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    MULTISTAGE PROCESS FOR COMBUSTING FUEL MIXTURES
    11.
    发明申请
    MULTISTAGE PROCESS FOR COMBUSTING FUEL MIXTURES 审中-公开
    燃烧混合物的多种方法

    公开(公告)号：WO1992009849A1

    公开(公告)日：1992-06-11

    申请号：PCT/US1991008917

    申请日：1991-11-26

    Applicant: CATALYTICA, INC. ,  TANAKA KIKINZOKU KOGYO K.K. ,  DALLA BETTA, Ralph, A. ,  TSURUMI, Kazunori ,  EZAWA, Nobuyasu ,  SCHLATTER, James, C. ,  NICKOLAS, Sarento, G.

    Inventor： CATALYTICA, INC. ,  TANAKA KIKINZOKU KOGYO K.K. ,  DALLA BETTA, Ralph, A.

    IPC: F23D14/18

    CPC classification number: F23C13/00 ,  F23C6/045 ,  F23C2900/13002

    Abstract: This invention is a combustion process having a series of stages in which a fuel/oxygen-gas-containing mixture (16, 18) is combusted stepwise using a series of specific catalysts and catalytic structures (figure 2) and, optionally, a final homogeneous combustion zone to produce a combusted gas at a selected temperature preferably between 1050 DEG and 1700 DEG C. Depending upon the pressure of operation, there may be two or three discrete catalytic stages (stages 1, 2 and 3). The choice of catalysts and the use of specific structures, including those employing integral heat exchange (44) results in a catalyst and its support which are stable due to their comparatively low temperature, do not deteriorate, and yet the product combustion gas is at a temperature suitable for use in a gas turbine, furnace, boiler, or the like, but has low NOx content. Neither fuel nor air is added to the combustion process except in the initial stage.

    Abstract translation: 本发明是具有一系列阶段的燃烧方法，其中含燃料/含氧气体的混合物（16,18）使用一系列特定催化剂和催化结构（图2）和任选的最终均匀的 燃烧区以在选定温度下优选在1050℃和1700℃之间产生燃烧气体。根据操作压力，可以存在两个或三个离散的催化级（级1,2和3）。 催化剂的选择和特定结构的使用，包括采用整体热交换（44）的结构，导致催化剂及其载体由于其相对较低的温度而稳定，不劣化，而产物燃烧气体为 温度适用于燃气轮机，炉，锅炉等，但NOx含量低。 除了初始阶段以外，燃烧过程都不加燃料和空气。

    NOx SENSOR ASSEMBLY
    14.
    发明申请
    NOx SENSOR ASSEMBLY 审中-公开
    NOx传感器总成

    公开(公告)号：WO1991019975A1

    公开(公告)日：1991-12-26

    申请号：PCT/US1991004177

    申请日：1991-06-12

    Applicant: CATALYTICA, INC. ,  WHEELOCK, E., Thomas

    Inventor： CATALYTICA, INC. ,  WHEELOCK, E., Thomas ,  DALLA BETTA, Ralph, D. ,  REED, Daniel, L. ,  SCHUBERT, Priscilla

    IPC: G01N33/00

    CPC classification number: G01N33/0037 ,  F02B1/04 ,  G01N25/30 ,  Y02A50/245

    Abstract: This invention is a self-contained NOx sensor assembly. It may be used to detect NOx levels in a flowing gas stream such as might be found in an exhaust gas from a combustion process and to produce a measurable electrical output related to the content of NOx measured. The NOx sensor assembly is of a configuration that may be detached from a mounting and replaced. The sensor assembly comprises two sensor elements one of which is made up of a catalyst on a temperature measuring device. The other is a gas stream ambient temperature measuring device. The catalyst is selected and configured so that it selectively reduces NOx and the resulting heat of the reaction raises the temperature of the allied temperature measuring device. The sensor assembly also contains a NOx reductant source. The sensor assembly may be placed in a moving vehicle for measuring NOx levels in its exhaust gas.

    Abstract translation: 本发明是一种独立的NOx传感器组件。 它可以用于检测流动气流中的NOx水平，例如可能在来自燃烧过程的废气中发现，并且产生与所测量的NOx含量相关的可测量的电输出。 NOx传感器组件具有可以从安装和拆卸的构造。 传感器组件包括两个传感器元件，其中一个传感器元件由温度测量装置上的催化剂构成。 另一种是气流环境温度测量装置。 催化剂的选择和配置使得其选择性地还原NOx，并且所产生的反应热量升高了相关温度测量装置的温度。 传感器组件还含有NO x还原剂源。 传感器组件可以放置在移动的车辆中，用于测量其废气中的NOx水平。

    SELECTIVE SORPTION OF DIALKYLATED MULTINUCLEAR AROMATIC COMPOUNDS
    15.
    发明申请
    SELECTIVE SORPTION OF DIALKYLATED MULTINUCLEAR AROMATIC COMPOUNDS 审中-公开
    选择性分离的二甲基纤维素芳族化合物

    公开(公告)号：WO1991001286A1

    公开(公告)日：1991-02-07

    申请号：PCT/US1990004153

    申请日：1990-07-24

    Applicant: CATALYTICA, INC. ,  FELLMANN, Jere, D. ,  WENTRCEK, Paul, R. ,  KILNER, Peter, H.

