公开(公告)号：DE19536076A1

公开(公告)日：1997-04-17

申请号：DE19536076

申请日：1995-09-28

Applicant: HOECHST AG

Inventor： SCHARBERT BERND DR ,  LOBMAIER GERHARD ,  HERRMANN WOLFGANG ANTON PROF D

IPC: B01J31/16 ,  B01J31/18 ,  B01J31/22 ,  C07D301/06 ,  B01J31/12 ,  C07D301/08 ,  C07D303/04

Abstract: Catalysts for selective epoxidation of alkenes are of formula MxOy(L)z (I), where x = 1, 2 or 3; y = 1 to 2x+1, such that x+z = a metal oxidn. no. of +5 (V) or +6 (Mo, Ru); z = 2 to 2x; M = Mo, Ru or V; and L = an N, O or S donor ligand. Also claimed are heterogeneous catalysts for selective oxidn. of olefins in the presence of O2, which contain an (in)organic support and (I); and the use of (I) in the selective epoxidation of alkenes of formula R R C=CR R (II) with atmos. O2. In formula (II), R = H, 1-20C alkyl, 1-12C alkoxy or 6-10C aryl; or R + R = a 5-30 C ring.

公开(公告)号：DE19519004A1

公开(公告)日：1996-11-28

申请号：DE19519004

申请日：1995-05-24

Applicant: HOECHST AG

Inventor： SCHULZ ROLF DR ,  SCHARBERT BERND DR ,  GELBARD GEORGES DR ,  VEDRINE JACQUES DR

IPC: B01J23/46 ,  B01J23/64 ,  B01J27/13 ,  B01J31/02 ,  B01J31/28 ,  B01J31/34 ,  C01B19/00 ,  C07B33/00 ,  C07C2/84 ,  C07C5/48 ,  C07C45/35 ,  C07C51/215 ,  C07C51/25 ,  C07C51/265 ,  C07C51/31 ,  C07D301/08 ,  B01J27/057 ,  B01J27/132 ,  B01J27/138 ,  B01J27/25 ,  B01J31/30 ,  C07B35/04 ,  C07C45/27 ,  C07C51/16

Abstract: Compounds for catalytic oxidation in the gaseous phase have the general formula (1) QaMbRucRdXeYfSegOh * H2Oi, in which the symbols Q, M, R, X, Y, a, b, c, d, e, f, g, h and i have the following meanings: Q stands for one or several elements selected in the group Na, K, Rb, Cs, NR R R R , Be, Mg, Ca, Sr, Ba, in which R , R , R and R represent independently from each other hydrogen, a C1-C20 alkyl or C1-C8 cycloalkyl residue, an aryl residue, in particular a methyl, ethyl, propyl or butyl residue; M stands for one or several elements among V, Mo, Wo; R stands for one or several elements selected in the group Sc, Y, La, Ce, Ti, Zr, Nb, Ta, V, Cr, Mn, Re, Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt, Cu; X stands for one or several elements among F, Cl, Br, J, NO3 , SO4 ; Y stands for one or several elements selected in the group Ga, In, Ge, Sn, S, Se, Te, P, As, Sb, Bi; a equals 1 to 30; b equals 5 to 50; c equals 0.1 to 10; d equals 0 to 10; e equals 0 to 20; f equals 0 to 10; g equals 0.01 to 10; h equals the number of oxygen atoms required to stochiometrically compensate for oxide formation; i equals 0 to 25.

公开(公告)号：ES2076642T3

公开(公告)日：1995-11-01

申请号：ES92115832

申请日：1992-09-16

Applicant: HOECHST AG

Inventor： SCHARBERT BERND DR

IPC: C07D213/61 ,  C07D213/30 ,  C07D213/46 ,  C07D213/63 ,  C07D213/71 ,  C07D213/79 ,  C07D213/803 ,  C07D213/81 ,  C07D213/84

公开(公告)号：DK0533132T3

公开(公告)日：1995-04-18

申请号：DK92115833

申请日：1992-09-16

Applicant: HOECHST AG

Inventor： SCHARBERT BERND DR

IPC: C07D213/79 ,  C07D213/803 ,  C25B3/23

Abstract: A process for the selective oxidation of hydroxymethylpyridine derivatives of the general formula I to pyridinecarboxylic acid derivatives thereof of the formula II on nickelic hydroxide anodes is described.

公开(公告)号：ES2066534T3

公开(公告)日：1995-03-01

申请号：ES92115833

申请日：1992-09-16

Applicant: HOECHST AG

Inventor： SCHARBERT BERND DR

IPC: C07D213/79 ,  C07D213/803 ,  C25B3/23

Abstract: A process for the selective oxidation of hydroxymethylpyridine derivatives of the general formula I to pyridinecarboxylic acid derivatives thereof of the formula II on nickelic hydroxide anodes is described.

公开(公告)号：AT113582T

公开(公告)日：1994-11-15

申请号：AT92115833

申请日：1992-09-16

Applicant: HOECHST AG

Inventor： SCHARBERT BERND DR

IPC: C07D213/79 ,  C07D213/803 ,  C25B3/23

Abstract: A process for the selective oxidation of hydroxymethylpyridine derivatives of the general formula I to pyridinecarboxylic acid derivatives thereof of the formula II on nickelic hydroxide anodes is described.

