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    HERSTELLUNG VON POLYMEREN DURCH KONTROLLIERTE RADIKALISCHE POLYMERISATION
    1.
    发明申请
    HERSTELLUNG VON POLYMEREN DURCH KONTROLLIERTE RADIKALISCHE POLYMERISATION 审中-公开
    聚合物通过受控的自由基聚合生产

    公开(公告)号：WO2013030261A1

    公开(公告)日：2013-03-07

    申请号：PCT/EP2012/066838

    申请日：2012-08-30

    Applicant: BASF SE ,  HESSE, Pascal ,  FLEISChmann, Sven ,  BECKER, Florian ,  MÜHLBACH, Klaus ,  HUNGENBERG, Klaus-Dieter ,  BRYM, Markus ,  KLEINER, Matthias

    Inventor： HESSE, Pascal ,  FLEISChmann, Sven ,  BECKER, Florian ,  MÜHLBACH, Klaus ,  HUNGENBERG, Klaus-Dieter ,  BRYM, Markus ,  KLEINER, Matthias

    IPC: C08F4/10 ,  C08F4/40 ,  C08F293/00 ,  C08F297/00

    CPC classification number: C08F2/01 ,  C08F2/38 ,  C08F4/40 ,  C08F220/14 ,  C08F293/005 ,  C08F2220/1825 ,  C08F2438/01 ,  C08F2438/02

    Abstract: Verfahren zur Herstellung von Polymeren durch kontrollierte radikalische Polymerisation, wobei die Polymerisation eines oder mehrerer radikalisch polymerisierbarer Momomere der allgemeinen Formel (I) mit R 1 , R 2 , R 3 H, C 1 -C 4 -Alkyl, R 4 C(=0)OR 5 , C(=0)NHR 15 , C(=0)NR 5 R 6 , OC(=0)CH 3 , C(=0)OH, CN, Aryl, Hetaryl, C(=0)OR 5 OH, C(=0)OR 5 Si(OR 5 ) 3 , Halogen, NHC(0)H, P(=0)(OR 7 ) 2 , R 5 C 1 -C 20 -Alkyl, R 15 C 1 -C 20 -Alkyl, R 6 C 1 -C 20 -Alkyl, R 7 H, C 1 -C 20 -Alkyl, in Gegenwart a. eines oder mehrerer Katalysatoren enthaltend Cu in Form von Cu(0), Cu(l), Cu (II) oder Mischungen aus diesen, b. eines oder mehrerer Initiatoren gewählt aus der Gruppe der organischen Halogenide oder Pseudohalogenide, c. eines oder mehrer Liganden, d. optional eines oder mehrer Lösungsmittel, e. optional eines oder mehrerer anorganischer Halogenidsalze, erfolgt, umfassend die Schritte i) Zugabe des Katalysators a., ii) optional Zugabe von Monomeren der allgemeinen Formel (I), iii) optional Zugabe von Lösungsmittel d., iv) Zugabe von Ligand c, v) Zugabe von Initiator b., vi) Zugabe von Monomeren der allgemeinen Formel (I), vii) optional Zugabe anorganischer Halogenidsalze e., unter der Maßgabe, dass die Zugabe zumindest eines Teiles der Monomeren der allgemeinen Formel (I) unmittelbar vor oder kurz nach dem letzten der Schritte i), iv) und v) erfolgt.

    Abstract translation: 一种通过受控的自由基聚合制备的聚合物，其中一个或多个可自由基聚合的Momomere通式（I）的R1，R2的聚合中，R 3是H，C1-C4烷基过程中，R 4为C（= O）OR 5，C（= 0）NHR15，-C（= O）NR 5 R 6，OC（= O）CH 3，C（= O）OH，CN，芳基，杂芳基，C（= O）OR5OH，C（= O）OR5Si（OR 5）3，卤素 ，NHC（O）H，P（= O）（OR 7）2，R 5的C1-C20烷基，R15 C 1 -C 20烷基，R 6 C 1 -C 20烷基，R 7是H，C1-C20烷基，在一个存在 ， 含Cu量在Cu的形式的一种或多种催化剂（0），铜（I），铜（II）或它们的混合物，B。 选自有机卤化物或拟卤化物，C中的一种或多种引发剂。 一个或多个配体，D。 任选的一种或多种溶剂，例如 ，是任选的一种或多种无机卤化物盐，其包含i的添加催化剂，步骤a）一个，ii）任选地加入上述通式（I）的单体，iii）任选地加入溶剂天。，IV）另外配位体C的，V ）添加引发剂b的。，ⅵ）除了通式（I）的单体的，VII）任选地添加无机卤化物盐即，其条件是在加入通式（I的单体的至少一部分的前立即或不久） 在最后的步骤i发生时），iv）和v）中。

