PYRAZOLYLDIOXOTHIOCHROMANOYL-DERIVATE
    11.
    发明公开
    PYRAZOLYLDIOXOTHIOCHROMANOYL-DERIVATE 有权
    PYRAZOLYLDIOXOTHIOCHROMANOYL衍生物

    公开(公告)号:EP1080089A1

    公开(公告)日:2001-03-07

    申请号:EP99924925.3

    申请日:1999-05-10

    CPC classification number: C07D409/06 A01N43/56 C07D409/14 C07F9/65586

    Abstract: The invention relates to pyrazolyldioxothiochromanoyl derivatives of formula (I) in which the variables have the following meanings: X represents oxygen, sulfur, S=O, S(=O)2, CR4R5, C=O or C=NR6; R1 hydrogen, nitro, halogen, cyano, alkyl, alkyl halide, alkoxy, alkoxy halide, alkyl thio, alkyl thio halide, alkyl sulfinyl, alkyl sulfinyl halide, alkyl sulfonyl, alkyl sulfonyl halide, optionally substituted amino sulfonyl or optionally substituted sulfonyl amino; R2 represents alkyl, alkyl halide, alkoxy or alkoxy halide; R3 represents hydrogen, alkyl or halogen; R4, R5 represent hydrogen, nitro, halogen, cyano, alkyl, alkyl halide, alkoxy, alkoxy halide, alkyl thio, alkyl thio halide, alkyl sulfinyl, alkyl sulfinyl halide, alkyl sulfonyl, alkyl sulfonyl halide or optionally substituted amino; or R?4 and R5¿ jointly construct a chain which can be substituted and/or discontinued by oxygen or sulfur; or an optionally substituted methylidene group; l represents 0 to 4; and R7 represents substituted pyrazole-4-yl-carbonyl or substituted pyrazole-4-yl-methylidene. The invention also relates to the salts of said derivatives which can be used for agricultural purposes, to a method for producing the pyrazolyldioxothiochromanoyl derivatives, to agents containing the same, and to the use of these derivatives or agents containing the same for controlling undesirable plants.

    VERFAHREN ZUR HERSTELLUNG VON PYRAZOLYLBENZOYLDERIVATEN SOWIE NEUE PYRAZOLYLBENZOYLDERIVATE

    公开(公告)号:EP1135386B1

    公开(公告)日:2003-04-02

    申请号:EP99966912.0

    申请日:1999-12-02

    CPC classification number: C07D409/06 C07D409/14

    Abstract: The invention relates to a method for producing pyrazolylbenzoyl derivatives of formula (I), wherein the substituents have the following meanings: R1 represents hydrogen, C¿1?-C4-alkyl or C1-C4 alkyl halide; R?2¿ represents hydrogen, C¿1?-C6-alkyl, C2-C6-alkenyl, C2-C6-alkinyl, benzyl, benzoyl, C1-C4-alkylcarbonyl, hydroxycarbonyl-C1-C4-alkyl, C1-C4-alkoxycarbonyl-C1-C4-alkyl, C1-C4-alkylsulfonyl or phenylsulfonyl, and these groups can be substituted by C1-C4-alkyl, C1-C4-alkoxy, C1-C4-alkylthio, halogen, hydroxy, amino, nitro or cyano; A,B represent, independently of each other, hydrogen, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkinyl, C1-C4-alkoxy and these groups can be substituted by halogen, hydroxy, C1-C4-alkoxy or cyano, halogen, hydroxy, cyano; nitro, a group-(Y)n-S(O)mR?3¿ or a group-(Y)¿n-CO-R?4; Z represents a 5- or 6-membered heterocyclic, saturated or unsaturated fused ring; Y represents O, NR5; n represents zero or one; m represents zero, one or two; R3 represents C¿1?-C4-alkyl, C1-C4-alkyl halide or NR?5R6; R4¿ represents C¿1?-C4-alkyl, C1-C4-alkyl halide, C1-C4-alkoxy, or NR?5R6; R5¿ represents hydrogen or C¿1?-C4-alkyl; and R?6¿ represents C¿1?-C4-alkyl. The invention also relates to novel pyrazolylbenzoyl derivatives, to herbicidal agents containing these derivatives and to a method for combating unwanted vegetation.