    Inventor： CATALYTICA, INC.

    IPC: C07C07/13

    CPC classification number: C07C7/13 ,  C07C15/24

    Abstract: The invention relates to a process for the separation of various dialkyl multinuclear aromatic compounds from a feed stream of mixed isomers of those compounds. A shape selective adsorbent is employed resulting in a process that is more efficient than processes based upon prior separation techniques. Of special interest are combination processes involving synthesis steps followed by sorption steps using the same shape selective materials.

    Abstract translation: 本发明涉及从这些化合物的混合异构体的进料流中分离各种二烷基多核芳族化合物的方法。 使用形状选择性吸附剂，导致比基于现有分离技术的方法更有效的方法。 特别感兴趣的是包括合成步骤的组合方法，随后使用相同形状选择性材料的吸附步骤。

    PROCESS FOR OBTAINING SUBSTANTIALLY ALDEHYDE-FREE KETONE PRODUCTS
    16.
    发明申请
    PROCESS FOR OBTAINING SUBSTANTIALLY ALDEHYDE-FREE KETONE PRODUCTS 审中-公开
    获得无碱性无卤酮产品的方法

    公开(公告)号：WO1990000536A1

    公开(公告)日：1990-01-25

    申请号：PCT/US1989002945

    申请日：1989-07-06

    Applicant: CATALYTICA, INC.

    Inventor： CATALYTICA, INC. ,  NEWMAN, Stanley, F. ,  DE DEKEN, Jacques, C. ,  COOK, Michael, L.

    IPC: C07C45/34

    CPC classification number: C07C45/34 ,  C07C45/80 ,  C07C45/82 ,  C07C45/85

    Abstract: Tischtschenko condensation of aldehydes is used to remove aldehydes from dry ketone-containing streams. The Tischtschenko condensation is used to condense the aldehydes into esters whose boiling points are significantly different than the ketones, greatly simplifying the separation of the esters from the ketones. An organic extraction step is used to obtain a substantially dry ketone containing stream. One particularly preferred class of extraction solvents is selected from the group consisting of butane, pentane, hexane, heptane, octane, nonane, decane and mixtures thereof. In particularly preferred embodiments, the Tischtschenko reaction is used in the context of aqueous-phase catalyzed olefin oxidation to ketones. The aldehyde to ester condensation permits easy and efficient removal of the aldehyde analogs of the desired ketones.

    Abstract translation: 使用Tischtschenko缩醛醛从干燥含酮流中除去醛。 Tischtschenko缩合用于将醛缩合成酯，其沸点与酮显着不同，极大地简化了酯与酮的分离。 使用有机萃取步骤获得基本上干燥的含酮流。 一类特别优选的萃取溶剂选自丁烷，戊烷，己烷，庚烷，辛烷，壬烷，癸烷及其混合物。 在特别优选的实施方案中，Tischtschenko反应在水相催化的烯烃氧化成酮的情况下使用。 醛与酯缩合允许容易且有效地除去所需酮的醛类似物。

    IMPROVED PROCESS AND CATALYST STRUCTURE EMPLOYING INTEGRAL HEAT EXCHANGE WITH OPTIONAL DOWNSTREAM FLAMEHOLDER
    17.
    发明申请
    IMPROVED PROCESS AND CATALYST STRUCTURE EMPLOYING INTEGRAL HEAT EXCHANGE WITH OPTIONAL DOWNSTREAM FLAMEHOLDER 审中-公开
    改进的工艺和催化剂结构采用整体热交换器与可选下游火焰探测器

    公开(公告)号：WO1995023915A1

    公开(公告)日：1995-09-08

    申请号：PCT/US1995001989

    申请日：1995-02-28

    Applicant: CATALYTICA, INC. ,  TANAKA KIKINZOKU KOGYO K.K.

    Inventor： CATALYTICA, INC. ,  TANAKA KIKINZOKU KOGYO K.K. ,  DALLA BETTA, Ralph, A. ,  SHOJI, Toru ,  YEE, David, K. ,  MAGNO, Scott, A.

    IPC: F01N03/10

    CPC classification number: F23C13/00 ,  F01N3/28 ,  F01N3/281 ,  F01N3/2814 ,  F01N3/2821 ,  F01N3/2882 ,  F01N2240/02 ,  F01N2330/321 ,  F01N2330/323 ,  F01N2330/42 ,  F23C6/045 ,  F23C9/006 ,  F23C2900/13002

    Abstract: The invention is an improved catalyst structure and its use in highly exothermic processes like catalyst combustion. This improved catalyst structure employed integral heat exchange in an array of longitudinally disposed, adjacent reaction passage-ways or channels, which are either catalyst-coated (14) or catalyst-free (16), wherein the configuration of the catalyst-coated channels (14) differ from the non-catalyst channels (16) such that, when applied in exothermic reaction processes, such as catalyst combustion, the desired reaction is promoted in the catalytic channels (14) and substantially limited in the non-catalytic channels (16). The invention further comprises an improved reaction system and process for combustion of a fuel wherein catalytic combustion using a catalyst structure employing integral heat exchange, preferably the improved structures of the invention, affords a partially-combusted, gaseous product which is passed to a homogeneous combustion zone where complete combustion is promoted by means of a flameholder.