    METHOD FOR PREPARING AN AQUEOUS ACRYLAMIDE SOLUTION HAVING A LOW ACRYLIC ACID CONCENTRATION
    3.
    发明申请
    METHOD FOR PREPARING AN AQUEOUS ACRYLAMIDE SOLUTION HAVING A LOW ACRYLIC ACID CONCENTRATION 审中-公开
    制备具有低丙烯酸浓度的水性丙烯酰胺溶液的方法

    公开(公告)号：WO2016050818A1

    公开(公告)日：2016-04-07

    申请号：PCT/EP2015/072508

    申请日：2015-09-30

    Applicant: BASF SE

    Inventor： BRAUN, Michael ,  DAEUWEL, Juergen ,  LANG, Hans-Juergen ,  OEDMAN, Peter ,  BALDENIUS, Kai-Uwe ,  KLEINER, Matthias ,  KIEFER, Michael ,  FREYER, Stephan ,  BUDDE, Michael

    IPC: C12P13/02

    CPC classification number: C12P13/02 ,  C07C233/09 ,  C08F20/56 ,  C08L33/26 ,  C08L2201/54 ,  C09K8/588 ,  C12Y402/01084 ,  D21H17/375

    Abstract: The present invention relates to methods for preparing an aqueous acrylamide solution having a low acrylic acid concentration. In addition, the present invention relates to methods for reducing the acrylic acid concentration of an aqueous acrylamide solution. The methods involve a bioconversion of acrylonitrile to acrylamide in the presence of a biocatalyst, wherein during the bioconversion the content of acrylonitrile is maintained at 0.3 w/w % or more referred to the total weight of the composition in the reactor. Also provided is an aqueous acrylamide solution which is obtained by the methods of the present invention. Furthermore, the present invention is related to an acrylamide homopolymer or copolymer obtained by polymerizing the acrylamide of the aqueous solution.

    Abstract translation: 本发明涉及制备丙烯酸浓度低的丙烯酰胺水溶液的方法。 此外，本发明涉及降低丙烯酰胺水溶液的丙烯酸浓度的方法。 所述方法涉及在生物催化剂存在下将丙烯腈生物转化为丙烯酰胺，其中在生物转化期间，丙烯腈的含量维持在反应器中组合物总重量的0.3w / w％以上。 还提供了通过本发明的方法获得的丙烯酰胺水溶液。 此外，本发明涉及通过聚合水溶液的丙烯酰胺而获得的丙烯酰胺均聚物或共聚物。

    VERFAHREN ZUR HERSTELLUNG VON POLYISOBUTENEN
    4.
    发明申请
    VERFAHREN ZUR HERSTELLUNG VON POLYISOBUTENEN 审中-公开
    用于生产聚异丁烯

    公开(公告)号：WO2014056845A1

    公开(公告)日：2014-04-17

    申请号：PCT/EP2013/070825

    申请日：2013-10-07

    Applicant: BASF SE

    Inventor： LANGE, Arno ,  KIEFER, Matthias ,  KLEINER, Matthias ,  CSIHONY, Szilard ,  POSSELT, Dietmar

    IPC: C08F110/10 ,  C08F4/00

    CPC classification number: C08F110/10 ,  C08F8/00 ,  C08F10/10 ,  C08F4/12 ,  C08F4/06 ,  C08F4/00

    Abstract: Herstellung von bifunktionellen Polyisobutenen, bei dem man Isobuten oder ein Isobutenhaltiges Monomerengemisch in Gegenwart einer Lewis-Säure und einer Verbindung der Formel (I), worin X für einen Acylrest oder den Rest einer organischen oder anorganischen Säuregruppe steht, R 1 bis R 4 gleich oder verschieden sind und für Wasserstoff oder einen Kohlenwasserstoffrest stehen, polymerisiert.

