro-2-hydroxypropane, bisepoxybutane or 1,4-dichlorobutane or a mixture of these, in a molar ratio of from 1:0.5 to 1:1.1, or by reacting (c) piperazine, bis-1,4-aminopropylpiperazine, 1-aminoethylpiperazine, 2-hydroxyethylpiperazine or 1-methylpiperazine, or a mixture of these, with a compound according to (b) in a molar ratio of from 1:0.5 to 1:1.1 and benzylating the condensate, the benzylation being carried out using 0.15-1.0 mole of benzyl chloride per equivalent of nitrogen in component (c). The cellulose fiber materials after-treated in this manner possess very good wetfastness.
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公开(公告)号:DE3324917A1
公开(公告)日:1985-01-17
申请号:DE3324917
申请日:1983-07-09
Applicant: BASF AG
Inventor: FIKENTSCHER ROLF DR , SCHNEIDER SIEGFRIED , KLAHR ERHARD DR , REINERT FRIEDRICH DR , ECKERT GUENTER DR , STUEBINGER ADOLF DR
IPC: B01J31/12 , C07B61/00 , C07D203/08
Abstract: beta -N-aziridinopropionates of relatively high boiling alcohols or polyalcohols are prepared by transesterifying a beta -N-aziridinopropionate of a lower alcohol of 1 to 4 carbon atoms with a relatively high boiling alcohol or polyalcohol by a process in which the transesterification is carried out in the presence of, as a transesterification catalyst, a titanium(IV) or tin(IV) compound which is soluble in an organic medium.
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