REDUCTION OF THE CONTENT OF COMPOUNDS CONTAINING OXYGEN AND/OR NITROGEN IN MATERIAL FLOWS CONTAINING ISOBUTENE
    1.
    发明申请
    REDUCTION OF THE CONTENT OF COMPOUNDS CONTAINING OXYGEN AND/OR NITROGEN IN MATERIAL FLOWS CONTAINING ISOBUTENE 审中-公开
    还原氧含AND / OR氮肥连接。在异丁烯物资流通水平

    公开(公告)号:WO2004101477A2

    公开(公告)日:2004-11-25

    申请号:PCT/EP2004005200

    申请日:2004-05-14

    CPC classification number: C07C7/13 C07C11/09

    Abstract: The invention relates to a method for reducing the content of compounds containing oxygen and/or nitrogen in material flows having an isobutene content of at least 10 wt. %. According to said method, the material flow is guided over a fixed bed of an acid-free zeolite having a mean pore size of between 0.3 and 1.5 nm, in a liquid phase, at a temperature T [in K] and at a linear speed v [in cm/min], the fixed bed having a dimension I [in cm] in the flow direction of the material flow, and T, v and I obeying the equation 2 l/v = 500 min. The inventive method prevents the formation of isobutene oligomers.

    Abstract translation: 公开了一种用于减少的含量的含氧和/或具有至少10重量%的异丁烯含量的流化合物,含氮其中所述线性在温度T在液相中的材料流[在K]并用的方法 速度v [在厘米/分钟]经过具有0.3的平均孔径的无酸沸石的固定床至1.5nm,其中在所述材料流动的延伸件1包括[以cm]和T,v和I的流动方向上的固定床 方程2 <(T-283 K)/ 10 K.> L / v <= 500分钟233。 的处理过程避免了异丁烯的形成。

    2.
    发明专利
    未知

    公开(公告)号:DE50102277D1

    公开(公告)日:2004-06-17

    申请号:DE50102277

    申请日:2001-07-13

    Applicant: BASF AG

    Abstract: The production of polyisobutene by liquid-phase, cationic polymerization of isobutene in the presence of a boron trifluoride catalyst followed by the addition of a solid deactivator at a required point in time uses a deactivator (I) containing boron trifluoride-binding prim., sec., tert. and/or quat. nitrogen atoms, which is insoluble in the reaction mixture. In the production of polyisobutenes (PIB) by liquid-phase, cationic polymerization of isobutene or hydrocarbon streams containing isobutene in the presence of boron trifluoride as catalyst, the catalytic activity of the BF3 is partly or completely eliminated at a required point in time by means of a solid deactivator which contains BF3-binding prim., sec., tert. and/or quat. nitrogen atoms and is insoluble in the reaction mixture.

    Method for producing polyisobutenes

    公开(公告)号:AU9376101A

    公开(公告)日:2002-02-25

    申请号:AU9376101

    申请日:2001-08-11

    Applicant: BASF AG

    Abstract: A process for the preparation of polyisobutylenes by cationic polymerization of isobutylene or isobutylene-containing hydrocarbon streams in the liquid phase in the presence of boron trifluoride acting as catalyst, the catalytic activity of boron trifluoride being partially or completely stopped by means of a solid deactivator following a given timelapse, which deactivator is an inorganic, anhydrous or hydrous oxygen compound of aluminum which is insoluble in the reaction mixture.

    5.
    发明专利
    未知

    公开(公告)号:DK0788475T3

    公开(公告)日:1999-12-20

    申请号:DK95917966

    申请日:1995-04-26

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP95/01581 Sec. 371 Date Nov. 4, 1996 Sec. 102(e) Date Nov. 4, 1996 PCT Filed Apr. 26, 1995 PCT Pub. No. WO95/30648 PCT Pub. Date Nov. 16, 1995Preparation of mixtures of O-phenoxyalkylhydroxylamines Ia and Ib (Ia): H2NOCH2CH(R1)OAr (Ib): H2NOCH(R1)CH2OAr and the corresponding salt mixtures by a) converting mixtures of isomers of O-(2-hydroxyethyl)oximes IIa and IIb (IIa): (III): into a mixture of sulfonates IVa and IVb (IVa): (IVb): b) reacting this mixture of IVa and IVb with a phenol HO-Ar (V) to give a mixture of O-phenoxyalkoximes VIa and VIb (VIa): (VIb): c) hydrolyzing this mixture in the presence of an acid and, if desired d) liberating the O-phenoxyalkylhydroxylamines Ia and Ib from the resulting salts using a mineral acid. Compounds Ia/Ib and VIa/VIb are important intermediates for crop protection agents.