    Abstract translation: 双官能的聚异丁烯，该方法包括聚合异丁烯或在路易斯酸的存在下和通式（I），其中X是一个酰基基团或一种有机或无机酸基团的残基的化合物的异丁烯单体混合物的制备中，R1〜R4为相同或不同 并且是氢或烃基聚合。

    MEANS AND METHODS FOR PRODUCING AN AMIDE COMPOUND
    5.
    发明申请
    MEANS AND METHODS FOR PRODUCING AN AMIDE COMPOUND 审中-公开
    用于生产酰胺化合物的方法和方法

    公开(公告)号：WO2017055518A1

    公开(公告)日：2017-04-06

    申请号：PCT/EP2016/073372

    申请日：2016-09-29

    Applicant: BASF SE

    Inventor： BRAUN, Michael Guenter ,  DAEUWEL, Juergen ,  OEDMAN, Peter ,  KIEFER, Michael ,  KLEINER, Matthias ,  LANG, Hans-Juergen ,  GHISLIERI, Diego

    IPC: C12P13/02 ,  C08F20/52

    CPC classification number: C12P13/02

    Abstract: The present disclosure relates to methods for producing an amide compound from a nitrile compound using a dried biocatalyst which has been pre-treated with a buffer, wherein the dried and pre-treated biocatalyst has improved properties as compared to a dried biocatalyst which has not been pre-treated with a buffer. In particular, the present disclosure provides means and methods to enhance the NHase activity of a dried biocatalyst for use in the production of amide compounds from nitrile compounds in aqueous solutions thereby improving the bioconversion process.

    Abstract translation: 本公开涉及使用已经用缓冲液进行预处理的干燥生物催化剂从腈化合物制备酰胺化合物的方法，其中干燥和预处理的生物催化剂与未被干燥的生物催化剂相比具有改善的性能 用缓冲液预处理。 特别地，本公开提供了用于增强用于在水溶液中由腈化合物生产酰胺化合物的干燥生物催化剂的NHase活性的方法和方法，从而改进了生物转化过程。

    METHOD FOR PREPARING AN AQUEOUS (METH) ACRYLAMIDE SOLUTION
    7.
    发明申请
    METHOD FOR PREPARING AN AQUEOUS (METH) ACRYLAMIDE SOLUTION 审中-公开

    公开(公告)号：WO2023041515A2

    公开(公告)日：2023-03-23

    申请号：PCT/EP2022/075377

    申请日：2022-09-13

    Applicant: BASF SE

    Inventor： DAEUWEL, Juergen ,  BRAUN, Michael Guenter ,  OEDMAN, Peter ,  LANG, Hans-Juergen ,  KLEINER, Matthias ,  GHISLIERI, Diego

    IPC: C12M1/26 ,  C07C231/24 ,  C08F220/56 ,  C12P13/02

    Abstract: The invention provides a method for preparing an aqueous (meth)acrylamide solution, said method comprising the following steps: (a) adding the following components (i) to (iii) to a reactor to obtain a composition for bioconversion: (i) a biocatalyst capable of converting (meth) acrylonitrile to (meth) acrylamide; (ii) (meth) acrylonitrile; and (iii) water; (b) performing a bioconversion on the composition obtained in step (a) as a reaction mixture in the reactor to obtain a crude aqueous (meth) acrylamide solution; and (c) passing the crude aqueous solution through at least one filter to provide a purified aqueous (meth) acrylamide solution, wherein at least one filter of step (c) has a nominal retention rating, with at least 90% efficiency, of from 4 to 22 μm. The invention further provides an apparatus for manufacturing aqueous (meth) acrylamide solution according to the inventive method. The method comprises a bioconversion unit; a supply of (meth) acrylonitrile; a supply of biocatalyst; and a supply of water. The apparatus comprises at least one filter for purifying crude aqueous (meth) acrylamide solution, which at least one filter has a nominal retention rating, with at least 90% efficiency, of 4 to 22 μm. The invention also covers aqueous (meth) acrylamide solution obtainable by the aforesaid inventive method, polymers made therefrom, and the use of aqueous solutions of said polymers for mining applications or oil field applications.

