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公开(公告)号：WO1990007480A1
公开(公告)日：1990-07-12
申请号：PCT/US1990000054
申请日：1990-01-03
Applicant: CATALYTICA, INC.
Inventor： CATALYTICA, INC. , KING, David, L. , COOPER, Michael, D. , USHIBA, Ken, K. , SANDERSON, William, A.
IPC: C07C05/22
CPC classification number: C07H3/02 , C07C2/26 , C07C2/58 , C07C37/08 , C07C37/14 , C07C37/20 , C07C41/09 , C07C45/455 , C07C45/46 , C07C45/49 , C07C45/53 , C07C45/72 , C07C45/74 , C07C51/14 , C07C201/08 , C07C407/00 , C07C409/24 , C07C409/26 , C07C2531/025 , C07C2531/10 , C07C2531/26 , C07C2531/38 , C07F9/3808 , Y02P20/52 , C07C205/06 , C07C39/04 , C07C43/043 , C07C43/06 , C07C39/06 , C07C39/16
Abstract: The present invention provides a process for the conversion of a reactant into a reaction product in the presence of a solid acid catalyst comprising one or more fluorine atoms, sulfo radicals and phosphono radicals, each such radical being bonded to the same or different carbon atom, with the proviso that at least one sulfo radical and at least one phosphono radical are bonded to such carbon atoms through the sulfur atom and the phosphorus atom, respectively. These compounds are preferably non-polymeric, i.e. they have a molecular weight of about 5000 or less. The above acid catalysts may be reacted with a tetravalent metal, e.g. Zr, to provide a solid acid catalyst.
Abstract translation: 本发明提供了在包含一个或多个氟原子，磺基和膦酰基的固体酸催化剂存在下将反应物转化成反应产物的方法，每个这样的基团键合到相同或不同的碳原子上， 条件是至少一个磺基和至少一个膦酰基分别通过硫原子和磷原子键合到这些碳原子上。 这些化合物优选是非聚合的，即其分子量为约5000或更小。 上述酸催化剂可以与四价金属反应，例如 Zr，以提供固体酸催化剂。
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2.发明申请IMPROVED LEWIS ACID PROMOTED TRANSITION ALUMINA CATALYSTS AND ISOPARAFFIN ALKYLATION PROCESSES USING THOSE CATALYSTS 审中-公开改进的LEWIS酸促进过渡氧化铝催化剂和使用这些催化剂的异噻唑烷基化方法
公开(公告)号：WO1994002243A1
公开(公告)日：1994-02-03
申请号：PCT/US1993006712
申请日：1993-07-16
Applicant: CATALYTICA, INC.
Inventor： CATALYTICA, INC. , COOPER, Michael, D. , KING, David, L. , SANDERSON, William, A.
IPC: B01J21/02
CPC classification number: B01J27/12 , B01J27/125 , C07C2/60 , C07C2521/04 , C07C2527/1213
Abstract: This invention is directed to a catalyst system for use in the alkylation of isoparaffin with olefins. More specifically, this invention is directed to an improved catalyst system containing specified amounts of water and a component of that system comprising certain transition aluminas promoted with a Lewis acid (preferably BF3). In addition, this invention is a catalytic process for the alkylation of isoparaffin with olefins. The catalyst component is produced by contacting the transition alumina with the Lewis acid at relatively low temperatures. The catalyst system comprises that component and an additional amount of free Lewis acid. The process entails isoparaffin alkylation with olefins using the catalyst component and its allied catalyst system.
Abstract translation: 本发明涉及一种用于烯烃与异链烷烃烷基化反应的催化剂体系。 更具体地，本发明涉及一种改进的催化剂体系，其包含特定量的水和该系统的组分，其包含用路易斯酸（优选BF 3）促进的某些过渡氧化铝。 此外，本发明是用烯烃烷基化异链烷烃的催化方法。 催化剂组分通过在较低温度下使过渡氧化铝与路易斯酸接触来制备。 催化剂体系包含该组分和另外量的游离路易斯酸。 该方法需要使用催化剂组分及其联合催化剂体系使烯烃进行异链烷烃化。
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3.发明申请PREPARATION OF TRIALKYLACETIC ACIDS, PARTICULARLY OF PIVALIC ACID, USING LEWIS ACID CATALYSIS 审中-公开使用酸洗催化剂制备特异酸，特别是酸性酸
公开(公告)号：WO1992018452A1
公开(公告)日：1992-10-29
申请号：PCT/US1992002943
申请日：1992-04-09
Applicant: CATALYTICA, INC.