公开(公告)号：DE4217336C2

公开(公告)日：1994-08-04

申请号：DE4217336

申请日：1992-05-26

Applicant: HOECHST AG

Inventor： SCHARBERT BERND DR ,  BABUSIAUX PIERRE DR

IPC: C25B3/25 ,  C25B3/04 ,  C07C59/153

Abstract: In the prodn. of glyoxylic acid (I) by electrochemical redn. of oxalic acid (II) in aq. soln. in (un)divided cells, (a) the cathode consists of (a-1) carbon or (a-2) at least 50 (wt.)% Cu, Ti, Zr, V, Nb, Ta, Fe, Co, Ni, Sn, Zn, Al and/or Cr; and (b) the aq. electrolyte or catholyte contains metal salt(s) (III) with a H2 over-voltage of at least 0.25 V at a current density (c.d.) of 2500 A/dm2. Pref. suitable cathodes consist of (a-1) graphite, or (a-2) at least 50, pref. at least 80% Fe, Co, Ni, Cr, Cu and/or Ti; an alloy of 2 or more of the cited metals; at least 80, partic. at least 93% alloy of 2 or more of Fe, Co, Ni, Cr, Cu and Ti; 93-96% alloy, 0-20, pref. 4-7% other metal, pref. Mn, Ti and/or Mo, and 0-3, pref. 0-1.2% non-metal, pref. C, Si, P and/or S; stainless steel, esp. stainless Cr-Ni steel. (III) is used in a concn. of (a1) 10 power(-6) to 10, pref. 10 power(-5) to 10 power(-1), esp. 10 power(-4) to 4 x 10 power(-2)% or (a-2) 10 power(-7) to 10, pref. 10 power(-6) to 0.1, esp. 10 power(-5) to 0.04%. (III) pref. is a Cu, Ag, Au, Fe, Hg, Tl, Ti, Zr, V, Ta, Ce, Co, Ni or pref., Pb, Sn, Bi, Zn, Cd or Cr salt or combination of these, esp. a Pb salt. The (II) concn. is between 0.1M and the satn. concn. at the electrolysis temp.. The electrolyte may also contain 10 power(-7) to 10, pref. 10 power(-5) to 10 power(-1)% mineral or organic acid. The cell pref. has a separator, esp. of a cation exchange membrane of polymer with COOH and/or SO3H gps..

公开(公告)号：CZ9202866A3

公开(公告)日：1993-06-16

申请号：CS286692

申请日：1992-09-17

Applicant: HOECHST AG

Inventor： WEIDMANN KLAUS DR ,  BICKEL MARTIN DR ,  KESSELER KURT DR ,  SCHARBERT BERND DR

IPC: C07D213/81 ,  A61K20060101 ,  A61K31/44 ,  C07D20060101 ,  C07D213/89

公开(公告)号：DE19530786A1

公开(公告)日：1997-02-27

申请号：DE19530786

申请日：1995-08-22

Applicant: HOECHST AG

Inventor： REINHARDT GERD DR ,  FRIDERICHS VERA ,  SCHARBERT BERND DR ,  SCHULZ ROLF PETER DR ,  KREBS BERNT PROF DR ,  BOEHNER RAINER DIPL ING ,  THUELIG CHRISTIAN DIPL ING

IPC: A61K8/00 ,  A61K8/22 ,  A61K8/33 ,  A61K8/37 ,  A61K8/38 ,  A61K8/40 ,  A61K8/41 ,  A61K8/42 ,  A61K8/46 ,  A61K8/49 ,  A61K8/58 ,  A61K8/60 ,  A61Q11/02 ,  C11D3/39 ,  C11D3/395

Abstract: A bleach compsn. contains: (a) a bleaching agent; and (b) a polyoxymetallate as bleach catalyst.

公开(公告)号：DE19519008A1

公开(公告)日：1996-11-28

申请号：DE19519008

申请日：1995-05-24

Applicant: HOECHST AG

Inventor： SCHARBERT BERND DR ,  SCHULZ ROLF DR

IPC: B01J23/00 ,  B01J23/652 ,  B01J31/02 ,  B01J31/28 ,  B01J31/34 ,  C07D301/06 ,  B01J27/053 ,  B01J27/057 ,  B01J27/13 ,  B01J27/132 ,  B01J27/138 ,  B01J31/30 ,  B01J31/36 ,  C01B19/00 ,  C01G55/00

Abstract: Compounds for catalytic oxidation in the liquid phase have the general formula (1): QaMbRucRdXeYfZgOh * H2Oi, in which the symbols Q, M, R, X, Y, a, b, c, d, e, f, g, h and i have the following meanings: Q stands for one or several elements selected in the group Na, K, Rb, Cs, NR R R R , Be, Mg, Ca, Sr, Ba, in which R , R , R and R represent independently from each other hydrogen, a C1-C20 alkyl or C1-C8 cycloalkyl residue, an aryl residue, in particular a methyl, ethyl, propyl or butyl residue; M stands for one or several elements among V, Mo, Wo; R stands for one or several elements selected in the group Sc, Y, La, Ce, Ti, Zr, Nb, Ta, V, Cr, Mn, Re, Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt, Cu; X stands for one or several elements among F, Cl, Br, J, NO3 , SO4 ; Y stands for one or several elements selected in the group Ga, In, Ge, Sn, S, Se, Te, P, As, Sb, Bi; Z stands for S or Se; a equals 1 to 30; b equals 5 to 50; c equals 0.1 to 10; d equals 0 to 10; e equals 0 to 20; f equals 0 to 10; g equals 0.01 to 10; h equals the number of oxygen atoms required to stochiometrically compensate for oxide formation; i equals 0 to 25.