中科微点-全球专利检索

  1. Login
  2. Sign Up

Search Results

19 records (took 0.026 seconds)

    HERSTELLUNG VON POLYMEREN DURCH KONTROLLIERTE RADIKALISCHE POLYMERISATION
    14.
    发明公开
    HERSTELLUNG VON POLYMEREN DURCH KONTROLLIERTE RADIKALISCHE POLYMERISATION 审中-公开
    聚合物通过受控的自由基聚合生产

    公开(公告)号：EP2751143A1

    公开(公告)日：2014-07-09

    申请号：EP12753968.2

    申请日：2012-08-30

    Applicant: BASF SE

    Inventor： HESSE, Pascal ,  FLEISChmann, Sven ,  BECKER, Florian ,  MÜHLBACH, Klaus ,  HUNGENBERG, Klaus-Dieter ,  BRYM, Markus ,  KLEINER, Matthias

    IPC: C08F4/10 ,  C08F4/40 ,  C08F293/00 ,  C08F297/00

    CPC classification number: C08F2/01 ,  C08F2/38 ,  C08F4/40 ,  C08F220/14 ,  C08F293/005 ,  C08F2220/1825 ,  C08F2438/01 ,  C08F2438/02

    Abstract: Method for producing polymers by means of controlled radical polymerisation, wherein the polymerisation of one or several radically polymerisable monomers of general formula (I), where R
    1 , R
    2 , R
    3 are H, C
    1 -C
    4 alkyl, R
    4 is C(=O)OR
    5 , C(=O)NHR
    15 , C(=O)NR
    5 R
    6 , OC(=O)CH
    3 , C(=O)OH, CN, aryl, hetaryl, C(=O)OR
    5 OH, C(=O)OR
    5 Si(OR
    5 )
    3 , halogen, NHC(O)H, P(=O)(OR
    7 )
    2 , R
    5 is C
    1 -C
    20 alkyl, R
    15 is C
    1 -C
    20 -alkyl, R
    6 is C
    1 -C
    20 alkyl, and R
    7 is H, C
    1 -C
    20 alkyl, occurs in the presence of a. one or several catalysts containing Cu in the form of Cu(0), Cu(l), Cu (II) or mixtures thereof, b. one or several initiators selected from the group of organic halogenides or pseudohalogenides, c. one or several ligands, d. optionally one or several solvents, and e. optionally one or several inorganic halogenide salts, said method consisting of the following steps i) addition of the catalyst a., ii) optional addition of monomers of general formula (I), iii) optional addition of solvent d., iv) addition of ligand c., v) addition of initiator b., vi) addition of monomers of general formula (I), and vii) optional addition of inorganic halogenide salts e., on the proviso that the addition of at least some of the monomers of general formula (I) occurs immediately before or shortly after the last of the steps i), iv) and v).

    REVERSE-PHASE POLYMERISATION PROCESS
    15.
    发明公开
    REVERSE-PHASE POLYMERISATION PROCESS 审中-公开
    UMKEHRPHASEN-POLYMERISATIONSPROZESS

    公开(公告)号：EP3027662A1

    公开(公告)日：2016-06-08

    申请号：EP14747573.5

    申请日：2014-07-29

    Applicant: BASF SE

    Inventor： HASCHICK, Robert ,  JELICIC, Aleksandra ,  BARRATT, John Scott ,  HESSE, Pascal ,  SOETJE, Oliver ,  FONSECA ZEPEDA, Gabriela Eugenia ,  KEELAPANDAL RAMAMOORTHY, Shankara Narayanan ,  LANGLOTZ, Björn

    IPC: C08F2/32 ,  C08F20/56

    CPC classification number: C08F220/56 ,  B01J19/123 ,  B01J19/24 ,  B01J2219/0869 ,  B01J2219/1203 ,  B01J2219/24 ,  C08F2/32 ,  C08F220/06 ,  C08F220/20 ,  C08F226/10 ,  C08F2220/382 ,  C08F2220/385 ,  C08F220/34