Inventor： CATALYTICA, INC. , RICHARD, Michael, A. , SANDERSON, William, A.
IPC: C07C51/14
CPC classification number: C07C51/14 , C07C53/128
Abstract: This invention is a process for the production of trialkyl acetic acids, particularly of pivalic acid, from branched olefins, particularly isobutene, and carbon monoxide using catalytic amounts of a Lewis acid such as boron trifluoride.
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4.发明申请ACID CATALYST AND USE THEREOF IN ALKYLATION OF OLEFINS WITH TERTIARY ALKANES 审中-公开酸催化剂及其与烷基烯烃烯烃的烷基化反应
公开(公告)号：WO1994010106A2
公开(公告)日：1994-05-11
申请号：PCT/US1993010463
申请日：1993-10-29
Applicant: CATALYTICA, INC.
Inventor： CATALYTICA, INC. , KING, David, L. , COOPER, Michael, D. , SANDERSON, William, A.
IPC: C07C0
CPC classification number: B01J31/0259 , B01J21/08 , B01J27/08 , B01J27/16 , B01J31/0211 , B01J31/0225 , B01J31/0227 , B01J31/0231 , B01J31/0258 , B01J31/0271 , B01J37/0201 , B01J2231/323 , B01J2531/48 , C07C2/62 , C07C2/66 , C07C5/2794 , C07C37/08 , C07C45/455 , C07C45/46 , C07C45/49 , C07C45/53 , C07C45/74 , C07C51/353 , C07C67/04 , C07C67/08 , C07C201/08 , C07C409/24 , C07C2527/08 , C07C2527/10 , C07C2527/1213 , C07C2527/125 , C07C2527/126 , C07C2527/128 , C07C2527/133 , C07C2527/135 , C07C2527/14 , C07C2531/025 , C07D301/14 , C10G29/205 , Y02P20/52 , C07C15/02 , C07C9/00 , C07C39/04 , C07C205/06
Abstract: The present invention provides an acid catalyst complex comprising an organosulfonic acid having at least one covalent carbon-fluorine bond or one covalent carbon-phosphorus bond provided by a phosphono radical which has been contacted with a Lewis Acid to produce a catalyst complex containing said Lewis Acid. The present invention also provides a process for the conversion of a reactant into a reaction product in the presence of said catalyst complex. In particular, the catalyst complex is useful for providing a high octane alkylate stream by converting a mixture comprising isoparaffins and olefins into said alkylate in the presence of said catalyst complex.
Abstract translation: 本发明提供了一种酸催化剂配合物，其包含具有至少一个共价碳 - 氟键的有机磺酸或由膦酰基提供的一个共价碳 - 磷键，其与路易斯酸接触以产生含有所述路易斯酸的催化剂络合物 。 本发明还提供了在所述催化剂络合物存在下将反应物转化为反应产物的方法。 特别地，催化剂络合物可用于通过在所述催化剂络合物的存在下将包含异链烷烃和烯烃的混合物转化成所述烷基化物来提供高辛烷基烷基化物流。
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5.发明申请PREPARATION OF TRIALKYLACETIC ACIDS, PARTICULARLY OF PIVALIC ACID, USING SOLID ACID CATALYSIS 审中-公开使用固体酸催化制备特异酸，特别是酸性酸
公开(公告)号：WO1992018592A1
公开(公告)日：1992-10-29
申请号：PCT/US1992002897
申请日：1992-04-09
Applicant: CATALYTICA, INC.
Inventor： CATALYTICA, INC. , SANDERSON, William, A. , RICHARD, Michael, A.
