公开(公告)号：WO2021034809A1

公开(公告)日：2021-02-25

申请号：PCT/US2020/046767

申请日：2020-08-18

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  CALIFORNIA INSTITUTE OF TECHNOLOGY

Inventor： AGAPIE, Theodor ,  XIONG, Shuoyan ,  BAILEY, Brad C. ,  SPINNEY, Heather A. ,  NETT, Alex J. ,  WILSON, David R. ,  KLOSIN, Jerzy

IPC: C07F15/00 ,  C07F15/04 ,  C08F4/70 ,  C08F4/80

Abstract: Processes of polymerizing olefin monomers using catalyst systems and catalysts systems that include a procatalyst having a structure according to formula (I): (I).

公开(公告)号：WO2019055731A1

公开(公告)日：2019-03-21

申请号：PCT/US2018/050991

申请日：2018-09-14

Applicant: NORTHWESTERN UNIVERSITY ,  DOW GLOBAL TECHNOLOGIES LLC

Inventor： RAGHURAMAN, Arjun ,  HEATH, William H. ,  MUKHOPADHYAY, Sukrit ,  SPINNEY, Heather A. ,  WILSON, David R. ,  NOTESTEIN, Justin M. ,  NGUYEN, SonBinh T.

IPC: C08G65/26 ,  C08G18/48

Abstract: A method of producing a polyether polyol that includes reacting a low molecular weight initiator with ethylene oxide in the presence of a polymerization catalyst, the low molecular weight initiator having a number average molecular weight of less than 1,000 g/mol and a nominal hydroxyl functionality at least 2, and the polymerization catalyst being a Lewis acid catalyst having the general formula M(R 1 )1(R 2 )1(R 3 )1(R 4 )0 or 1. Whereas, M is boron, aluminum, indium, bismuth or erbium, R 1 , R 2 , and R 3 each includes a same fluoroalkyl-substituted phenyl group, and optional R 4 includes a functional group or functional polymer group. R 1 , R 2 , and R 3 are the same fluoroalkyl-substituted phenyl group. The method further includes forming a polyether polyol having a number average molecular weight of greater than the number average molecular weight of the low molecular weight initiator in the presence of the Lewis acid catalyst.

公开(公告)号：WO2014025414A3

公开(公告)日：2014-02-13

申请号：PCT/US2013/033828

申请日：2013-03-26

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： KEATON, Richard, J. ,  MARGL, Peter M. ,  BOELTER, Scott D. ,  ROMER, Duane, R. ,  NOWLIN, Debra L. ,  WILMOT, Nathan ,  DUGGAL, Rajat ,  WILSON, David R. ,  WELSH, Dean M.

IPC: B01J23/644 ,  C08G18/48 ,  C08G18/66 ,  C08G18/76 ,  C08G18/22 ,  C08G18/32 ,  C08K5/5398

Abstract: Polyisocyanate-based polymers are formed by curing a reaction mixture containing at least one polyisocyanate and at least one isocyanate-reactive compound having at least two isocyanate-reactive groups in the presence of a bismuth thiophosphoric acid diester salt.

公开(公告)号：WO2020176277A1

公开(公告)日：2020-09-03

申请号：PCT/US2020/018368

申请日：2020-02-14

Applicant: NORTHWESTERN UNIVERSITY ,  DOW GLOBAL TECHNOLOGIES LLC

Inventor： BHAGAT, Mihir ,  BENNETT, Charmaine ,  ZHU, Youlong ,  NGUYEN, SonBinh T. ,  BROADBELT, Linda ,  NOTESTEIN, Justin M. ,  BELOWICH, Matthew E. ,  RAGHURAMAN, Arjun ,  HEATH, William H. ,  MUKHOPADHYAY, Sukrit ,  SPINNEY, Heather A. ,  WILSON, David R.

IPC: C08G65/26 ,  C08G18/48

Abstract: A method of producing a polyether alcohol that includes feeding an initiator into a reactor, feeding one or more monomers into the reactor, feeding a polymerization catalyst into the reactor, the polymerization catalyst being a Lewis acid catalyst having a general formula M(R 1 ) 1 (R 2 ) 1 (R 3 ) 1 (R 4 ) 0 or 1 , separate from feeding the initiator into the reactor, feeding a hydrogen bond acceptor additive into the reactor, the hydrogen bond acceptor additive being a C 2 to C 20 organic molecule having at least two hydroxyl groups, of which two hydroxyl groups are situated in 1,2-, 1,3-, or 1,4- positions on the organic molecule, and allowing the initiator to react with the one or more monomers in the presence of the polymerization catalyst and the hydrogen bond acceptor additive to form a polyether alcohol having a number average molecular weight greater than a number average molecular weight of the initiator.

公开(公告)号：WO2019067280A4

公开(公告)日：2019-04-04

申请号：PCT/US2018/051680

申请日：2018-09-19

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： KRASOVSKIY, Arkady L. ,  WILSON, David R. ,  VAIDYA, Tulaza ,  CARNAHAN, Edmund M. ,  FONTAINE, Philip P. ,  IVERSON, Carl N.

IPC: C08F4/659 ,  C08F210/16 ,  C08F4/64

Abstract: Embodiments are directed to a catalyst system comprising metal ligand complexes and processes for polyolefin polymerization using the metal ligand complex having the following structure : where X is selected from the group consisting of -OR X or NR X 2 .

