13.
    发明专利
    未知

    公开(公告)号:DE59207493D1

    公开(公告)日:1996-12-12

    申请号:DE59207493

    申请日:1992-12-10

    Applicant: BASF AG

    Abstract: Preparation of tertiary phosphines (I) by reducing the corresponding phosphine oxides (IIa) or phosphine dihalides (IIb), using silicon or a silicon alloy as reducing agent.

    14.
    发明专利
    未知

    公开(公告)号:DE4414090A1

    公开(公告)日:1995-10-26

    申请号:DE4414090

    申请日:1994-04-22

    Applicant: BASF AG

    Abstract: A process for the selective hydrogenation of compounds containing at least one aromatic group and epoxy group with hydrogen in the presence of a ruthenium-containing catalyst. The catalyst is a homogeneous ruthenium catalyst prepared by reduction of a ruthenium compound using a metal having a redox potential of -0.75 to -2.5 volts, a borohydride, aluminium hydride, aluminium alkyl compound, lithium alkyl or aryl-compound in the presence of an ether.

    20.
    发明专利
    未知

    公开(公告)号:AT146773T

    公开(公告)日:1997-01-15

    申请号:AT94104664

    申请日:1994-03-24

    Applicant: BASF AG

    Abstract: A process for preparing halomethylbenzoyl cyanides I Ph-CO-CNI (Ph=phenyl radical substituted by chloromethyl or bromomethyl which, if desired, can additionally carry 1-4 further radicals) by reacting halomethylbenzoyl chlorides II Ph-CO-ClII with an alkali metal cyanide or transition metal cyanide, if appropriate in an organic diluent, and novel halomethylbenzoyl cyanides I' I' (X=halogen, C1-C4-alkyl, C1-C4-alkoxy, CF3, C1-C5-alkyl-(C1-C5-alkyl)hydroxyimino or C1-C5-alkyl-(C2-C5-alkenyl)hydroxyimino; m=0 to 4 and Y=chloromethyl or bromomethyl) are described. The halomethylbenzoyl cyanides I are important intermediates for the synthesis of plant protection agents.

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