    METHOD FOR PREPARING AN ACRYLAMIDE SOLUTION HAVING A LOW ACRYLIC ACID CONCENTRATION
    9.
    发明申请
    METHOD FOR PREPARING AN ACRYLAMIDE SOLUTION HAVING A LOW ACRYLIC ACID CONCENTRATION 审中-公开
    制备具有低丙烯酸浓度的丙烯酰胺溶液的方法

    公开(公告)号：WO2016050819A1

    公开(公告)日：2016-04-07

    申请号：PCT/EP2015/072509

    申请日：2015-09-30

    Applicant: BASF SE

    Inventor： BRAUN, Michael ,  DAEUWEL, Juergen ,  FELGENHAUER, Katja ,  OEDMAN, Peter ,  BALDENIUS, Kai-Uwe ,  FREYER, Stephan ,  BUDDE, Michael ,  KLEINER, Matthias

    IPC: C12P13/02

    CPC classification number: C12P13/02

    Abstract: The present invention relates to methods for preparing an aqueous acrylamide solution having a low acrylic acid concentration. In addition, the present invention relates to methods for reducing the acrylic acid concentration of an aqueous acrylamide solution. The methods involve a bioconversion of acrylonitrile to acrylamide in the presence of a biocatalyst. In these methods a biocatalyst is employed which is contacted with urea. Also provided is an aqueous acrylamide solution which is obtained by the methods of the present invention. Furthermore, the present invention is related to an acrylamide homopolymer or copolymer obtained by polymerizing the acrylamide of the aqueous solution. The present invention also relates to the use of urea in the preparation of an aqueous acrylamide solution by a bio-based process where acrylonitrile is converted to acrylamide using a biocatalyst.

    Abstract translation: 本发明涉及制备丙烯酸浓度低的丙烯酰胺水溶液的方法。 此外，本发明涉及降低丙烯酰胺水溶液的丙烯酸浓度的方法。 该方法涉及在生物催化剂存在下将丙烯腈生物转化为丙烯酰胺。 在这些方法中，使用与尿素接触的生物催化剂。 还提供了通过本发明的方法获得的丙烯酰胺水溶液。 此外，本发明涉及通过聚合水溶液的丙烯酰胺而获得的丙烯酰胺均聚物或共聚物。 本发明还涉及尿素在通过基于生物的方法制备丙烯酰胺水溶液中的用途，其中使用生物催化剂将丙烯腈转化为丙烯酰胺。

    METHOD FOR PRODUCING ACRYLAMIDE FROM ACRYLONITRILE IN AN AQUEOUS SOLUTION
    10.
    发明申请
    METHOD FOR PRODUCING ACRYLAMIDE FROM ACRYLONITRILE IN AN AQUEOUS SOLUTION 审中-公开
    在水溶液中由丙烯酸生产丙烯酰胺的方法

    公开(公告)号：WO2016050817A1

    公开(公告)日：2016-04-07

    申请号：PCT/EP2015/072507

    申请日：2015-09-30

    Applicant: BASF SE

    Inventor： BRAUN, Michael ,  DAEUWEL, Juergen ,  OEDMAN, Peter ,  BUDDE, Michael ,  BALDENIUS, Kai-Uwe ,  KLEINER, Matthias ,  FREYER, Stephan ,  KIEFER, Michael ,  LANG, Hans-Juergen

    IPC: C12P13/02

    CPC classification number: C12P13/02 ,  C12Y402/01084

    Abstract: The present invention relates to methods for producing acrylamide from acrylonitrile in an aqueous solution with a Nitrile hydratase (NHase) producing microorganism in the presence of a saccharide. The present invention further relates to methods for reducing the amount of acrylic acid which is generated while producing acrylamide from acrylonitrile in an aqueous solution with the help of microorganisms. The methods of the present invention are further capable of reducing the reaction time necessary to convert acrylonitrile into acrylamide with a Nitrile hydratase (NHase) producing microorganism in an aqueous solution and of increasing the reaction rate of acrylonitrile into acrylamide mediated by a Nitrile hydratase (NHase) producing microorganism in an aqueous solution.

    Abstract translation: 本发明涉及在糖类存在下，在含有腈水解酶（NHase）的微生物的水溶液中由丙烯腈生产丙烯酰胺的方法。 本发明还涉及减少在微生物的帮助下在水溶液中由丙烯腈制备丙烯酰胺时产生的丙烯酸的量的方法。 本发明的方法还能够减少在水溶液中用腈水解酶（NHase）生成的微生物将丙烯腈转化为丙烯酰胺所需的反应时间，并且将丙烯腈的反应速率提高到腈水解酶（NHase）介导的丙烯酰胺中 ）在水溶液中产生微生物。

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