    Abstract: A reverse-phase suspension polymerisation process for the manufacture of polymer beads comprising forming aqueous monomer beads comprising an aqueous solution of water-soluble ethylenically unsaturated monomer or monomer blend and polymerising the monomer or monomer blend to form polymer beads while suspended in a non-aqueous liquid, and recovering polymer beads, in which the process comprises, providing in a vessel (1) a volume (2) of non-aqueous liquid wherein the volume of non-aqueous liquid extends between at least one polymer bead discharge point (3) and at least one monomer feed point (4), feeding the aqueous monomer or monomer blend through orifices (5) into, or onto, the non-aqueous liquid to form aqueous monomer beads, allowing the aqueous monomer beads to flow towards the polymer bead discharge point subjecting the aqueous monomer beads to polymerisation conditions to initiate polymerisation to form polymerising beads, wherein the polymerising beads have formed polymer beads when they reach the polymer bead discharge point, removing a suspension of the polymer beads in non-aqueous liquid from the vessel at the polymer bead discharge point and recovering water soluble or water swellable polymer beads from the suspension. The invention also relates to the apparatus suitable for carrying out a reverse-phase suspension polymerisation and polymer beads obtainable by the process or employing the apparatus.

    Abstract translation: 一种用于制备聚合物珠粒的反相悬浮聚合方法，其包括形成包含水溶性烯属不饱和单体或单体共混物的水溶液的含水单体珠粒，并将单体或单体共混物聚合以形成聚合物珠粒，同时悬浮在非水性 液体和回收的聚合物珠粒，其中该方法包括在容器（1）中提供非水性液体的体积（2），其中非水性液体的体积在至少一个聚合物珠粒排出点（3） 和至少一个单体进料点（4），通过孔口（5）将含水单体或单体共混物进料到非水性液体中或其上，以形成含水单体珠粒，使含水单体珠流向聚合物珠粒 排出点使含水单体珠粒聚合条件以引发聚合以形成聚合珠粒，其中聚合珠粒已形成聚合物珠粒 当它们到达聚合物珠粒排放点时，在聚合物珠粒排放点处从容器中除去聚合物小珠在非水性液体中的悬浮液，并从悬浮液中回收水溶性或水可溶胀聚合物珠粒。 本发明还涉及适用于进行反相悬浮聚合的装置和通过该方法或使用该装置可获得的聚合物珠。

    REVERSE-PHASE POLYMERISATION PROCESS
    16.
    发明公开
    REVERSE-PHASE POLYMERISATION PROCESS 审中-公开
    反相聚合

    公开(公告)号：EP3027660A1

    公开(公告)日：2016-06-08

    申请号：EP14744355.0

    申请日：2014-07-29

    Applicant: BASF SE

    Inventor： HESSE, Pascal ,  JELICIC, Aleksandra ,  FONSECA ZEPEDA, Gabriela Eugenia ,  HASCHICK, Robert ,  KEELAPANDAL RAMAMOORTHY, Shankara Narayanan ,  NAYLOR, Gareth Ian ,  BARRATT, John Scott ,  SOETJE, Oliver ,  LIEVRE, Marcel ,  RAINAU, Florian ,  LEBKÜCHER, Mark

    IPC: C08F2/32 ,  C08F20/56

    CPC classification number: C08F2/32 ,  B01J19/10 ,  B01J2219/0888 ,  B01J2219/24 ,  C08F2/01 ,  C08F220/06 ,  C08F220/20 ,  C08F220/56 ,  C08F226/10 ,  C08F2220/382 ,  C08F2220/385 ,  C08F220/34

    Abstract: A reverse-phase suspension polymerisation process for the manufacture of polymer beads comprising forming aqueous monomer beads comprising an aqueous solution of water-soluble ethylenically unsaturated monomer or monomer blend and polymerising the monomer or monomer blend, to form polymer beads while suspended in a non-aqueous liquid, and recovering polymer beads, in which the process comprises providing in a vessel (1) a volume (2) of non-aqueous liquid wherein the volume of non-aqueous liquid extends between at least one polymer bead discharge point (3) and at least one monomer feed point (4), feeding the aqueous monomer or monomer blend through orifices (5) into, or onto, the non-aqueous liquid to form aqueous monomer beads, allowing the aqueous monomer beads to flow towards the polymer bead discharge point initiating polymerisation of the aqueous monomer beads to form polymerising beads, wherein the polymerising beads form polymer beads when they reach the polymer bead discharge point, removing a suspension of the polymer beads in non-aqueous liquid from the vessel at the polymer bead discharge point and recovering, water soluble or water swellable polymer beads from the suspension, in which the aqueous monomer or monomer blend and/or the orifices is/are vibrated such that the frequency multiplied by the weight average droplet diameter is between 150 and 800 mm/s. The invention also relates to the apparatus suitable for carrying out a reverse-phase suspension polymerisation and polymer beads obtainable by the process or employing the apparatus. Furthermore, the invention also relates to polymer beads having a weight mean particle size in the range of 0.05 to 5 mm which are held in a container in an amount of at least 300 kg having a standard deviation of particle size less than 20%. In addition, the invention also provides polymer beads having a weight mean particle size in the range 0.05 to 5 mm having a standard deviation of particle size less than 20% and having an amount of residual acrylamide of less than 500 ppm.

