HERBICIDES CONTAINING 3-AMINOBENZO(B)THIOPHENES AS AN ANTIDOTE
    13.
    发明申请
    HERBICIDES CONTAINING 3-AMINOBENZO(B)THIOPHENES AS AN ANTIDOTE 审中-公开
    含有3-氨基苯并(B)噻吩作为抗凝血剂的除草剂

    公开(公告)号:WO9304057A3

    公开(公告)日:1993-07-22

    申请号:PCT/EP9201798

    申请日:1992-08-07

    Applicant: BASF AG

    CPC classification number: A01N25/32 C07D333/66 C07D333/68

    Abstract: Disclosed are herbicides containing at least one 3-aminobenzo[b]thiophene (I) with an antagonistic action (in which R1 = -COX or -COOX; X = H, halogen, optionally substituted amino, optionally substituted C¿1?-C10 alkyl, optionally sustituted C1-C8 alkenyl, optionally substituted C3-C10 cycloalkyl, optionally substituted C3-C10 cycloalkenyl, a 5/6-membered heterocyclic aromatic, optionally substituted phenyl or optionally substituted naphthyl; R?2 and R3¿ = H, CN, NO¿2?, SH, halogen, optionally substituted amino, optionally substituted C1-C10 alkyl, optionally substituted C1-C6 alkoxy, optionally substituted C2-C8 alkenyl, optionally substituted C3-C10 cycloalkyl, optionally substituted C3-C10 cycloalkenyl, optionally substituted phenyl, optionally substituted naphthyl or a 5/6-membered heterocyclic aromatic; R?4 to R7¿ = H, optionally substituted C¿1?-C10 alkyl, optionally substituted C2-C8 alkenyl, optionally substituted C3-C10 cycloalkyl, optionally substituted C3-C10 cycloalkenyl, an optionally substituted 5/6-membered heterocyclic aromatic, optionally substituted phenyl or optionally substituted naphthyl or R?4 + R5¿ and/or R6 + R7 form, together with the N-atom to which they are bound, a 5- to 7-membered ring), plus the basic salts of those compounds of formula (I) which carry at least one carboxyl, hydroxythiocarbonyl or sulphonic acid group and the acid salts of those compounds of formula (I) which contain a basic nitrogen atom, and at least one herbicidal substance selected (A) from the group comprising the cyclohexenone derivatives or (B) from the group comprising the 4-(hetero)aryloxyphenoxyacetic acid derivatives.

    Abstract translation: 公开了含有至少一种具有拮抗作用的3-氨基苯并[b]噻吩(I)的除草剂(其中R1 = -COX或-COOX; X = H,卤素,任选取代的氨基,任选取代的取代基; 1'-C10 烷基,任选取代的C 1 -C 8烯基,任选取代的C 3 -C 10环烷基,任选取代的C 3 -C 10环烯基,5/6元杂环芳族,任选取代的苯基或任选取代的萘基; R 2和R 3' NO 2,SH,卤素,任选取代的氨基,任选取代的C 1 -C 10烷基,任选取代的C 1 -C 6烷氧基,任选取代的C 2 -C 8烯基,任选取代的C 3 -C 10环烷基, 任选取代的苯基,任选取代的萘基或5元/ 6元杂环芳基; R 4至R 7任选; = H,任选取代的C 1 -C 10烷基;任选取代的C 2 -C 8烯基;任选取代的C 3 -C 10环烷基; 取代的C 3 -C 10环烯基,任选取代的5/6元杂环芳族,任选取代的苯基或任选取代的萘基或R 4'+ R 5' 和/或R 6 + R 7与它们所连接的N原子一起形成5至7元环),加上那些带有至少一个羧基的羟基硫代羰基的式(I)化合物的碱性盐 或磺酸基团和含有碱性氮原子的那些式(I)化合物的酸式盐,和至少一种选自(A)选自(A)包含环己烯酮衍生物或(B)选自下组的化合物的除草剂物质 - (杂)芳氧基苯氧乙酸衍生物。

