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    12.
    发明专利
    未知

    公开(公告)号：DE3504337A1

    公开(公告)日：1986-08-14

    申请号：DE3504337

    申请日：1985-02-08

    Applicant: HOECHST AG

    Inventor： JUST CHRISTOPH DR ,  PLATH DIETER DR ,  WALZ GERD DR

    IPC: C08F222/22 ,  C08F246/00 ,  C09D135/00 ,  C09D175/14 ,  C08F220/00 ,  C08F212/00 ,  C08F218/04 ,  C09D3/727

    Abstract: Copolymers based on (A) 5-95% by weight of at least one polymerizable carbamoyloxyalkyldicarboxylic acid ester, carrying hydroxyl groups, of the general formula I in which R1 represents hydrogen or alkyl or hydroxyalkyl having in each case 1 to 30 carbon atoms in the alkyl radical, R2 represents alkyl or hydroxyalkyl having in each case 1 to 30 carbon atoms in the alkyl radical, or the radical subject to the proviso that R1 is hydrogen and x is an integer from 2 to 10, R3 represents linear or branched alkylene having 2 to 5 carbon atoms, R4 represents hydrogen or methyl and R5 represents hydroxyalkyl or hydroxyaminoalkyl having in each case 2 to 20 carbon atoms in the alkyl radical, or an alkyl radical of this type which also contains ester groups and/or ether groups, and (B) 5-95% by weight of at least one copolymerizable monomer belonging to the group comprising (a) alpha , beta -olefinically unsaturated monocarboxylic acid and alkyl and hydroxyalkyl esters thereof having in each case 1 to 18 carbon atoms in the alkyl radical, and amides and nitriles thereof, and also monoalkyl and dialkyl esters of alpha , beta -olefinically unsaturated dicarboxylic acids having 1 to 18 carbon atoms in the alkyl radical, (b) vinyl-aromatic monomers, (c) vinyl esters of organic monocarboxylic acids having 1 to 18 carbon atoms in the carboxylic acid radical, and (d) glycidyl esters of unsaturated monocarboxylic and/or dicarboxylic acids, the sum of the components (A) and (B) being in all cases 100% by weight, and a process for their preparation. The copolymers are used for the preparation of shaped articles and/or coatings which have excellent properties.

    15.
    发明专利
    未知

    公开(公告)号：DE3779411D1

    公开(公告)日：1992-07-02

    申请号：DE3779411

    申请日：1987-12-21

    Applicant: HOECHST AG

    Inventor： JUST CHRISTOPH DR ,  DUERR HELMUT DR ,  BRINDOEPKE GERHARD DR

    IPC: C08L61/20 ,  C08G18/62 ,  C08G18/65 ,  C08L33/04 ,  C08L33/14 ,  C08L75/04 ,  C09D137/00 ,  C09D175/04 ,  C09J137/00 ,  C09J175/00

    Abstract: A hardenable mixt. contains (A) cpds. contg. 1,3-dioxolane-2-one gps., gps. reactive with NCO, and opt. other gps., (B) polyisocyanates and/or aminoplast resins, and (C) opt. other hardenable cpds. The gps. reactive with NCO are OH. Cpd. (A) has (a) 3-95 (5-70)% of units from an olefinically unsatd. monomer contg. 1,3-dioxolane-2-one gps., pref. statistically distributed over the chain of (A) and esp. of formula (I); (b) 95-7 (95-30)% of an olefinically unsatd. copolymerisable monomer contg. OH gps., esp. an OH-contg. ester of an unsatd. mono- or di-carboxylic acid with a 1-8C alcohol, and (c) up to 90% of copolymerisable olefinically unsatd. monomer(s); component (c) is esp. a vinylaromatic hydrocarbon, an ester, amide or nitrile of an olefinically unsatd. mono- or di-carboxylic acid, etc. The polyisocyanate in the conversion prod. from 3 mols. of hexamethylene diisocyanate and 1 mol. of water. The aminoplast is a melamine resin. The component (C) is a phenol resin. n = 1-6; R1 = H, alkyl or COOR'; R2, R' = H or alkyl; R3 = H, Me or Et.

