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公开(公告)号:NO159474C
公开(公告)日:1989-01-04
申请号:NO833566
申请日:1983-09-30
Applicant: BASF AG
Inventor: VOLKAMER KLAUS , WAGNER ECKHART , WAGNER ULRICH
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公开(公告)号:NO160178B
公开(公告)日:1988-12-12
申请号:NO854706
申请日:1985-11-25
Applicant: BASF AG
Inventor: WAGNER ECKHART , VOLKAMER KLAUS , HEFNER WERNER , WAGNER ULRICH , SCHUBERT FRANZ
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公开(公告)号:NO159519B
公开(公告)日:1988-10-03
申请号:NO833565
申请日:1983-09-30
Applicant: BASF AG
Inventor: WAGNER ECKHART , VOLKAMER KLAUS , WAGNER ULRICH
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14.
公开(公告)号:CA1222258A
公开(公告)日:1987-05-26
申请号:CA455081
申请日:1984-05-24
Applicant: BASF AG
Inventor: LINDNER ALFRED , BROELLOS KLAUS , SANDROCK GERHARD , VOLKAMER KLAUS , HEFNER WERNER
Abstract: The invention relates to a process for the separation of a C4-hydrocarbon mixture which essentially contains n-butenes and butanes. This process is characterized in that the mixture is reacted with a carboxylic acid in the presence of an acidic catalyst to form a butyl carboxylate; the reaction mixture obtained from the esterification zone is distilled to give, as the top product, a fraction containing the butanes, and, as the bottom product, a fraction containing the resulting butyl carboxylate; the butyl carboxylate is decomposed at elevated temperatures to give the carboxylic acid and n-butenes; and the mixture of n-butenes and carboxylic acid is then distilled, the n-butenes being obtained as the top product, and the carboxylic acid as the bottom product. This process permits to use apparatus that are less expensive than those required for the conventional extractive distillation method.
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公开(公告)号:CA1219882A
公开(公告)日:1987-03-31
申请号:CA457291
申请日:1984-06-22
Applicant: BASF AG
Inventor: LINDNER ALFRED , WAGNER ULRICH , VOLKAMER KLAUS , HOELDERICH WOLFGANG , HOCHSTEIN WALDHELM , IMMEL WOLFGANG
IPC: B01J27/00 , B01J27/28 , B01J29/00 , C07B61/00 , C07C1/00 , C07C5/23 , C07C5/25 , C07C7/04 , C07C11/08 , C07C67/00
Abstract: 1-Butene is recovered from a C4-hydrocarbon mixture which contains 2-butenes and may or may not contain 1-butene by catalytic isomerization of the 2-butenes to 1-butene at elevated temperatures and isolation of the 1-butene, by a process in which the said isomerization is carried out in the presence of an acidic catalyst at from 150 to 500.degree.C, the isomerization mixture obtained from the isomerization zone is fed into a distillation zone, 1-butene is taken off at the top of the distillation zone, a fraction containing 2-butenes is taken off in the lower third of the distillation zone and fed into the isomerization zone, and the starting C4hydrocarbon mixture which contains 2-butenes and may or may not contain 1-butene is fed to the distillation zone and/or the isomerization zone.
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公开(公告)号:CA1212820A
公开(公告)日:1986-10-21
申请号:CA438134
申请日:1983-09-30
Applicant: BASF AG
Inventor: VOLKAMER KLAUS , WAGNER ECKHART , WAGNER ULRICH
Abstract: CO2 and/or H2S are removed from gases which contain CO2 and/or H2S by a process in which the said gas is treated, in an absorption stage at from 40 to 100.degree.C, with an aqueous absorption liquid containing from 20 to 70% by weighty of methyldiethanolamine, the treated gas is taken off at the top of the absorption stage, the aqueous absorption liquid laden with CO2 and/or H2S is taken off at the bottom of the absorption stage and then regenerated by being let down in one or more flash stages, the flash gases being taken off at the top of the flash stage or flash stages, the losses of water as a result of water present in the gas streams taken off at the top of the absorption stage and of the flash stage or flash stages are compensated by feeding in, at the bottom of the last flash stage or, where only one flash stage is used, at the bottom of this, and amount of steam corresponding to the water loss, and the regenerated absorption liquid is recycled to the absorption stage.
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公开(公告)号:CA1182774A
公开(公告)日:1985-02-19
申请号:CA402343
申请日:1982-05-05
Applicant: BASF AG
Inventor: BROELLOS KLAUS , VOLKAMER KLAUS , LINDNER ALFRED
Abstract: A process for obtaining a conjugated diolefin from a mixture of C4 or C5 hydrocarbons which contains this diolefin, by single-stage or multistage extractive distillation using a selective solvent and recycling the latter to the extractive distillation, after it has been obtained from the stripping zone downstream from each extractive distillation, a bleed stream of the recycled selective solvent being regenerated in a solvent purification stage in which the high-boiling or non-volatile impurities present in the solvent are separated off, and the regenerated solvent obtained from the solvent purification stage also being recycled, which process comprises regenerating the solvent in a thin-film evaporation zone.
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公开(公告)号:CA1145290A
公开(公告)日:1983-04-26
申请号:CA347098
申请日:1980-03-06
Applicant: BASF AG
Inventor: VOLKAMER KLAUS , BROELLOS KLAUS , LINDNER ALFRED , WAGNER ULRICH , WEITZ HANS-MARTIN , SCHNEIDER KLAUS-JUERGEN
Abstract: A process for isolating a conjugated diolefin from a C4- or C5-hydrocarbon mixture containing the diolefin, by single-stage or multi-stage extractive distillation using a selective solvent, wherein the selective solvent is a solvent mixture which comprises: a) from 50 to 98 percent by weight of an N-alkyl-substituted lower aliphatic acid amide or of an N-alkyl-substituted alicyclic acid amide having 5 ring members and b) from 2 to 50 percent by weight of a lower aliphatic carboxylic acid ester or carbonic acid ester boiling at from 30.degree.C to 200.degree.C.
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公开(公告)号:CA1145288A
公开(公告)日:1983-04-26
申请号:CA347043
申请日:1980-03-05
Applicant: BASF AG
Inventor: VOLKAMER KLAUS , BROELLOS KLAUS , LINDNER ALFRED , WAGNER ULRICH , WEITZ HANS-MARTIN , SCHNEIDER KLAUS-JUERGEN
Abstract: A process for isolating a conjugated diolefin from a C4- or C5-hydrocarbon mixture containing the diolefin, by single-stage or multi-stage extractive distillation using a selective solvent, wherein the selective solvent is a solvent mixture which comprises: a) from 75 to 98 per cent by weight of an N-alkylsubstituted lower aliphatic acid amide or of an N-alkylsubstituted alicyclic acid amide having 5 ring members, boiling at from 140 to 260.degree.C, or butyrolactone or methoxypropionitrile and b) from 2 to 25 per cent by weight of acetonitrile.
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公开(公告)号:CS219323B2
公开(公告)日:1983-03-25
申请号:CS745076
申请日:1976-11-18
Applicant: BASF AG
Inventor: APPL MAX , WAGNER ULRICH , HENRICI HANS J , KUESSNER KLAUS , VOLKAMER KLAUS , FUERST ERNST
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