    Abstract translation: 本发明是改进的催化剂结构及其在高度放热过程如催化剂燃烧中的应用。 这种改进的催化剂结构在纵向设置的相邻反应通道或通道的阵列中采用整体热交换，其是催化剂涂覆的（14）或无催化剂（16），其中催化剂涂覆的通道（ 14）与非催化剂通道（16）不同，使得当用于放热反应过程如催化剂燃烧时，在催化通道（14）中促进所需的反应，并且在非催化通道（16）中基本受限 ）。 本发明还包括改进的燃料燃烧反应系统和方法，其中使用采用整体热交换的催化剂结构的催化燃烧，优选本发明的改进结构，提供部分燃烧的气态产物，其被传递到均匀燃烧 通过火焰稳定器促进完全燃烧的区域。

    IMPROVED LEWIS ACID PROMOTED TRANSITION ALUMINA CATALYSTS AND ISOPARAFFIN ALKYLATION PROCESSES USING THOSE CATALYSTS
    18.
    发明申请
    IMPROVED LEWIS ACID PROMOTED TRANSITION ALUMINA CATALYSTS AND ISOPARAFFIN ALKYLATION PROCESSES USING THOSE CATALYSTS 审中-公开
    改进的LEWIS酸促进过渡氧化铝催化剂和使用这些催化剂的异噻唑烷基化方法

    公开(公告)号：WO1994002243A1

    公开(公告)日：1994-02-03

    申请号：PCT/US1993006712

    申请日：1993-07-16

    Applicant: CATALYTICA, INC.

    Inventor： CATALYTICA, INC. ,  COOPER, Michael, D. ,  KING, David, L. ,  SANDERSON, William, A.

    IPC: B01J21/02

    CPC classification number: B01J27/12 ,  B01J27/125 ,  C07C2/60 ,  C07C2521/04 ,  C07C2527/1213

    Abstract: This invention is directed to a catalyst system for use in the alkylation of isoparaffin with olefins. More specifically, this invention is directed to an improved catalyst system containing specified amounts of water and a component of that system comprising certain transition aluminas promoted with a Lewis acid (preferably BF3). In addition, this invention is a catalytic process for the alkylation of isoparaffin with olefins. The catalyst component is produced by contacting the transition alumina with the Lewis acid at relatively low temperatures. The catalyst system comprises that component and an additional amount of free Lewis acid. The process entails isoparaffin alkylation with olefins using the catalyst component and its allied catalyst system.

    Abstract translation: 本发明涉及一种用于烯烃与异链烷烃烷基化反应的催化剂体系。 更具体地，本发明涉及一种改进的催化剂体系，其包含特定量的水和该系统的组分，其包含用路易斯酸（优选BF 3）促进的某些过渡氧化铝。 此外，本发明是用烯烃烷基化异链烷烃的催化方法。 催化剂组分通过在较低温度下使过渡氧化铝与路易斯酸接触来制备。 催化剂体系包含该组分和另外量的游离路易斯酸。 该方法需要使用催化剂组分及其联合催化剂体系使烯烃进行异链烷烃化。

    DESULFURIZATION PROCESS USING BROMINE
    19.
    发明申请
    DESULFURIZATION PROCESS USING BROMINE 审中-公开
    使用溴的脱硫工艺

    公开(公告)号：WO1993020008A1

    公开(公告)日：1993-10-14

    申请号：PCT/US1993003143

    申请日：1993-04-02

    Applicant: CATALYTICA, INC.

    Inventor： CATALYTICA, INC. ,  SCHUBERT, Paul, F. ,  SCHUBERT, David, W. ,  MAHAJAN, Suresh ,  ROSTRUP-NIELSEN, Thomas

    IPC: C01B17/20

    CPC classification number: B01D53/507 ,  B01D53/73 ,  C01B17/74

    Abstract: This invention is a combination process for removal of sulfur oxides (SOx) from gases containing both the SOx and oxygen (106). The fluid used to remove the SOx contains sulfuric acid and bromine. The SOx is converted to sulfuric acid and the bromine is thereafter converted to hydrobromic acid. The hydrobromic acid is concentrated and catalytically converted to bromine for ultimate recycling to the SOx removal step (132). The SOx is finally recovered as a strong sulfuric acid (104).

    Abstract translation: 本发明是从含有SO x和氧（106）的气体中除去硫氧化物（SOx）的组合方法。 用于除去SOx的流体含有硫酸和溴。 将SO x转化为硫酸，然后将溴转化为氢溴酸。 将氢溴酸浓缩并催化转化成溴，以最终循环至SO x去除步骤（132）。 SO x最终作为强硫酸回收（104）。

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