公开(公告)号：FR1508646A

公开(公告)日：1968-01-05

申请号：FR91780

申请日：1967-01-19

Applicant: BASF AG

Inventor： NAARMANN HERBERT ,  STABENOW JOACHIM ,  KASTNING ERNST-GUENTHER

IPC: C08F36/04

Abstract: 1,164,375. Redox catalysts for diene polymerization. BADISCHE ANILIN- & SODAFABRIK A.G. 20 Jan., 1967 [22 Jan., 1966] No. 3132/67. Heading C3P. A 1,3-diene or a monomer mixture containing a 1,3-diene is polymerized in aqueous emulsion using a redox catalyst of at least two components, wherein each component of the catalyst system is soluble in the monomer or monomer mixture to an amount of at least 1 % under polymerization conditions, one of the components comprising a butadiene sulphone. Suitable peroxides include cumene hydroperoxide, pinene hydroperoxide, benzoyl peroxide, p, p 1 -dinitrobenzoyl peroxide, lauroyl peroxide, diethyl-, ditertiary butyl- and ditolyl peroxycarbonate, ethyl α-methoxy peroxyacetate, 3 - phenyl - 3 - tert. - butyl peroxyphthalide, and γ-tertiary butyl peroxyvalerolactone.