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    1.
    发明专利
    未知

    公开(公告)号：DE19530787A1

    公开(公告)日：1997-02-27

    申请号：DE19530787

    申请日：1995-08-22

    Applicant: HOECHST AG

    Inventor： SCHARBERT BERND DR ,  SCHULZ ROLF PETER DR ,  KREBS BERNT PROF DR ,  BOEHNER RAINER DIPL ING ,  THUELIG CHRISTIAN DIPL ING

    IPC: B01J23/34 ,  B01J27/02 ,  B01J27/187 ,  C01B19/00 ,  C01G45/00 ,  C11D3/02 ,  C11D3/39 ,  C11D3/395 ,  D21C9/10 ,  B01J27/057 ,  B01J31/34 ,  B01J27/132 ,  C11D7/54

    Abstract: Manganiferous catalytically active polyoxometalates of formula (1) (Q)q (MnpAaXxYyMmOdZz(H2O)b) c H2O and the process for the manufacture thereof. In formula (I), Q, A, X, Y, M, Z, q, p, a, x, y, m, z, d, b and c have the following meaning: Q represents one or more cations selected from the group H, Li, K, Na, Rb, Cs, Ca, Mg, Sr, Ba, Al, PR R R R and NR R R R with R , R , R et R representing H or C1-C20-alkyl, C5-C8-cycloalkyl or aryl; subscript q falls in a range of 1 to 60, more especially in a range of 1 to 40 and, in the case of a single-value counter-cation, also describes the charge on the anionic unit; Mn is manganese; subscript p falls in a range of 0.1 to 10, A is a heterometal and represents one or more transitional metals of the 2 to 8 subsidiary groups except for Zn, especially Ru, V, Ti, Zr, Cr, Fe, Co, Cu, Sn, Ni, Re or Os; subscript a falls in a range of 0 to 10; X represents one or more elements selected from the group Ga, B, P, Si, Ge, As, F, Cl, Br and J; subscript x falls in the range of 0 to 10; Y represents Sb, S, Se, Te or Bi; subscript y falls in the range of 0.1 to 10; M represents one or more transition metals selected from the group Mo, W, Nb, Ta and V; subscript m falls in the range of 0.5 to 60; Z represents one or more anions selected from the group OH , F , Cl , Br , I , N3 , NO3 , ClO4 , NCS-, SCN-, PF6 , RSO3 , RSO4 , CF3SO3 , BR4 , BF4 , OAc with R = H, C1-C20-alkyl, C5-C8-cycloalkyl or aryl; subscript z falls in the range 0 to 10; subscript d represents the number of oxygen atoms necessary to balance the charge and b and c are numbers in the range 0 to 50. The oxidisation catalysts described are particularly good for activating peroxide compounds and oxygen.

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