    TRICYCLIC CYCLOHEXANEDIONE DERIVATIVES
    18.
    发明申请
    TRICYCLIC CYCLOHEXANEDIONE DERIVATIVES 审中-公开
    三环环己二酮衍生物

    公开(公告)号:WO0059911A2

    公开(公告)日:2000-10-12

    申请号:PCT/EP0002565

    申请日:2000-03-23

    CPC classification number: C07D495/04 A01N43/90

    Abstract: The invention relates to tricyclic cyclohexanedione derivatives of formula (I) in which the substituents have the following meaning: R is hydrogen, C1-C6 alkyl, C1-C6 haloalkyl, C1-C6 alkoxy, C1-C6 haloalkoxy, C1-C6 alkylthio, C1-C6 haloalkylthio, C1-C6 alkylsulfinyl, C1-C6 haloalkylsulfinyl, C1-C6 alkylsulfonyl, C1-C6 haloalkylsulfonyl, halogen, cyano or nitro; X is O or NR ; R is hydrogen, C1-C6 alkyl, C1-C6 alkoxy, C1-C6 haloalkyl, C1-C6 haloalkoxy, phenyl that is optionally substituted with C1-C3 alkyl, halogen, cyano, nitro or C1-C3 alkylsulfonyl or phenylsulfonyl that is optionally substituted with C1-C3 alkyl, halogen, cyano or nitro; R , R is hydrogen, C1-C6 alkyl, C1-C6 haloalkyl, C1-C6 alkoxy, C1-C6 haloalkoxy, C1-C6 alkylthio, C1-C6 haloalkylthio, C1-C6 alkylsulfinyl, C1-C6 haloalkylsulfinyl, C1-C6 alkylsulfonyl, C1-C6 haloalkylsulfonyl, NR R , C2-C6 alkoxyalkyl, C1-C6 alkoxycarbonyl, C1-C6 alkylcarbonyl, halogen, cyano, nitro, phenyl that is optionally substituted with C1-C3 alkyl, halogen, cyano or nitro; R is hydrogen or C1-C4 alkyl; R is hydrogen, C1-C6 alkyl or halogen; R is hydrogen or C1-C6 alkyl; R is C1-C6 alkyl or C1-C6 alkoxy; 1 is 0, 1 or 2; n is 1 or 2; R is substituted (3-oxo-1-cyclohexene-2-yl)carbonyl or substituted (1,3-dioxo-2-cyclohexyl)methylidene. The invention also relates to the agriculturally useful salts of the compounds (I), to methods for producing said tricyclic cyclohexanedione derivatives and to the intermediates for their production. The invention encompasses agents containing the inventive compounds and the use of said derivatives or of agents containing them for weed control.

    Abstract translation: (I),式三环环己二酮衍生物,其中取代基具有以下含义:R t <1>为氢,C1-C6烷基,C1-C6卤代烷基,C1-C6-烷氧基,C1-C6卤代烷氧基,C1-C6 烷硫基,C1-C6卤代烷硫基,C1-C6烷基亚磺酰基,C1-C6卤代烷基亚磺酰,C 1 -C 6 - 烷基磺酰基,C1-C6卤代烷基磺酰基,卤素,氰基或硝基; X是O或NR <2>; [R <2>的氢,C1-C6烷基,C1-C6-烷氧基,C1-C6卤代烷基,C1-C6-卤代烷氧基,任选地被C1-C3烷基,卤素,氰基,硝基或C1-C3烷基磺酰基取代的取代的 苯基或任选地被C1-C3烷基,卤素,氰基或硝基取代的苯磺酰基; [R <3>,R <4>为氢,C1-C6烷基,C1-C6卤代烷基,C1-C6-烷氧基,C1-C6卤代烷氧基,C1-C6烷硫基,C1-C6卤代烷硫基,C1-C6 烷基亚磺酰基,C1-C6-卤代烷基亚磺酰,C 1 -C 6 - 烷基磺酰基,C1-C6卤代烷基磺酰基,NR <7> - [R <8>,C2-C6烷氧基烷基,C1-C6烷氧羰基,C1-C6烷基羰基,卤素, 氰基,硝基,任选地被C1-C3烷基,卤素,氰基或硝基取代; [R <5>是氢或C1-C4烷基; [R <6>为氢,C1-C6烷基或卤素; [R <7>是氢或C1-C6烷基; [R <8> C1-C6烷基或C1-C6烷氧基; 1 0,1或2; n是1或2; [R <9>取代的(3-氧代-1-环己烯-2-基)羰基,或取代的(1,3-二氧代-2-环己基)亚甲基; 和化合物(I)的可农用盐,用于制备三环环己二酮衍生物以及中间体其制备方法,含有它们的组合物,以及使用这些衍生物或组合物的包含它们的用于控制杂草的方法。

