Abstract:
PROBLEM TO BE SOLVED: To provide a highly reactive polyurethane composition containing a uretdione group, curable at very low temperatures and suitable especially for producing plastics, highly glossy or mat, light-resistant and weatherproof powder coating applied articles, and adhesives. SOLUTION: The highly reactive liquid polyurethane composition containing the uretdione group and having >40°C melting point comprises (A) a curing agent containing the uretdione group, (B) a catalyst, (C) optionally a polymer containing hydroxy or amine, (D) at least one compound having reactivity to acid groups, (E) an acid, (F) an auxiliary and an additive. COPYRIGHT: (C)2005,JPO&NCIPI
Abstract:
PROBLEM TO BE SOLVED: To provide a radiation-curing powder coating composition which is stably stored at 35°C, yields a cured coating film which is stiff and flexible and generates a weather-resistant coating. SOLUTION: The radiation-curing powder coating composition contains (I) a binder comprising (A) 60-90 mass% at least one amorphous urethane acrylate and (B) 10-40 mass% at least one crystalline urethane acrylate [provided that a mixture comprising components (A) and (B) has a glass transition temperature Tg of ≥35°C] and (II) an auxiliary and an additive. Here, an UV-initiator is removed from the powder coating composition. COPYRIGHT: (C)2003,JPO
Abstract:
PROBLEM TO BE SOLVED: To provide a polyurethane powder coating composition containing a highly reactive uretdione group especially suitable for preparing a plastic or a highly glossy or matte, light-fast, weather-resistant powder coating, which is curable at extremely low temperatures. SOLUTION: A known uretdione-containing powder coating hardener is used for preparing the polyurethane powder coating composition to lower the curing temperature of the powder coating composition, since the formation of a quaternary ammonium salt with hydroxide or fluoride as a counter ion drastically accelerates re-decomposition of the uretdione group. COPYRIGHT: (C)2003,JPO
Abstract:
PROBLEM TO BE SOLVED: To provide a radiation-curable powder coating composition which is storage-stable and gives, after hardening a coating film, a coating exhibiting high flexibility as well as weather resistance, high adhesion and remarkably excellent flow leveling property. SOLUTION: The radiation-curable powder coating composition comprises (I) a binder comprising at least one crystalline urethane acrylate having a melting point of 40-130°C; and (II) an auxiliary and an additive. COPYRIGHT: (C)2003,JPO
Abstract:
PROBLEM TO BE SOLVED: To provide an ultraviolet light-curable powdered coating composition. SOLUTION: This ultraviolet light-curable powdered coating composition comprises a binder comprising (A) at least one amorphous urethane acrylate and (B) at least one crystalline urethane acrylate (wherein, the Tg of a mixture of A and B is >=35 deg.C) and an auxiliary and an additive. The ultraviolet light- curable powdered coating composition is cross-linked to produce the weather- resistant coating film having high gloss and good light stability.
Abstract:
PROBLEM TO BE SOLVED: To provide a highly reactive polyurethane powder coating composition based on an epoxy-group-terminated, uretdione-group-containing polyaddition compound. SOLUTION: The polyurethane-powder coating composition substantially contains (A) an epoxy-group-terminated, uretdione-group-containing polyaddition compound, (B) a hydroxy-group-containing polymer, (C) a catalyst, and optionally (D) an auxiliary and an additive substance. Ingredients (A) and (B) are present in such a ratio that 0.3-1 uretdione group of ingredient (A) is allotted to each of all the hydroxy groups of ingredient (B). The amount of the catalyst (C) is 0.001-3 mass% based on the total amount of ingredients (A) and (B). COPYRIGHT: (C)2005,JPO&NCIPI
Abstract:
PROBLEM TO BE SOLVED: To provide a solid uretodione group-containing polycondensation compound for a polyurethane-powder coating composition curable at a low temperature. SOLUTION: The above problem is solved by a solid uretodione group-containing polyaddition compound obtained by reacting (A) at least one of aliphatic, (cyclic) aliphatic and alicyclic polyisocyanate component comprising at least 40 mass% of a uretodione group-containing polyisocyanate compound having an average functionality of at least 2.0, and ≤60 mass% of at least one of a diisocyanate compound and/or a uretodione group-free isocyanurate compound; (B) dodecane diol-1, 12; and at least one of other compounds having at least one hydroxyl group, the polyaddition compound having a melting point of 40-130°C, a free NCO-content of
Abstract:
PROBLEM TO BE SOLVED: To provide a highly reactive polyurethane composition containing a uretdione group, curable at very low temperatures and suitable especially for producing plastics, highly glossy or mat, light-resistant and weatherproof powder coating applied articles, and adhesives. SOLUTION: The highly reactive liquid polyurethane composition containing the uretdione group and having COPYRIGHT: (C)2005,JPO&NCIPI
Abstract:
PROBLEM TO BE SOLVED: To find a highly reactive uretdione group-containing polyurethane coating composition which is curable at very low temperatures and particularly suited in use for manufacturing a plastic and a highly gloss or matte powder coating layer having light stability and weatherability. SOLUTION: Since a metal hydroxide and a metal alcoholate strongly accelerate the redecomposition of the uretdione group, the curing temperature of the powder coating composition can be remarkably lowered when a uretdione group-containing powder coating curing agent is used. COPYRIGHT: (C)2005,JPO&NCIPI
Abstract:
PROBLEM TO BE SOLVED: To provide a manufacturing method of obtaining a desired alicyclic isocyanate with a high selectivity. SOLUTION: The method comprises reacting an aromatic isocyanate with hydrogen in the presence of a supported catalyst containing ruthenium alone as the active metal or together with at least one metal of subgroup I, VII and VIII metals in the periodic table in an amount of 0.01-20 mass%, the catalyst carrier having a BET surface area of 30 m 2 /g to less than 70 m 2 /g and not less than 50 % of the pore volume of the catalyst carrier being micropores having a pore diameter of greater than 50 nm and less than 50 % of the pore volume of the catalyst carrier being micropores having a pore diameter of 2-50 nm. According to this method, a desired isocyanate can be obtained with a high selectivity and the ratio of the 4,4'-trans-trans-isomer is low and in this instance, the low 4,4'-trans-trans-isomer ratio can be maintained in spite of a high degree of conversion. The catalyst life is long and, simultaneously, and the isomer distribution hardly changes even after a considerably long-term operation. COPYRIGHT: (C)2004,JPO