公开(公告)号：MXPA03003377A

公开(公告)日：2004-12-13

申请号：MXPA03003377

申请日：2001-11-16

Applicant: BASF AG

Inventor： VERRELST WIM

IPC: B01J27/12 ,  B01J27/32 ,  B01J38/00 ,  B01J38/52 ,  C08F4/14 ,  C08F6/00 ,  C08F6/02 ,  C08F6/08 ,  C08F10/00

Abstract: Procedimiento para desactivar y recuperar trifluoruro borico en la obtencion de poliisobutenos por polimerizacion cationica de isobuteno o corrientes de hidrocarburo que contienen isobuteno, en la fase liquida, en presencia de trifluoruro borico como tal o en forma de un complejo catalitico, que contiene trifluoruro borico, en donde se separa el complejo de catalizador como fase substancialmente liquida de la descarga del reactor, cuyo procedimiento esta caracterizado porque a) se adiciona a la descarga del reactor de polimerizacion a 60 hasta 0 degree C metanol, etanol o una mezcla de metanol y etanol en una cantidad suficiente, para que se precipite una fase alcoholica rica en triufluoruro borico, y b) se separa la fase alcoholica segun (a) y c) se recicla el trifluoruro borico de la fase alcoholica segun (b) en forma apropiada al procedimiento.

公开(公告)号：DE50102277D1

公开(公告)日：2004-06-17

申请号：DE50102277

申请日：2001-07-13

Applicant: BASF AG

Inventor： WETTLING THOMAS ,  BORCHERS DIRK ,  VERRELST WIM ,  RATH PETER

IPC: C08F2/38 ,  C08F4/14 ,  C08F6/02 ,  C08F10/10

Abstract: The production of polyisobutene by liquid-phase, cationic polymerization of isobutene in the presence of a boron trifluoride catalyst followed by the addition of a solid deactivator at a required point in time uses a deactivator (I) containing boron trifluoride-binding prim., sec., tert. and/or quat. nitrogen atoms, which is insoluble in the reaction mixture. In the production of polyisobutenes (PIB) by liquid-phase, cationic polymerization of isobutene or hydrocarbon streams containing isobutene in the presence of boron trifluoride as catalyst, the catalytic activity of the BF3 is partly or completely eliminated at a required point in time by means of a solid deactivator which contains BF3-binding prim., sec., tert. and/or quat. nitrogen atoms and is insoluble in the reaction mixture.

公开(公告)号：AU9376101A

公开(公告)日：2002-02-25

申请号：AU9376101

申请日：2001-08-11

Applicant: BASF AG

Inventor： WETTLING THOMAS ,  BORCHERS DIRK ,  VERRELST WIM ,  RATH HANS PETER

IPC: C08F4/14 ,  C08F6/02 ,  C08F6/08 ,  C08F10/10 ,  C08F110/10

Abstract: A process for the preparation of polyisobutylenes by cationic polymerization of isobutylene or isobutylene-containing hydrocarbon streams in the liquid phase in the presence of boron trifluoride acting as catalyst, the catalytic activity of boron trifluoride being partially or completely stopped by means of a solid deactivator following a given timelapse, which deactivator is an inorganic, anhydrous or hydrous oxygen compound of aluminum which is insoluble in the reaction mixture.

公开(公告)号：AT266682T

公开(公告)日：2004-05-15

申请号：AT01967167

申请日：2001-07-13

Applicant: BASF AG

Inventor： WETTLING THOMAS ,  BORCHERS DIRK ,  VERRELST WIM ,  RATH HANS PETER

IPC: C08F2/38 ,  C08F4/14 ,  C08F6/02 ,  C08F10/10

Abstract: The production of polyisobutene by liquid-phase, cationic polymerization of isobutene in the presence of a boron trifluoride catalyst followed by the addition of a solid deactivator at a required point in time uses a deactivator (I) containing boron trifluoride-binding prim., sec., tert. and/or quat. nitrogen atoms, which is insoluble in the reaction mixture. In the production of polyisobutenes (PIB) by liquid-phase, cationic polymerization of isobutene or hydrocarbon streams containing isobutene in the presence of boron trifluoride as catalyst, the catalytic activity of the BF3 is partly or completely eliminated at a required point in time by means of a solid deactivator which contains BF3-binding prim., sec., tert. and/or quat. nitrogen atoms and is insoluble in the reaction mixture.

