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    12.
    发明专利
    未知

    公开(公告)号：DE59304220D1

    公开(公告)日：1996-11-21

    申请号：DE59304220

    申请日：1993-12-02

    Applicant: BASF AG

    Inventor： BURKHART BERND ,  OFTRING ALFRED ,  SCHWENDEMANN VOLKER ,  SCHROEDER ULRICH ,  GLASER KLAUS

    IPC: C07C335/32 ,  C25D3/12 ,  C25D3/16

    Abstract: PCT No. PCT/EP93/03383 Sec. 371 Date Jun. 15, 1995 Sec. 102(e) Date Jun. 15, 1995 PCT Filed Dec. 2, 1993 PCT Pub. No. WO94/13862 PCT Pub. Date Jun. 23, 1994Nickel-plated shaped parts are produced by galvanic precipitation of nickel from aqueous-acid baths which contain as essential constituents one or several nickel salts, one or several inorganic acids and one or several brighteners. As brighteners are used thiourea salts having general formula (I), in which R1 to R4 stand for hydrogen, C1 to C18-alkyl, which may be substituted by carboxyl groups, C1 to C4-alkoxycarbonyl groups or cyano groups, C2 to C12-alkenyl, C2 to C12-alkinyl, C5 to C8-cycloalkyl, C7 to C12-phenylalkyl or phenyl, which may be substituted by one or two C1 to C4-alkyl residues, C1 to C4-alkoxy residues, halogen atoms, hydroxyl groups, phenyl groups, phenyl residues or C1 to C4 alkoxycarbonyl groups; Y sands for a chemical bond or for linear or branched alkylene, alkenylene or alkinylene having each up to 20 C. atoms; A stands for hydrogen or a group having the formulae: -CO-H, -CO-R5, -CO-OH, -CO-OR5, -CO-NR6R7, -CO-CH2-CO-OR5, -O-CO-H, -O-CO-R5, -NR6-CO-R5, -NR6-CO-R5, -OR5, -SO2-R5, -SO2-OH, -SO2-OR5, -PO(PH)2, -PO(OH)(OR5), -PO(OR5)2, OPO(OH)2, -OPO(PH)(PR5) or -OPO(OR5)2 in which R5 stands for C1 to C12-alkyl, C2 to C12-alkenyl, C2 to C12-alkinyl, C5 to C8-cycloalkyl, C7 to C12-phenylalkyl or phenyl, which may be substituted by one or two C1 to C4-alkyl residues, halogen atoms, hydroxyl groups, phenyl residues or C1 to C4-alkoxycarbonyl groups; and R6 and R7 stand for hydrogen or C1 to C4-alkyl; n is a number from 1 to 4 and X(-) stands for s water solubility-promoting, n-valent inorganic or organic anion.

    16.
    发明专利
    未知

    公开(公告)号：DE50000971D1

    公开(公告)日：2003-01-30

    申请号：DE50000971

    申请日：2000-02-21

    Applicant: BASF AG

    Inventor： HAEHNLE HANS-JOACHIM ,  SCHROEDER ULRICH ,  HEIDER WOLFGANG ,  SCHORNICK GUNNAR ,  ANSTOCK THOMAS

    IPC: A61L15/24 ,  A61L15/42 ,  A61L15/60 ,  B01J20/26 ,  C08J9/12 ,  C08J9/30 ,  C09K3/10 ,  C09K17/20

    Abstract: Water-absorbing, expanded, crosslinked polymers obtainable by(I) foaming a polymerizable aqueous mixture which comprises(a) monoethylenically unsaturated monomers which contain acidic groups and are optionally neutralized,(b) optionally other monoethylenically unsaturated monomers,(c) crosslinkers,(d) initiators,(e) 0.1-20% by weight of at least one surfactant,(f) optionally at least one solubilizer and(g) optionally thickeners, foam stabilizers, polymerization regulators, fillers and/or cell nucleating agents,where the foaming takes place by dissolving a gas which is inert to free radicals under a pressure of 2-400 bar in the polymerizable aqueous mixture, and then decompressing the latter to atmospheric pressure, and(II) polymerizing the foamed mixture to form an expanded hydrogel and, where appropriate, adjusting the water content of the expanded polymer to 1-60% by weight, process for preparing the water-absorbing, expanded, crosslinked polymers and use of these polymers in sanitary articles employed for absorbing body fluids, in dressing material for covering wounds, as sealing material, as soil improver, as soil substitute and as packaging material.

    18.
    发明专利
    未知

    公开(公告)号：DE19909214A1

    公开(公告)日：2000-09-07

    申请号：DE19909214

    申请日：1999-03-03

    Applicant: BASF AG

    Inventor： HAEHNLE HANS-JOACHIM ,  SCHROEDER ULRICH ,  HEIDER WOLFGANG ,  SCHORNICK GUNNAR ,  ANSTOCK THOMAS

    IPC: A61L15/24 ,  A61L15/42 ,  A61L15/60 ,  B01J20/26 ,  C08J9/12 ,  C08J9/30 ,  C09K3/10 ,  C09K17/20 ,  C08J9/20 ,  C09K3/12 ,  C09K17/18 ,  A61F13/15

    Abstract: The invention relates to water-absorbing, cellular, cross-linked polymers which are obtained by the following steps: (I) expanding a polymerizable aqueous mixture which contains (a) monoethylenically unsaturated monomers that contain acidic groups and that are optionally neutralized, (b) optionally other monoethylenically unsaturated monomers, (c) cross-linking agents, (d) initiators, (e) 0.1 to 20 wt.-%. of at least one surfactant, (f) optionally at least one solubilizer and (g) optionally thickeners, foam stabilizers, polymerization controllers, fillers and/or nucleating agents. A gas that is inert vis-à-vis radicals is dissolved in the polymerizable aqueous mixture at a pressure of 2 to 400 bar to expand the mixture and the mixture is then relaxed to atmospheric pressure; (II) polymerizing the expanded mixture while forming a cellular hydrogel and optionally adjusting the water content of the cellular polymer to 1 to 60 wt.-%. The invention further relates to methods for producing water-absorbing, cellular, cross-linked polymers and to the use of said polymers in hygiene articles that are used for absorbing body fluids, in dressings for covering wounds, as sealing material, as soil conditioner, soil substitute and as packaging material.

    20.
    发明专利
    未知

    公开(公告)号：ES2085774T3

    公开(公告)日：1996-06-01

    申请号：ES93909543

    申请日：1993-05-05

    Applicant: BASF AG

    Inventor： BURKHART BERND ,  OFTRING ALFRED ,  WIDDER RUDI ,  SCHROEDER ULRICH

    IPC: C07D215/10 ,  C07D213/20 ,  C07D217/10 ,  C23C18/00 ,  C25D3/12

    Abstract: PCT No. PCT/EP93/01090 Sec. 371 Date Oct. 19, 1994 Sec. 102(e) Date Oct. 19, 1994 PCT Filed May 5, 1993 PCT Pub. No. WO93/23377 PCT Pub. Date Nov. 25, 1993A process for the preparation of N-allyl compounds of the general formula I I in which denotes a nitrogen-containing heterocyclic compound, R1, R3, and R4 independently denote hydrogen or C1-C4 alkyl, R2 denotes hydrogen or methyl, n is equal to 1, 2, 3, or 4, and X denotes a water-solubilizing anion, wherein a compound of formula II II is caused to react, in aqueous medium, with a compound of formula III III in which A denotes a radical which can be eliminated as an anion. The compounds produced by the process of the invention are very well suited for use as brighteners in nickel electroplating.

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