    6.
    发明专利
    未知

    公开(公告)号:AT185793T

    公开(公告)日:1999-11-15

    申请号:AT95917966

    申请日:1995-04-26

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP95/01581 Sec. 371 Date Nov. 4, 1996 Sec. 102(e) Date Nov. 4, 1996 PCT Filed Apr. 26, 1995 PCT Pub. No. WO95/30648 PCT Pub. Date Nov. 16, 1995Preparation of mixtures of O-phenoxyalkylhydroxylamines Ia and Ib (Ia): H2NOCH2CH(R1)OAr (Ib): H2NOCH(R1)CH2OAr and the corresponding salt mixtures by a) converting mixtures of isomers of O-(2-hydroxyethyl)oximes IIa and IIb (IIa): (III): into a mixture of sulfonates IVa and IVb (IVa): (IVb): b) reacting this mixture of IVa and IVb with a phenol HO-Ar (V) to give a mixture of O-phenoxyalkoximes VIa and VIb (VIa): (VIb): c) hydrolyzing this mixture in the presence of an acid and, if desired d) liberating the O-phenoxyalkylhydroxylamines Ia and Ib from the resulting salts using a mineral acid. Compounds Ia/Ib and VIa/VIb are important intermediates for crop protection agents.

    8.
    发明专利
    未知

    公开(公告)号:DE50106917D1

    公开(公告)日:2005-09-01

    申请号:DE50106917

    申请日:2001-11-16

    Applicant: BASF AG

    Abstract: The invention relates to a method for deactivating and recovering boron trifluoride when producing polyisobutenes by means of cationic polymerization of isobutene or hydrocarbon streams containing isobutene in the liquid phase in the presence of boron trifluoride or in the form of a boron trifluoride catalyst complex. The catalyst complex is separated, essentially in the liquid phase, from the reactor discharge. The method comprises the following steps: a) removing from the polymerization reactor at -60 to 020 C., methanol, ethanol or a mixture of methanol and ethanol in such a quantity that an alcohol phase rich in boron trifluoride is formed; b) separating the alcohol phase according to (a) and, (c) optionally recycling the boron trifluoride of the alcohol phase obtained from (b) to the method in a suitable manner.

    9.
    发明专利
    未知

    公开(公告)号:DE10322153A1

    公开(公告)日:2004-12-02

    申请号:DE10322153

    申请日:2003-05-16

    Applicant: BASF AG

    Abstract: A process for reducing the content of oxygen-containing and/or nitrogen-containing compounds in streams having an isobutene content of at least 10% by weight, which comprises passing the stream in the liquid state at a temperature T [in K] and a linear velocity v [in cm/min] over a fixed bed of an acid-free zeolite having a mean pore size of from 0.3 to 1.5 nm, where the fixed bed has a length l [in cm] in the flow direction of the stream and T, v and l obey the relationship 2 (T-283 K)/10 K .l/v is described. The process avoids the formation of isobutene oligomers.

    10.
    发明专利
    未知

    公开(公告)号:AT268342T

    公开(公告)日:2004-06-15

    申请号:AT01974173

    申请日:2001-08-11

    Applicant: BASF AG

    Abstract: A process for the preparation of polyisobutylenes by cationic polymerization of isobutylene or isobutylene-containing hydrocarbon streams in the liquid phase in the presence of boron trifluoride acting as catalyst, the catalytic activity of boron trifluoride being partially or completely stopped by means of a solid deactivator following a given timelapse, which deactivator is an inorganic, anhydrous or hydrous oxygen compound of aluminum which is insoluble in the reaction mixture.

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