公开(公告)号：HU0300675A2

公开(公告)日：2003-08-28

申请号：HU0300675

申请日：2001-08-11

Applicant: BASF AG

Inventor： BORCHERS DIRK ,  RATH HANS PETER ,  VERRELST WIM ,  WETTLING THOMAS DR

IPC: C08F4/14 ,  C08F6/02 ,  C08F6/08 ,  C08F10/10 ,  C08F110/10

Abstract: A process for the preparation of polyisobutylenes by cationic polymerization of isobutylene or isobutylene-containing hydrocarbon streams in the liquid phase in the presence of boron trifluoride acting as catalyst, the catalytic activity of boron trifluoride being partially or completely stopped by means of a solid deactivator following a given timelapse, which deactivator is an inorganic, anhydrous or hydrous oxygen compound of aluminum which is insoluble in the reaction mixture.

公开(公告)号：CA2426077A1

公开(公告)日：2003-04-15

申请号：CA2426077

申请日：2001-11-16

Applicant: BASF AG

Inventor： WETTLING THOMAS ,  VERRELST WIM ,  BORCHERS DIRK ,  RATH HANS PETER

IPC: B01J27/12 ,  B01J27/32 ,  B01J38/00 ,  B01J38/52 ,  C08F4/14 ,  C08F6/00 ,  C08F6/02 ,  C08F6/08 ,  C08F10/00

Abstract: The invention relates to a method for deactivating and recovering boron trifluoride when producing polyisobutenes by means of cationic polymerisation of isobutene or hydrocarbon streams containing isobutene in the liquid phase in the presence of boron trifluoride or in the form of a boron trifluoride catalyst complex. Said catalyst complex is separated, essentially in the liquid phase, from the reactor discharge. Said method contains the following steps, a) removing from the polymerisation reactor at -60 to 0 ~C, methanol, ethanol or a mixture of methanol and ethanol in such a quantity that an alcohol phase rich in boron trifluoride is deposited b) separating the alcohol phase according to (a) and, (c) from the alcohol phase according to (b) is reintegrated into the inventive method in a suitable manner if desired.

公开(公告)号：CA2418032A1

公开(公告)日：2003-01-31

申请号：CA2418032

申请日：2001-08-11

Applicant: BASF AG

Inventor： RATH HANS PETER ,  VERRELST WIM ,  WETTLING THOMAS ,  BORCHERS DIRK

IPC: C08F4/14 ,  C08F6/02 ,  C08F6/08 ,  C08F10/10 ,  C08F110/10

Abstract: The invention relates to a method for producing polyisobutenes by means of cationic polymerisation of isobutene or hydrocarbon flows containing isobute ne in the liquid phase in the presence of boron trifluoride as a catalyst. The catalytic efficacy of the boron trifluoride is partially or fully eliminated at a desired point in time by means of a solid deactivator, said deactivator being an inorganic, anhydrous, or aqueous aluminium oxide which is insoluble in the reaction mixture.

公开(公告)号：DE10035298A1

公开(公告)日：2002-01-31

申请号：DE10035298

申请日：2000-07-18

Applicant: BASF AG

Inventor： WETTLING THOMAS ,  BORCHERS DIRK ,  VERRELST WIM

IPC: C08F2/38 ,  C08F4/14 ,  C08F6/02 ,  C08F10/10

Abstract: The production of polyisobutene by liquid-phase, cationic polymerization of isobutene in the presence of a boron trifluoride catalyst followed by the addition of a solid deactivator at a required point in time uses a deactivator (I) containing boron trifluoride-binding prim., sec., tert. and/or quat. nitrogen atoms, which is insoluble in the reaction mixture. In the production of polyisobutenes (PIB) by liquid-phase, cationic polymerization of isobutene or hydrocarbon streams containing isobutene in the presence of boron trifluoride as catalyst, the catalytic activity of the BF3 is partly or completely eliminated at a required point in time by means of a solid deactivator which contains BF3-binding prim., sec., tert. and/or quat. nitrogen atoms and is insoluble in the reaction mixture.