    REVERSE-PHASE POLYMERISATION PROCESS
    18.
    发明公开
    REVERSE-PHASE POLYMERISATION PROCESS 审中-公开
    反相聚合工艺

    公开(公告)号：EP3027661A1

    公开(公告)日：2016-06-08

    申请号：EP14744840.1

    申请日：2014-07-29

    Applicant: BASF SE

    Inventor： BARRATT, John Scott ,  JELICIC, Aleksandra ,  HESSE, Pascal ,  SOETJE, Oliver ,  HASCHICK, Robert ,  FONSECA ZEPEDA, Gabriela Eugenia ,  KEELAPANDAL RAMAMOORTHY, Shankara Narayanan ,  JECK, Sandra ,  KUHN, Jelan

    IPC: C08F2/32 ,  B01D29/00 ,  C08F20/56 ,  C08J11/02

    CPC classification number: C08F265/04 ,  B01D29/00 ,  B01J19/24 ,  B01J2219/24 ,  C08F2/32 ,  C08F220/06 ,  C08F220/20 ,  C08F220/56 ,  C08F226/10 ,  C08F2220/382 ,  C08F2220/385 ,  C08J3/12 ,  C08J11/02 ,  C08J2351/00 ,  C08F220/34

    Abstract: A reverse-phase suspension polymerisation process for the manufacture of polymer beads comprising forming aqueous monomer beads of an aqueous solution comprising water-soluble ethylenically unsaturated monomer or monomer blend and polymerising the monomer or monomer blend to form polymer beads while suspended in a non-aqueous liquid, recovering polymer beads, and then cleaning the non-aqueous liquid in which the process comprises providing the non-aqueous liquid in a vessel (1), forming a suspension of monomer beads from the aqueous monomer or monomer blend in the non-aqueous liquid, initiating polymerisation to form polymerising beads, removing a suspension of the polymer beads in non-aqueous liquid from the vessel and recovering, water soluble or water swellable polymer beads from the suspension, in which the non-aqueous liquid contains impurities which comprise particles, and then transferring the non-aqueous liquid from the suspension to a cleaning stage, in which the cleaning stage provides a cleaned non-aqueous liquid suitable for use in a reverse-phase suspension polymerisation process, which cleaning stage comprises removing particles from the non-aqueous liquid in at least one filtration step. The invention also relates to the apparatus suitable for carrying out a reverse-phase suspension polymerisation and polymer beads obtainable by the process or employing the apparatus. The invention further relates to a cleaned non-aqueous liquid obtainable by the process.

    Abstract translation: 用于制造聚合物珠粒的反相悬浮聚合方法包括形成包含水溶性烯属不饱和单体或单体共混物的水溶液的含水单体珠粒，并将单体或单体共混物聚合以形成聚合物珠粒，同时将其悬浮于非水 液体，回收聚合物珠粒，然后清洗非水液体，其中该方法包括在容器（1）中提供非水液体，由含水单体或单体混合物形成单体珠粒悬浮于非水溶液 液体，引发聚合形成聚合珠粒，从容器中除去聚合物珠粒在非水液体中的悬浮液，并从悬浮液中回收水溶性或水溶胀性聚合物珠粒，其中非水液体含有包含颗粒 ，然后将非水液体从悬浮液转移到清洁阶段，其中清洁阶段 e提供适用于反相悬浮聚合工艺的清洁过的非水液体，该清洁阶段包括在至少一个过滤步骤中从非水液体中除去颗粒。 本发明还涉及适用于进行反相悬浮聚合的设备和可通过该方法或使用该设备获得的聚合物珠粒。 本发明还涉及通过该方法可获得的清洁过的非水液体。

Patent Agency Ranking