公开(公告)号：WO2019067280A1

公开(公告)日：2019-04-04

申请号：PCT/US2018/051680

申请日：2018-09-19

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： KRASOVSKIY, Arkady L. ,  WILSON, David R. ,  VAIDYA, Tulaza ,  CARNAHAN, Edmund M. ,  FONTAINE, Philip P. ,  IVERSON, Carl N.

IPC: C08F4/659 ,  C08F210/16 ,  C08F4/64

Abstract: Embodiments are directed to a catalyst system comprising metal ligand complexes and processes for polyolefin polymerization using the metal ligand complex having the following structure : where X is selected from the group consisting of -OR X or NR X 2 .

公开(公告)号：WO2019067274A4

公开(公告)日：2019-04-04

申请号：PCT/US2018/051638

申请日：2018-09-19

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： KRASOVSKIY, Arkady L. ,  WILSON, David R. ,  STUBBERT, Bryan D. ,  VAIDYA, Tulaza ,  KLOSIN, Jerzy ,  CARNAHAN, Edmund M. ,  FONTAINE, Philip P. ,  ROSEN, Mari S.

IPC: C08F4/659 ,  C08F210/16 ,  C08F4/64

Abstract: Embodiments are directed to a catalyst system comprising metal ligand complexes and processes for polyolefin polymerization using the metal ligand complex having the following structure: where each X is selected from the group consisting of -(CH 2 )SiR X 3 .

公开(公告)号：WO2019055741A1

公开(公告)日：2019-03-21

申请号：PCT/US2018/051002

申请日：2018-09-14

Applicant: NORTHWESTERN UNIVERSITY ,  DOW GLOBAL TECHNOLOGIES LLC

Inventor： RAGHURAMAN, Arjun ,  HEATH, William H. ,  HOOK, Bruce D. ,  YU, Wanglin ,  MUKHOPADHYAY, Sukrit ,  SPINNEY, Heather A. ,  WILSON, David R. ,  NOTESTEIN, Justin M. ,  NGUYEN, SonBinh T.

IPC: C08G65/10 ,  C08G65/26

Abstract: A method of producing an alcohol ethoxylate surfactant or lubricant includes reacting a low molecular weight initiator with ethylene oxide in the presence of a polymerization catalyst, the low molecular weight initiator having a nominal hydroxyl functionality at least 1, and the polymerization catalyst being a Lewis acid catalyst having the general formula M(R 1 )1(R 2 )1(R 3 )1(R 4 ) 0 or 1 , whereas M is boron, aluminum, indium, bismuth or erbium, R 1 , R 2 and R 3 each includes a same fluoroalkyl-substituted phenyl group, and optional R 4 includes a functional group or functional polymer group. R 1 , R 2 , and R 3 are the same fluoroalkyl-substituted phenyl group. The method further includes forming the alcohol ethoxylate surfactant or lubricant having a number average molecular weight of greater than the number average molecular weight of the low molecular weight initiator in the presence of the Lewis acid catalyst.

公开(公告)号：WO2019055740A1

公开(公告)日：2019-03-21

申请号：PCT/US2018/051001

申请日：2018-09-14

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： RAGHURAMAN, Arjun ,  HEATH, William H. ,  MUKHOPADHYAY, Sukrit ,  SPINNEY, Heather A. ,  WILSON, David R.

IPC: C08G65/26 ,  C08G18/48 ,  C08G65/10

Abstract: A Lewis acid polymerization catalyst has a general formula M(R 1 ) 1 (R 2 ) 1 (R 3 ) 1 (R 4 ) 0 or 1, whereas M is boron, R 1 , R 2 , R 3 , and R 4 are each independent, R 1 is a 3,5-bis(trifluoromethyl)-substituted phenyl group, R 2 is the 3,5-bis(trifluoromethyl) substituted phenyl group or a first fluoro-substituted phenyl group selected from Set 1 structures, R 3 is independently a second fluoro-substituted phenyl group selected from the Set 1 structures, and optional R 4 includes a third functional group or functional polymer group.

公开(公告)号：WO2019055734A1

公开(公告)日：2019-03-21

申请号：PCT/US2018/050995

申请日：2018-09-14

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： RAGHURAMAN, Arjun ,  HEATH, William H. ,  MUKHOPADHYAY, Sukrit ,  SPINNEY, Heather A. ,  WILSON, David R.

IPC: C08G65/26 ,  C08G18/48

Abstract: A method of producing a polyether polyol includes reacting a low molecular weight initiator with ethylene oxide in the presence of a polymerization catalyst, and the low molecular weight initiator has a nominal hydroxyl functionality at least 2. The polymerization catalyst is a Lewis acid catalyst having the general formula M(R 1 ) 1 (R 2 ) 1 (R 3 ) 1 (R 4 )0 or 1, whereas M is boron, aluminum, indium, bismuth or erbium, R 1 , R 2 , R 3 , and R 4 are each independent, R 1 includes a fluoroalkyl-substituted phenyl group, R 2 incudes a fluoroalkyl-substituted phenyl group or a fluoro/chloro-substituted phenyl group, R 3 includes a fluoroalkyl-substituted phenyl group or a fluoro/chloro-substituted phenyl group, and optional R 4 includes a functional group or functional polymer group, R 1 being different from at least one of R 2 and R 3 .