13.
    发明专利
    未知

    公开(公告)号:FI68066C

    公开(公告)日:1985-07-10

    申请号:FI802190

    申请日:1980-07-09

    Applicant: HOECHST AG

    Abstract: Vinyl polymers with acetylacetoxy groups form the basis of polymer dispersions which are used as binding agent dispersions in paints, particularly suitable vinyl polymers are obtained by polymerizing an acetylacetoxy compound together with a least one further olefinically unsaturated compound, while using as acetylacetoxy compound an allyl ether derivative of the formula or The copolymerization is carried out in particular in emulsion at a temperature in the range of from -30 DEG to 200 DEG C. As comonomers there are used especially vinyl esters and (meth-)acrylic acid esters. The polymerization is commonly effected in the presence of a radical-forming initiator and optionally in the presence of emulsifiers and protective colloids.

    ACETYLACETOXYALKYL-ALLYL ETHERS,THEIR MANUFACTURE

    公开(公告)号:AU531700B2

    公开(公告)日:1983-09-01

    申请号:AU6028580

    申请日:1980-07-10

    Applicant: HOECHST AG

    Abstract: Unsaturated acetoacetic acid esters are suitable as comonomers in the polymerization of unsaturated compounds in an aqueous medium. Particularly suitable are acetylacetoxyalkyl-allyl ethers which may be synthesized in an easy manner and correspond to the formulae or Said allyl ether derivatives are especially prepared by reacting an allyl alcohol with an epoxide and reacting the resulting hydroxyalkyl-allyl ether with diketene. Both reaction steps are carried out at a temperature of from 0 DEG to 100 DEG C., preferably in the presence of a catalyst. The allyl ether derivatives may be copolymerized especially with vinyl compounds, such as vinyl esters, acrylic acid esters, olefins, vinyl halides and vinyl aromatic hydrocarbons.

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