    Abstract translation: 本发明涉及制备式(I)的吡唑基苯甲酰基衍生物的方法,其中取代基具有以下含义:R 1表示氢,C 1 -C 4烷基或C 1 -C 4烷基卤化物; R 2代表氢,C 1 -C 6烷基,C 2 -C 6烯基,C 2 -C 6炔基,苄基,苯甲酰基,C 1 -C 4烷基羰基,羟基羰基-C 1 -C 4烷基, 烷氧基羰基-C1-C4-烷基,C1-C4-烷基磺酰基或苯基磺酰基,并且这些基团可以被C1-C4-烷基,C1-C4-烷氧基,C1-C4-烷硫基,卤素,羟基,氨基,硝基或氰基 ; A,B彼此独立地表示氢,C 1 -C 6烷基,C 2 -C 6烯基,C 2 -C 6炔基,C 1 -C 4烷氧基,并且这些基团可以被卤素,羟基,C 1 -C 4 - 烷氧基或氰基,卤素,羟基,氰基; 硝基,基团 - (Y)n -S(O)mR 3 3或基团 - (Y)n -CO-R 4。 Z表示5或6元杂环饱和或不饱和稠环; Y代表O,NR 5; n代表零或1; m表示零个,一个或两个; R 3代表C 1 -C 4烷基,C 1 -C 4烷基卤或NR 5 R 6; R 4代表C 1 -C 4烷基,C 1 -C 4烷基卤化物,C 1 -C 4烷氧基或NR 5 R 6; R5代表氢或C1-C4烷基; R 6'代表C 1 -C 4烷基。 本发明还涉及新的吡唑基苯甲酰基衍生物,含有这些衍生物的除草剂以及用于防治不想要的植物的方法。

    3-(4,5-DIHYDROISOXAZOL-5-YL)BENZOYLCYCLOHEXENONE UND IHRE VERWENDUNG ALS HERBIZIDE
    14.
    发明公开
    3-(4,5-DIHYDROISOXAZOL-5-YL)BENZOYLCYCLOHEXENONE UND IHRE VERWENDUNG ALS HERBIZIDE 有权
    3-(4,5-二氢嘧啶-5-基)BENZOYLCYCLOHEXENONE及其作为除草剂

    公开(公告)号:EP1284969A1

    公开(公告)日:2003-02-26

    申请号:EP01936353.0

    申请日:2001-05-11

    CPC classification number: A01N43/80 C07D261/04 C07D261/20

    Abstract: The invention relates to 3-(4,5-dihydroisoxazole-5-yl)benzoylcyclohexenones of the general formula (I), wherein the variables have the following meanings: R1, R2 represents hydrogen, nitro, halogen, cyano, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, haloalkylthio, alkylsulfinyl, haloalkylsulfinyl, alkylsulfonyl or C¿1?-C6 haloalkylsulfonyl; R?3¿ represents hydrogen, halogen or alkyl; R4 represents hydrogen or alkyl; R5, R6 represents hydrogen, halogen, cyano, nitro, alkyl, alkoxy, alkylthio, dialkylamino, phenyl, benzyl or carbonyl, wherein the 7 last residues can be substituted; R11 represents optionally substituted cyclohexenone that is linked in the 2 position and that carries a hydroxy residue or derivatives thereof in the 1 position. The invention further relates to the agriculturally useful salts thereof, to methods for producing the 3-(4,5-dihydroisoxazole-5-yl)benzoylcyclohexenones, to agents that contain the inventive compound, and to the use of said derivatives or agents containing them for controlling undesired plants.

    3-(4,5-DIHYDROISOXAZOL-5-YL)BENZOYLCYCLOHEXENONE UND IHRE VERWENDUNG ALS HERBIZIDE
    20.
    发明授权
    3-(4,5-DIHYDROISOXAZOL-5-YL)BENZOYLCYCLOHEXENONE UND IHRE VERWENDUNG ALS HERBIZIDE 有权
    3-(4,5-二氢嘧啶-5-基)BENZOYLCYCLOHEXENONE及其作为除草剂

    公开(公告)号:EP1284969B1

    公开(公告)日:2004-08-18

    申请号:EP01936353.0

    申请日:2001-05-11

    CPC classification number: A01N43/80 C07D261/04 C07D261/20

    Abstract: The invention relates to 3-(4,5-dihydroisoxazole-5-yl)benzoylcyclohexenones of the general formula (I), wherein the variables have the following meanings: R1, R2 represents hydrogen, nitro, halogen, cyano, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, haloalkylthio, alkylsulfinyl, haloalkylsulfinyl, alkylsulfonyl or C¿1?-C6 haloalkylsulfonyl; R?3¿ represents hydrogen, halogen or alkyl; R4 represents hydrogen or alkyl; R5, R6 represents hydrogen, halogen, cyano, nitro, alkyl, alkoxy, alkylthio, dialkylamino, phenyl, benzyl or carbonyl, wherein the 7 last residues can be substituted; R11 represents optionally substituted cyclohexenone that is linked in the 2 position and that carries a hydroxy residue or derivatives thereof in the 1 position. The invention further relates to the agriculturally useful salts thereof, to methods for producing the 3-(4,5-dihydroisoxazole-5-yl)benzoylcyclohexenones, to agents that contain the inventive compound, and to the use of said derivatives or agents containing them for controlling undesired plants.

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