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公开(公告)号:SE434804B
公开(公告)日:1984-08-20
申请号:SE7712150
申请日:1977-10-27
Applicant: HOECHST AG
Inventor: REBSDAT S , MAYER S , ALFRANSEDER J , RIEDL J
IPC: B01J23/66 , B01J23/96 , B01J31/40 , B01J38/48 , C07B61/00 , C07D301/10 , C07D303/04 , B01J23/54
Abstract: The activity of supported silver catalysts for the direct oxidation of ethylene to ethylene oxide with molecular oxygen or air is improved by applying to the catalyst from 1 to 1,000 ppm, preferably 20 to 500 ppm, of cesium and/or rubidium in two or more than two steps and using the catalyst after each impregnation step again for the production of ethylene oxide by direct oxidation of ethylene with molecular oxygen or air.
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公开(公告)号:DK142982B
公开(公告)日:1981-03-09
申请号:DK105172
申请日:1972-03-07
Applicant: HOECHST AG
Inventor: JACOBOWSKY A , RECHMEIER G , RIEDL J , FROEHLICH W , MITTERMAIER E
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公开(公告)号:BR8003412A
公开(公告)日:1980-12-30
申请号:BR8003412
申请日:1980-05-30
Applicant: HOECHST AG
IPC: B01J23/00 , B01J23/72 , B01J23/74 , B01J27/10 , B01J27/122 , B01J27/128 , C07B61/00 , C07C17/00 , C07C17/02 , C07C17/156 , C07C19/045 , C07C67/00 , C07C17/15
Abstract: A process for the manufacture of 1,2-dichloroethane from ethylene by reaction with hydrogen chloride and inert gases containing oxygen, and also by reaction with chlorine, is described. The two chlorination reactions are carried out successively at 180 DEG to 360 DEG C. and under a pressure of 0.09 to 1.1 MPa in a common reaction space containing fluidized catalyst particles. A stoichiometric excess of ethylene is employed for the first chlorination reaction. The heat formed in the reaction space is removed by indirect cooling. The process is simple in terms of apparatus and permits a better re-use of the total heat of reaction of the chlorination of ethylene.
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公开(公告)号:BR7707210A
公开(公告)日:1978-07-25
申请号:BR7707210
申请日:1977-10-27
Applicant: HOECHST AG
Inventor: RIEDL J , REBSDAT S , MAYER S , ALFRANSEDER J
IPC: B01J23/66 , B01J23/96 , B01J31/40 , B01J38/48 , C07B61/00 , C07D301/10 , C07D303/04 , B01J31/04 , B01J31/02
Abstract: The activity of supported silver catalysts for the direct oxidation of ethylene to ethylene oxide with molecular oxygen or air is improved by applying to the catalyst from 1 to 1,000 ppm, preferably 20 to 500 ppm, of cesium and/or rubidium in two or more than two steps and using the catalyst after each impregnation step again for the production of ethylene oxide by direct oxidation of ethylene with molecular oxygen or air.
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公开(公告)号:NO751170A
公开(公告)日:1975-10-07
申请号:NO751170
申请日:1975-04-04
Applicant: HOECHST AG
Inventor: RIEDL J , FROEHLICH W , MITTERMAIER E
CPC classification number: C07C17/25 , B01J12/005 , B01J19/242 , B01J2219/00006 , B01J2219/00157 , B01J2219/00159 , B01J2219/00186 , C07C17/395 , C07C21/06
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公开(公告)号:ZA8003244B
公开(公告)日:1981-06-24
申请号:ZA8003244
申请日:1980-05-30
Applicant: HOECHST AG
IPC: B01J23/00 , B01J23/72 , B01J23/74 , B01J27/122 , B01J27/128 , C07B61/00 , C07C17/00 , C07C17/02 , C07C17/156 , C07C19/045 , C07C67/00 , C07C
CPC classification number: C07C17/156 , C07C19/045
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公开(公告)号:BR8005991A
公开(公告)日:1981-03-31
申请号:BR8005991
申请日:1980-09-19
Applicant: HOECHST AG
Inventor: MAYER S , ALFRANSEDER J , RIEDL J , REBSDAT S , SCHAFFELHOFER I
IPC: B01J23/50 , B01J23/66 , B01J23/68 , B01J23/96 , B01J38/48 , B01J38/66 , C07B61/00 , C07D301/10 , C07D303/04
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公开(公告)号:AU511144B2
公开(公告)日:1980-07-31
申请号:AU2789877
申请日:1977-08-15
Applicant: HOECHST AG
Inventor: REBSDAT S , MAYER S , ALFRANSEDER J , RIEDL J
Abstract: The activity of supported silver catalysts used up in the direct oxidation of ethylene with molecular oxygen or air is improved by impregnating the catalyst arranged in a fixed bed with a solution of a caesium and/or rubidium compound in an inert organic solvent, optionally together with up to 40% by weight of water, calculated on the total liquid, as dissolving intermediary, so as to produce a concentration gradient of from 0.3 to 20 parts of caesium and/or rubidium per 1 million parts of catalyst and per meter of fixed bed, counter to the direction of flow of the gas to be reacted. In this manner the activity of the catalyst is considerably improved which results in an increased selectivity of the oxidation of ethylene to ethylene oxide.
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公开(公告)号:BR7705359A
公开(公告)日:1978-06-06
申请号:BR7705359
申请日:1977-08-12
Applicant: HOECHST AG
Inventor: ALFRANSEDER J , MAYER S , REBSDAT S , RIEDL J
Abstract: The activity of supported silver catalysts used up in the direct oxidation of ethylene with molecular oxygen or air is improved by impregnating the catalyst arranged in a fixed bed with a solution of a caesium and/or rubidium compound in an inert organic solvent, optionally together with up to 40% by weight of water, calculated on the total liquid, as dissolving intermediary, so as to produce a concentration gradient of from 0.3 to 20 parts of caesium and/or rubidium per 1 million parts of catalyst and per meter of fixed bed, counter to the direction of flow of the gas to be reacted. In this manner the activity of the catalyst is considerably improved which results in an increased selectivity of the oxidation of ethylene to ethylene oxide.
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公开(公告)号:SE7712150L
公开(公告)日:1978-04-30
申请号:SE7712150
申请日:1977-10-27
Applicant: HOECHST AG
Inventor: REBSDAT S , MAYER S , ALFRANSEDER J , RIEDL J
IPC: B01J23/66 , B01J23/96 , B01J31/40 , B01J38/48 , C07B61/00 , C07D301/10 , C07D303/04 , B01J23/54 , C07D
Abstract: The activity of supported silver catalysts for the direct oxidation of ethylene to ethylene oxide with molecular oxygen or air is improved by applying to the catalyst from 1 to 1,000 ppm, preferably 20 to 500 ppm, of cesium and/or rubidium in two or more than two steps and using the catalyst after each impregnation step again for the production of ethylene oxide by direct oxidation of ethylene with molecular oxygen or air.
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