IPC: C11D01/28
CPC classification number: C07F9/3808 , C07C51/14 , C07C53/128
Abstract: This invention is a process for the production of trialkyl acetic acids, particularly of pivalic acid, from branched olefins, particularly isobutene, and carbon monoxide using a solid acid catalyst and optionally with minor amounts of a Lewis acid such as boron trifluoride.
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Patent Agency Ranking6.发明公开LEWIS ACID PROMOTED TRANSITION ALUMINA CATALYSTS AND ISOPARAFFIN ALKYLATION PROCESSES USING THOSE CATALYSTS 失效Lewis酸资助过渡铝用催化剂和ISOPARAFFINALKYLIERUNGSVERFAHREN这种催化剂。
公开(公告)号：EP0550640A1
公开(公告)日：1993-07-14
申请号：EP91918129.0
申请日：1991-09-25
Applicant: CATALYTICA, INC.
Inventor： COOPER, Michael, D. , KING, David, L. , SANDERSON, William, A.
CPC classification number: B01J27/32 , B01J21/04 , B01J27/08 , B01J27/128 , B01J27/135 , B01J38/12 , C07C2/60 , C07C2521/04 , C07C2527/08 , C07C2527/10 , C07C2527/1213 , C07C2527/125 , C07C2527/126 , C07C2527/128 , C07C2527/133 , C07C2527/135 , C07C2527/14 , Y02P20/584
Abstract: Cette invention concerne a) un système de catalyseur, b) un composant de ce système comprenant certaines alumines de transition améliorées par un acide de Lewis (de préférence BF3), et c) un procédé catalytique pour l'alkylation d'isoparaffine avec des oléfines. Le composant catalyseur est produit en mettant en contact l'alumine de transition avec l'acide de Lewis à des températures relativement basses ou à des températures auxquelles certaines caractéristiques apparaissent dans le spectre de résonance magnétique nucléaire (RMN) du composant. Le système de catalyseur comprend ce composant et une quantité additionnelle d'acide de Lewis libre. Le procédé permet l'alkylation d'isoparaffine/oléfine en utilisant le composant catalyseur et le système catalytique associé.
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7.发明授权LEWIS ACID PROMOTED TRANSITION ALUMINA CATALYSTS AND ISOPARAFFIN ALKYLATION PROCESSES USING THOSE CATALYSTS 失效由路易斯酸活化的过渡Aluminiumoxydkatalysatoren和方法，用于使用这些催化剂的异链烷烃进行烷基化
公开(公告)号：EP0550640B1
公开(公告)日：1997-03-26
申请号：EP91918129.7
申请日：1991-09-25
Applicant: CATALYTICA, INC.
Inventor： COOPER, Michael, D. , KING, David, L. , SANDERSON, William, A.
IPC: B01J27/24 , B01J27/186 , B01J27/187 , C07C2/58 , B01J27/199 , B01J27/135 , B01J21/02 , B01J27/08 , C07C2/60 , B01J27/12 , B01J27/125
CPC classification number: B01J27/32 , B01J21/04 , B01J27/08 , B01J27/128 , B01J27/135 , B01J38/12 , C07C2/60 , C07C2521/04 , C07C2527/08 , C07C2527/10 , C07C2527/1213 , C07C2527/125 , C07C2527/126 , C07C2527/128 , C07C2527/133 , C07C2527/135 , C07C2527/14 , Y02P20/584
Abstract: This invention is to: a) a catalyst system, b) a component of that system comprising certain transition aluminas promoted with a Lewis acid (preferably BF3), and c) a catalytic process for the alkylation of isoparaffin with olefins. The catalyst component is produced by contacting the transition alumina with the Lewis acid at relatively low temperatures or at those temperatures at which certain characteristic peaks appear in the component's nuclear magnetic resonance (NMR) spectrum. The catalyst system comprises that component and an additional amount of free Lewis acid. The process entails olefin/isoparaffin alkylation using the catalyst component and its allied catalyst system.
