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公开(公告)号:GB962433A
公开(公告)日:1964-07-01
申请号:GB778461
申请日:1961-03-03
Applicant: BASF AG
Inventor: ZACHER WIELAND , EILBRACHT HANS , FRIEDENREICH HEINRICH , GOEBEL SIEBERT
Abstract: A colourless lubricant for gas compressors comprises a turbid suspension of 0.01% to 5% by weight of a hard wax (as defined in the Specification) containing polar groups, e.g. ester, amide or free acid groups, in a colourless lubricating oil, preferably paraffinum liquidum. The wax is montan wax, montan wax acid, montan wax esterified with an alcohol, e.g. ethylene glycol or butylene glycol, or a mixture of a montan wax acid and an ester of a higher alcohol. Calcium salts of montan wax acid may be added to the hard wax in amounts of 10, 20 or 30% by weight.
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公开(公告)号:GB1047957A
公开(公告)日:1966-11-09
申请号:GB3322063
申请日:1963-08-22
Applicant: BASF AG
Inventor: KINKEL KLAUS , PFANNMUELLER HELMUT , RODER PETER , ROTZOLL RUDI-HEINZ , TITTEL MANFRED , URBAN FREIDRICH , ZACHER WIELAND
IPC: C08F10/00 , C08F110/02
Abstract: Polyethylene of density 0.91 to 0.94 is produced by polymerization of ethylene at 150 DEG to 300 DEG C. and 1500 to 3000 atmospheres in a tubular reactor with oxygen as catalyst and in the presence of a chain transfer agent, wherein the reaction mixture is heated to 168 DEG to 174 DEG C. in the reactor and then heat is immediately extracted externally through the reactor wall by means of a coolant whose temperature does not exceed 170 DEG C., the temperature of the reaction mixture not falling below 168 DEG C. In examples, the cooling medium used is water under pressure and at 160-170 DEG C. The transfer agent may be hydrogen, a hydrocarbon, an alcohol, an ester, an acid anhydride, an aldehyde or a ketone. Sheet of good transparency may be obtained.
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公开(公告)号:GB1042303A
公开(公告)日:1966-09-14
申请号:GB15564
申请日:1964-01-02
Applicant: BASF AG
Inventor: TRIESCHMANN HANS GEORG , UNTERSTENHOEFER LEO , RODER PETER , ZACHER WIELAND , GUNDEL WOLFGANG
Abstract: Moulding material contains 30-95% bitumen and 5-70% of an ethylene copolymer. The bitumen has penetration 10-210 and may have R and B softening point of 37-72 DEG C., and may be asphaltic bitumen, petrolene, malthene, asphaltene or pyrobitumen, natural or obtained by petroleum distillation. The ethylene copolymer is of 30-97% ethylene and 70-3% vinyl ester or esters and/or copolymerizable acrylic and/or methacrylic compounds. Such compounds may be acrylic or methacrylic acids and their esters, and amides and nitriles which may bear substituents on the N atom. Many examples are given. Other ethylenically unsaturated compounds exemplified may additionally be present in the copolymer. The copolymers used have melt indices of 0.1-100. The moulding material may be applied molten to surfaces which are preferably preheated and which may be primed, e.g. with bitumen emulsion. Fillers, e.g. wood flour, carbon black, diatomaceous earth, kaolin, quartz powder, stone chips, sand, glass fibres, mineral wool, rubber powder, wool felt, jute, or synthetic fibres, may be present. A composition may contain, e.g. 5-70% by weight, with reference to bitumen and copolymer, of filler of particle diameter 0.01-0.09 mm.; or there may be present, with reference to the total weight of the composition, e.g. 4-10% bitumen, 2-10% copolymer, 6-20% mineral filler of particle diameter 0.01-0.09 mm., and 60-88% of mineral filler of particle diameter of 0.09-20 mm.
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公开(公告)号:FR1367928A
公开(公告)日:1964-07-24
申请号:FR946022
申请日:1963-08-29
Applicant: BASF AG
Inventor: KINKEL KLAUS , PFANNMUELLER HELMUT , RODER PETER , ROTZOLL RUDI-HEINZ , TITTEL MANFRED , URBAN FRIEDRICH , ZACHER WIELAND
IPC: C08F10/00 , C08F110/02
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15.
公开(公告)号:CA662725A
公开(公告)日:1963-05-07
申请号:CA662725D
Applicant: BASF AG
Inventor: ZACHER WIELAND , GOEBEL SIEBERT , EILBRACHT HANS
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公开(公告)号:FR1307600A
公开(公告)日:1962-10-26
申请号:FR881085
申请日:1961-12-06
Applicant: BASF AG
Inventor: EILBRACHT HANS , PFANNMUELLER HELMUT , ROTZOLL RUDI-HEINZ , URBAN FRIEDRICH , ZACHER WIELAND
IPC: C08F10/00
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公开(公告)号:FR1260460A
公开(公告)日:1961-05-05
申请号:FR830758
申请日:1960-06-22
Applicant: BASF AG
Inventor: EILBRACHT HANS , GOEBEL SIEBERT , ZACHER WIELAND
IPC: C08F10/00
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公开(公告)号:CA1100690A
公开(公告)日:1981-05-05
申请号:CA252137
申请日:1976-05-10
Applicant: BASF AG
Inventor: MIETZNER FRANZ G , PFLEGER KLAUS , GROPPER HANS , BUECHNER OSKAR , BOETTCHER KLAUS , ZACHER WIELAND
IPC: C08F6/00 , C08F6/06 , C08F6/26 , C08F10/00 , C08F210/00 , C08F210/02 , C08F218/00 , C08F218/02 , C08F2/00
Abstract: A process for the manufacture of copolymers of ethylene with vinyl acetate at pressures above 800 atmospheres and at from 150 to 350.degree.C, using mean residence times of up to at most 100 seconds. The reaction mixture obtained from the polymerization is kept for from 2 to 10 minutes at from 150 to 250.degree.C under a pressure below 500 atmospheres. Homogeneous ethylene/ vinyl acetate copolymers are obtained without the formation of substantial amounts of free acetic acid by decomposition of the vinyl acetate.
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公开(公告)号:CA1068448A
公开(公告)日:1979-12-18
申请号:CA270376
申请日:1977-01-21
Applicant: BASF AG
Inventor: BOETTCHER KLAUS , HOERDT HEINRICH G , ZACHER WIELAND , BUECHNER OSKAR
Abstract: A process for the high pressure polymerization of ethylene at elevated temperatures in a polymerization zone followed by transfer of the reaction mixture, through a cooling zone, into the separation zone. In this process, the pressure at the cooling zone outlet is perodically reduced briefly, at recurring intervals, these brief pressure reductions being independent of the pressure reductions in the polymerization zone. Using this process, the conversion in the polymerization unit can be increased and a more homogeneous ethylene polymer can be obtained.
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20.
公开(公告)号:CA730758A
公开(公告)日:1966-03-22
申请号:CA730758D
Applicant: BASF AG
Inventor: EILBRACHT HANS , ZACHER WIELAND , PFANNMUELLER HELMUT , URBAN FRIEDRICH
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