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公开(公告)号:DD232652A5
公开(公告)日:1986-02-05
申请号:DD25247283
申请日:1983-06-28
Applicant: HOECHST AG
Inventor: REBSDAT SIEGFRIED , MAYER SIGMUND , ALFRANSEDER JOSEF
IPC: B01J23/66 , B01J37/02 , C07B61/00 , C07D301/10 , C07D303/04
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公开(公告)号:DD209749A5
公开(公告)日:1984-05-23
申请号:DD25022483
申请日:1983-04-26
Applicant: HOECHST AG
Inventor: REBSDAT SIEGFRIED , MAYER SIGMUND , ALFRANSEDER JOSEF
IPC: B01J23/54 , B01J23/66 , C07D301/10 , B01J27/24
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公开(公告)号:BR8304218A
公开(公告)日:1984-03-13
申请号:BR8304218
申请日:1983-08-05
Applicant: HOECHST AG
Inventor: REBSDAT SIEGFRIED , MAYER SEGMUND , ALFRANSEDER JOSEF
IPC: B01J23/66 , B01J23/96 , B01J38/48 , C07B61/00 , C07D301/10 , C07D301/04
Abstract: A method for improving the activity of a used supported silver catalyst, used for the manufacture of ethylene oxide by reaction of ethylene with oxygen or air, which method consists essentially of: (a) impregnating said used catalyst at a temperature from 80 DEG C. to 150 DEG C. and for 0.75 hour to 10 hours with an impregnating solution containing water, a water-miscible organic solvent selected from the group consisting of methanol, ethanol, propanol, and isopropanol, at least one compound of cesium, rubidium, or of cesium and rubidium in an amount providing from 50 mg to 1000 mg per kilogram of solution, said solution containing from 5 to 50 percent by weight of water; (b) separating the impregnated catalyst from excess impregnating solution; and (c) drying the impregnated catalyst.
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公开(公告)号:AU1639283A
公开(公告)日:1984-01-05
申请号:AU1639283
申请日:1983-06-29
Applicant: HOECHST AG
Inventor: REBSDAT SIEGFRIED , MAYER SIGMUND , ALFRANSEDER JOSEF
IPC: B01J23/58 , B01J23/66 , B01J37/02 , C07D301/10 , B01J23/02
Abstract: Silver catalysts, useful for the oxidation of ethylene to ethylene oxide, contain 3-20 percent by weight of silver and 0.003-0.05 percent by weight of potassium, rubidium, cesium, or a mixture thereof as a promoter present on a heat-resistant porous support to which they have been applied by several impregnating steps.
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公开(公告)号:AU522992B2
公开(公告)日:1982-07-08
申请号:AU3964178
申请日:1978-09-07
Applicant: HOECHST AG
Inventor: REBSDAT SIEGFRIED , MAYER SIEGMUND , ALFRANSEDER JOSEF , RIEDL JOSEF
IPC: B01J23/96 , B01J38/48 , C07B61/00 , C07D301/10 , C07D303/04 , B01J23/66
Abstract: The activity of supported silver catalysts, which have been used for the direct oxidation of ethylene to ethylene oxide with molecular oxygen or air and to which from 1 to 1,000 parts, per 1 million parts of catalyst, of cesium and/or rubidium have been applied, is improved by washing the catalyst with an inert liquid prior to the application of cesium and/or rubidium.
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公开(公告)号:CA960698A
公开(公告)日:1975-01-07
申请号:CA115203
申请日:1971-06-09
Applicant: HOECHST AG
Inventor: SCHUIERER ERICH , ULM KLAUS , REBSDAT SIEGFRIED , WIMMER IGNAZ
IPC: C07C29/12 , C07C31/38 , C07C31/40 , C07C203/00 , C07C203/04
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公开(公告)号:CA878024A
公开(公告)日:1971-08-10
申请号:CA878024D
Applicant: HOECHST AG
Inventor: SCHUIERER ERICH , HAHN HELMUT , REBSDAT SIEGFRIED , MULLER KLAUS-DIETER
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公开(公告)号:CA869592A
公开(公告)日:1971-04-27
申请号:CA869592D
Applicant: HOECHST AG
Inventor: RUCHLAK KASIMIR , REBSDAT SIEGFRIED , SCHUIERER ERICH , HAHN HELMUT
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公开(公告)号:MX162490A
公开(公告)日:1991-05-13
申请号:MX19787683
申请日:1983-06-30
Applicant: HOECHST AG
Inventor: REBSDAT SIEGFRIED , MAXER SIGMUND , ALFRANSEDER JOSEF
IPC: B01J23/58 , B01J23/66 , B01J37/02 , C07D301/10 , C07D303/04
Abstract: Silver catalysts, useful for the oxidation of ethylene to ethylene oxide, contain 3-20 percent by weight of silver and 0.003-0.05 percent by weight of potassium, rubidium, cesium, or a mixture thereof as a promoter present on a heat-resistant porous support to which they have been applied by several impregnating steps.
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公开(公告)号:HU190487B
公开(公告)日:1986-09-29
申请号:HU145783
申请日:1983-04-28
Applicant: HOECHST AG
Inventor: REBSDAT SIEGFRIED , MAYER SIGMUND , ALFRANSEDER JOSEF
IPC: B01J23/54 , B01J23/66 , C07D301/10 , B01J23/50
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