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8.发明公开PREPARATION OF TRIALKYLACETIC ACIDS, PARTICULARLY OF PIVALIC ACID, USING SOLID ACID CATALYSIS 失效MANUFACTURINGTRIALKYLACETSÄUREN，特别是与新戊酸的固体酸催化剂。
公开(公告)号：EP0580735A1
公开(公告)日：1994-02-02
申请号：EP92910320.0
申请日：1992-04-09
Applicant: CATALYTICA INC.
Inventor： SANDERSON, William, A. , RICHARD, Michael, A.
CPC classification number: C07F9/3808 , C07C51/14 , C07C53/128
Abstract: L'invention se rpporte à un procédé de production d'acides trialkylacétiques, notamment d'acide pivalique, à partir d'oléfines ramifiées, notamment à l'isobutène, et de monoxyde de carbone au moyen d'un catalyseur à acide solide et, éventuellement, de quantités mineures d'un acide de Lewis tel que le trifluorure de bore.
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9.发明公开IMPROVED LEWIS ACID PROMOTED TRANSITION ALUMINA CATALYSTS AND ISOPARAFFIN ALKYLATION PROCESSES USING THOSE CATALYSTS 失效改进刘易斯酸活化和方法ISOPARAFFIN过渡ALUMINIUMOXYDKATALYSATOREN烷基化使用本催化剂。
公开(公告)号：EP0650394A1
公开(公告)日：1995-05-03
申请号：EP93917235.0
申请日：1993-07-16
Applicant: CATALYTICA INC.
Inventor： COOPER, Michael, D. , KING, David, L. , SANDERSON, William, A.
CPC classification number: B01J27/12 , B01J27/125 , C07C2/60 , C07C2521/04 , C07C2527/1213
Abstract: This invention is directed to a catalyst system for use in the alkylation of isoparaffin with olefins. More specifically, this invention is directed to an improved catalyst system containing specified amounts of water and a component of that system comprising certain transition aluminas promoted with a Lewis acid (preferably BF3). In addition, this invention is a catalytic process for the alkylation of isoparaffin with olefins. The catalyst component is produced by contacting the transition alumina with the Lewis acid at relatively low temperatures. The catalyst system comprises that component and an additional amount of free Lewis acid. The process entails isoparaffin alkylation with olefins using the catalyst component and its allied catalyst system.
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公开(公告)号：EP0452411A1
公开(公告)日：1991-10-23
申请号：EP90902427.0
申请日：1990-01-03
Applicant: CATALYTICA INC.
Inventor： KING, David, L. , COOPER, Michael, D. , USHIBA, Ken, K. , SANDERSON, William, A.
IPC: B01J31 , C07C1 , C07C2 , C07C5 , C07C6 , C07C27 , C07C29 , C07C37 , C07C41 , C07C45 , C07C51 , C07C67 , C07C69 , C07C201 , C07C205 , C07C409 , C07D327 , C07F9 , C07H3
CPC classification number: C07H3/02 , C07C2/26 , C07C2/58 , C07C37/08 , C07C37/14 , C07C37/20 , C07C41/09 , C07C45/455 , C07C45/46 , C07C45/49 , C07C45/53 , C07C45/72 , C07C45/74 , C07C51/14 , C07C201/08 , C07C407/00 , C07C409/24 , C07C409/26 , C07C2531/025 , C07C2531/10 , C07C2531/26 , C07C2531/38 , C07F9/3808 , Y02P20/52 , C07C205/06 , C07C39/04 , C07C43/043 , C07C43/06 , C07C39/06 , C07C39/16
Abstract: L'invention concerne un procédé de conversion d'un réactif en un produit de réaction en présence d'un catalyseur acide solide comprenant un ou plusieurs atomes de fluor, des radicaux sulfo et des radicaux phosphono, chacun desdits radicaux étant lié au même atome de carbone ou à un atome de carbone différent, à condition qu'au moins un radical sulfo et au moins un radical phosphono soient liés auxdits atomes de carbone par l'atome de soufre et l'atome de phosphono respectivement. Ces composés sont de préférence non polymères, c'est-à-dire qu'ils ont une masse moléculaire d'environ 5000 au moins. On peut faire réagir les catalyseurs acides précités avec un métal tétravalent, par exemple Zr, afin de produire un catalyseur acide solide.
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