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    PROCESS FOR THE PREPARATION OF 2-OXO-1,3-DIOXOLANES
    12.
    发明专利
    PROCESS FOR THE PREPARATION OF 2-OXO-1,3-DIOXOLANES 未知

    公开(公告)号：AU6744887A

    公开(公告)日：1987-07-16

    申请号：AU6744887

    申请日：1987-01-09

    Applicant: HOECHST AG

    Inventor： BRINDOPKE GERHARD

    IPC: B05D7/24 ,  B01J27/08 ,  B01J31/06 ,  C07B61/00 ,  C07D317/36 ,  C08G18/65 ,  C08G71/00 ,  C08G59/14 ,  C08G18/30 ,  C08G18/58

    Abstract: A process for the preparation of 2-oxo-1,3-dioxolanes by reaction of epoxides with carbon dioxide in the presence of alkali iodides wherein at least one epoxy compound is reacted in the presence or absence of inert solvent either with a combination of A) at least one alkali iodide and B) at least one compound of the group a) polyol and b) an ether or polyether or, if the epoxy compound already has the structural features of the compounds Ba) and Bb), with the alkali iodide A) alone, at temperatures from 40 DEG to 180 DEG C. while introducing carbon dioxide at normal pressure or at slightly increased pressure, to form the corresponding organic carbonates. The 2-oxo-1,3-dioxolanes obtained are used for the preparation of synthetic resins, containing urethane groups, in the form of coatings of molded bodies.

    PROCESS FOR THE PREPARATION OF 2-OXO-1,3-DIOXOLANES
    18.
    发明专利
    PROCESS FOR THE PREPARATION OF 2-OXO-1,3-DIOXOLANES 未知

    公开(公告)号：AU589732B2

    公开(公告)日：1989-10-19

    申请号：AU6744887

    申请日：1987-01-09

    Applicant: HOECHST AG

    Inventor： BRINDOPKE GERHARD

    IPC: B05D7/24 ,  B01J27/08 ,  B01J31/06 ,  C07B61/00 ,  C07D317/36 ,  C08G18/65 ,  C08G71/00 ,  C08G59/14 ,  C08G18/30 ,  C08G18/58 ,  C07D317/38

    Abstract: A process for the preparation of 2-oxo-1,3-dioxolanes by reaction of epoxides with carbon dioxide in the presence of alkali iodides wherein at least one epoxy compound is reacted in the presence or absence of inert solvent either with a combination of A) at least one alkali iodide and B) at least one compound of the group a) polyol and b) an ether or polyether or, if the epoxy compound already has the structural features of the compounds Ba) and Bb), with the alkali iodide A) alone, at temperatures from 40 DEG to 180 DEG C. while introducing carbon dioxide at normal pressure or at slightly increased pressure, to form the corresponding organic carbonates. The 2-oxo-1,3-dioxolanes obtained are used for the preparation of synthetic resins, containing urethane groups, in the form of coatings of molded bodies.

    POLYMERIC MICHAEL ADDITION REACTION PRODUCTS
    20.
    发明专利
    POLYMERIC MICHAEL ADDITION REACTION PRODUCTS 未知

    公开(公告)号：AU572640B2

    公开(公告)日：1988-05-12

    申请号：AU4080785

    申请日：1985-04-03

    Applicant: HOECHST AG

    Inventor： BRINDOPKE GERHARD ,  WALZ GERD ,  WALDMANN KARL ,  SCHON MANFRED

    IPC: C08G61/12 ,  C07D487/04 ,  C07D487/10 ,  C08F8/00 ,  C08F236/02 ,  C08F299/02 ,  C08G16/00 ,  C08G18/81 ,  C08G18/83 ,  C08G61/00 ,  C08G61/10 ,  C09D165/00 ,  C08F2/00 ,  C08F8/30 ,  C08F8/34 ,  C08F8/40 ,  C08F220/20 ,  C08F220/34 ,  C08F220/36 ,  C08F220/38 ,  C08F265/04 ,  C08G81/02 ,  C08J3/24 ,  C09D3/48

    Abstract: A 3-component lacquer composed of A) compounds containing at least two R1R2C=CR3-X groups (I) wherein R1 denotes hydrogen or a hydrocarbon radical having 1 to 10 carbon atoms, R2 and R3 are individually hydrogen, a hydrocarbon radical having 1 to 10 carbon atoms, an ester group containing the radical R4 of a monohydric alcohol having up to 12 carbon atoms, -CN, -NO2 or a -CO-NHR1 or -CO-R1 group, X is -CO- which is attached to a further R1R2C=CR3- group either directly or via the radical of a polyhydric alcohol or of an amine and B) compounds containing: (a) at least two active H atoms or (b) at least two groups having active H atoms of the type -AH (II) or (c) at least one active H atom and at least one group of the type (II) and A is -CH- or -NH- or -S- and optionally with customary additives and C) at least one catalyst selected from the group consisting of diazabicyclooctane (DABCO), fluorides of quaternary ammonium compounds on their own or as a mixture with alkyl silicates, amidines, tertiary phosphanes of the formula P(CH2-Y)3 in which the Ys are identical or different and are -OH, -CH2CN or -N(Z)2 in which Z is an alkyl having 1 to 5 carbon atoms, tertiary phosphanes of the formula P(R4,R5,R6) in which R4, R5 and R6 are alkyl of 1 to 12 carbon atoms or a phenyl which is unsubstituted or substituted by at least one alkyl, alkoxy or dialkylamino, each of which has 1 to 4 carbon atoms in the alkyl, and R4, R5 and R6 are identical or different, but at least one of them is phenyl, and aminophosphoranes of the formula (R7,R8,R9) P=N-C (R10, R11,R12) in which R7, R8 and R9 are identical or different and denote an alkyl having 1 to 12 carbon atoms or a alkoxy or dialkylamino group, each of which has 1 to 4 carbon atoms in the alkyl, and R10, R11 and R12 are identical or different and each represents an alkyl having 1 to 5 carbon atoms or a phenyl.

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