    16.
    发明专利
    未知

    公开(公告)号：DE3674810D1

    公开(公告)日：1990-11-15

    申请号：DE3674810

    申请日：1986-01-29

    Applicant: HOECHST AG

    Inventor： JUST CHRISTOPH DR ,  PLATH DIETER DR ,  WALZ GERD DR

    IPC: C08F222/22 ,  C08F246/00 ,  C09D135/00 ,  C09D175/14

    Abstract: Copolymers based on (A) 5-95% by weight of at least one polymerizable carbamoyloxyalkyldicarboxylic acid ester, carrying hydroxyl groups, of the general formula I in which R1 represents hydrogen or alkyl or hydroxyalkyl having in each case 1 to 30 carbon atoms in the alkyl radical, R2 represents alkyl or hydroxyalkyl having in each case 1 to 30 carbon atoms in the alkyl radical, or the radical subject to the proviso that R1 is hydrogen and x is an integer from 2 to 10, R3 represents linear or branched alkylene having 2 to 5 carbon atoms, R4 represents hydrogen or methyl and R5 represents hydroxyalkyl or hydroxyaminoalkyl having in each case 2 to 20 carbon atoms in the alkyl radical, or an alkyl radical of this type which also contains ester groups and/or ether groups, and (B) 5-95% by weight of at least one copolymerizable monomer belonging to the group comprising (a) alpha , beta -olefinically unsaturated monocarboxylic acid and alkyl and hydroxyalkyl esters thereof having in each case 1 to 18 carbon atoms in the alkyl radical, and amides and nitriles thereof, and also monoalkyl and dialkyl esters of alpha , beta -olefinically unsaturated dicarboxylic acids having 1 to 18 carbon atoms in the alkyl radical, (b) vinyl-aromatic monomers, (c) vinyl esters of organic monocarboxylic acids having 1 to 18 carbon atoms in the carboxylic acid radical, and (d) glycidyl esters of unsaturated monocarboxylic and/or dicarboxylic acids, the sum of the components (A) and (B) being in all cases 100% by weight, and a process for their preparation. The copolymers are used for the preparation of shaped articles and/or coatings which have excellent properties.

    POLYMERIZABLE, HYDROXYLIC GROUPS BEARING CARBAMOYLOXYALKYLDICARBOXYLIC ACID ESTERS, PROCESS FOR THEIR PREPARATION AND THEIR USE
    18.
    发明专利
    POLYMERIZABLE, HYDROXYLIC GROUPS BEARING CARBAMOYLOXYALKYLDICARBOXYLIC ACID ESTERS, PROCESS FOR THEIR PREPARATION AND THEIR USE 未知

    公开(公告)号：DE3662879D1

    公开(公告)日：1989-05-24

    申请号：DE3662879

    申请日：1986-01-29

    Applicant: HOECHST AG

    Inventor： JUST CHRISTOPH DR ,  PLATH DIETER DR ,  WALZ GERD DR

    IPC: C08F22/22 ,  C08F222/22 ,  C07C125/06

    Abstract: Polymerizable carbamoyloxyalkyldicarboxylic acid esters, carrying hydroxyl groups, of the general formula (I) (I) in which R1 represents hydrogen or allyl or hydroxyalkyl having in each case 1 to 30 carbon atoms in the alkyl radical, R2 represents alkyl or hydroxyalkyl having in each case 1 to 30 carbon atoms in the alkyl radical or the radical subject to the proviso that R1 is hydrogen and x is an integer from 2 to 20, R3 represents linear or branched alkylene having 2 to 5 carbon atoms, R4 represents hydrogen or methyl and R5 represents hydroxyalkyl or hydroxyaminoalkyl having in each case 2 to 20 carbon atoms in the alkyl radical or an alkyl radical of this type which also contains ester and/or ether groups, and a process for their preparation. The esters according to the invention can be used for the preparation of copolymers.

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