    HERBICIDAL SULPHONYL UREAS, PROCESS AND INTERMEDIATES FOR PRODUCING THE SAME
    19.
    发明申请
    HERBICIDAL SULPHONYL UREAS, PROCESS AND INTERMEDIATES FOR PRODUCING THE SAME 审中-公开
    除草剂磺酰脲,生产方法和中间体

    公开(公告)号:WO9305048A3

    公开(公告)日:1993-05-27

    申请号:PCT/EP9201879

    申请日:1992-08-25

    Applicant: BASF AG

    CPC classification number: C07D521/00

    Abstract: Substituted sulphonyl ureas have the general formula (I), in which n and m equal 0 or 1 and the substituents have the following meaning: R1 is hydrogen, alkyl, alkenyl or alkinyl; R2 is halogen or trifluoromethyl, when m equals 0 or, when m equals 1, R2 is alkyl, alkenyl or alkinyl, and when X stands for O or S and m equals 1, trifluoromethyl or chlorodifluoromethyl; X is O, S or N-R4, whereas R4 is hydrogen or alkyl; R3 is hydrogen, halogen, alkyl, halogenalkyl, alkoxy or halogenalkoxy; A is NO¿2?, NH2, OH, CN, SCN, S(O)oR?5, SO¿2NR?6R7, ER7¿, whereas E stands for O, S or NR9, the groups (a), (b) possibly substituted C¿1?-C4-alkyl or C2-C4-alkenyl; R?5¿ is a possibly substituted alkyl group, a possibly substituted cycloalkyl group, an alkenyl group or an alkinyl group; R6 is hydrogen, an alkoxy group, an alkyl group, or represents together with R7 a C4-C6-alkylene chain, wherein a methylene group may be substituted by an oxygen atom or a C1-C4-alkylimino group; R7 is a possibly substituted alkyl, alkenyl or alkinyl group, a cycloalkyl group and may also represent, when E = NR9, methyl sulphone, trifluoromethyl sulphone, ethylsulphone, possibly halogen-substituted acetyl, dimethylcarbamoyl, dimethylsulphamoyl; o equals 0, 1 or 2; p, q equal 0 and/or 1 (when p = 0, q = 0); R8 is hydrogen or halogen; R9 is hydrogen, methyl, ethyl; R10 is alkyl, halogenalkyl, alkoxyalkyl, alkenyl, cycloalkyl, halogenalkenyl or, when p = 1 and q = 0, it may also be alkylamino or dialkylamino. Also disclosed are their environmentally compatible salts, a process and intermediates for producing the compounds having the formula (I) and their use as herbicides.

    Abstract translation: 取代的磺酰脲具有通式(I),其中n和m等于0或1,并且取代基具有以下含义:R 1是氢,烷基,烯基或炔基; 当m等于0或当m等于1时,R2是烷基,链烯基或炔基,并且当X代表O或S并且m等于1时,R2是卤素或三氟甲基; X是O,S或N-R4,而R4是氢或烷基; R3是氢,卤素,烷基,卤代烷基,烷氧基或卤代烷氧基; (a),(b)和(b)中,A代表O和S; NR代表O,S或NR 9; A代表O和S; NR 2代表NH 2,OH,CN,SCN,S(O)OR 5,SO& )可能被取代的C 1 -C 4烷基或C 2 -C 4链烯基; 的R 5&iquest?; 是可能被取代的烷基,可能被取代的环烷基,链烯基或炔基; R6是氢,烷氧基,烷基,或者与R7一起代表C4-C6-亚烷基链,其中亚甲基可以被氧原子或C1-C4-烷基亚氨基取代; 当E = NR9时,R7是可能被取代的烷基,烯基或炔基,环烷基并且还可以表示甲基砜,三氟甲基砜,乙基砜,可能被卤素取代的乙酰基,二甲基氨基甲酰基,二甲基氨磺酰基; o等于0,1或2; p,q等于0和/或1(当p = 0时,q = 0); R8是氢或卤素; R9是氢,甲基,乙基; R10是烷基,卤代烷基,烷氧基烷基,链烯基,环烷基,卤代链烯基或当p = 1和q = 0时,它也可以是烷基氨基或二烷基氨基。 还公开了它们的环境相容性盐,用于制备具有式(I)的化合物的方法和中间体以及它们作为除草剂的用途。

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