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公开(公告)号：NO128166B
公开(公告)日：1973-10-08
申请号：NO482868
申请日：1968-12-03
Applicant: HOECHST AG
Inventor： OBERST H , EBIGT J , DUVE G , SCHOMMER A
IPC: C08F291/00 , F16K11/052 , C08F41/00 , C09J3/14 , F16F15/02 , B32B15/08
Abstract: 1,246,997. Vibration damping laminates. FARBWERKE HOECHST A.G. 4 Dec., 1968 [6 Dec., 1967], No. 57606/68. Heading B5N. [Also in Divisions B2 and C3] A vibration damping laminated system comprises two plates, e.g. of metal such as steel, bonded together with an interlayer comprising a graft polymer of 40-80% by weight of a equimolar mixture of styrene and acrylonitrile on 60-20% by weight of a copolymer of 30-40% by weight of vinyl acetate, 30-40% by weight of 2-ethylhexyl acrylate, 10-30% by weight di-n-butyl maleate and 5-15% by weight of a copolymerizable unsaturated caroxylic acid, e.g. crotonic acid. The graft polymer may be cross-linked with a compound containing a plurality of epoxide or isocyanate groups. The graft polymer may contain minor amounts of fillers, e.g. heavy spar, silicic acid, graphite, soot or a mixture thereof, and one or more plasticizers. The total thickness of the laminated system may be 1-6 mm., the thickness of the interlayer being 0À1-1 mm. and the ratio of the thickness of the plates being from 1 : 1 to 4 : 1. The graft polymer may be applied to the plates by trowelling, brushing or pouring at an elevated temperature and the system cooled under pressure between rollers. A solution of the copolymer in the mixture of styrene and acrylonitrile containing a polymerization initiator, e.g. tertiary butyl hydroperoxide, may be applied between the plates and the laminated system subjected to heating at 60-180 C. to effect grafting.
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公开(公告)号：NO128164B
公开(公告)日：1973-10-08
申请号：NO476668
申请日：1968-11-28
Applicant: HOECHST AG
Inventor： OBERST H , EBIGT J , DUVE G , SCHOMMER A
Abstract: 1,254,117. Vibration damping laminates. FARBWERKE HOECHST A.G. 3 Dec., 1968 [5 Dec., 1967], No. 57351/68. Heading B5N. [Also in Divisions B2 and C3] A vibration damping laminated system comprises two plates bonded together by an interlayer comprising a graft polymer of from 35 to 65% by weight, based on the weight of the graft polymer, of styrene or a mixture of styrene and from 0À1 to 10% by weight, based on the weight of styrene, of a copolymerizable carboxylic acid, or from 65 to 35% by weight, based on the weight of the graft polymer, of a copolymer containing from 10 to 30 parts by weight of units derived from vinyl acetate and from 70 to 90 parts by weight of units derived from ethylene, the total number of parts by weight of the various units in the copolymer being 100. The copolymerizable carboxylic acid may be acrylic, methacrylic or a mixture thereof and the plates may be of steel. The graft polymer may be applied to the plates by travelling, brushing or pouring at elevated temperature and the system is cooled under pressure between rollers, or a gel of the copolymer in styrene or the styrene/carboxylic acid mixture containing a polymerization initiator is applied between the plates and the resulting system is heated to form the graft polymer in situ.
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公开(公告)号：SE360095B
公开(公告)日：1973-09-17
申请号：SE1649868
申请日：1968-12-03
Applicant: HOECHST AG
Inventor： OBERST H , EBIGT J , DUVE G , SCHOMMER A
Abstract: 1,249,140. Vibration damping laminates. FARBWERKE HOECHST A.G. 4 Dec., 1968 [6 Dec., 1967], No. 57602/68. Heading B5N. [Also in Divisions B2 and C3] A vibration damping laminated system comprises two plates, e.g. of metal such as steel, bonded together with an interlayer comprising a graft polymer of 40-80% by weight of styrene or a mixture of styrene with 0À1-10% by weight, based on the weight of styrene, of a copolymerizable carboxylic acid, e.g. acrylic and/or methacrylic acid, on 60-20% by weight of a copolymer of 30-40% by weight of vinyl acetate, 30-40% by weight of 2-ethylhexyl acrylate, 10-30% by weight of di-n-butyl maleate and 5-15% by weight of a copolymerizable unsaturated carboxylic acid, e.g. crotonic acid. The graft polymer may be crosslinked with a compound containing a plurality of epoxide or isocyanate groups. The graft polymer may contain minor amounts of fillers, e.g. heavy spar, silicic acid, graphite, soot or a mixture thereof, and one or more plasticizers. The total thickness of the laminated system may be 1-6 mm., the thickness of the interlayer being 0À1-1 mm. and the ratio of the thickness of the plates being from 1 : 1 to 4 : 1. The graft polymer may be applied to the plates by trowelling, brushing or pouring at an elevated temperature and the system cooled under pressure between rollers. A solution of the copolymer in styrene or a mixture of styrene and 0À1-10% by weight of copolymerizable acid containing a polymerization initiator, e.g. tertiary butyl hydroperoxide, may be applied between the plates and the laminated system subjected to heating at 60-180 C. to effect grafting.
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公开(公告)号：DK122187B
公开(公告)日：1972-01-31
申请号：DK593668
申请日：1968-12-04
Applicant: HOECHST AG
Inventor： SCHOMMER A , EBIGT J , DUVE G , OBERST H
IPC: C08F255/02 , E04B1/98 , C08F41/00 , B32B15/08 , C08J1/40
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公开(公告)号：DK122186B
公开(公告)日：1972-01-31
申请号：DK593568
申请日：1968-12-04
Applicant: HOECHST AG
Inventor： SCHOMMER A , EBIGT J , DUVE G , OBERST H
IPC: C08F255/02 , E04B1/98 , C08F41/00 , B32B15/08 , C08J1/40
Abstract: 1,254,117. Vibration damping laminates. FARBWERKE HOECHST A.G. 3 Dec., 1968 [5 Dec., 1967], No. 57351/68. Heading B5N. [Also in Divisions B2 and C3] A vibration damping laminated system comprises two plates bonded together by an interlayer comprising a graft polymer of from 35 to 65% by weight, based on the weight of the graft polymer, of styrene or a mixture of styrene and from 0À1 to 10% by weight, based on the weight of styrene, of a copolymerizable carboxylic acid, or from 65 to 35% by weight, based on the weight of the graft polymer, of a copolymer containing from 10 to 30 parts by weight of units derived from vinyl acetate and from 70 to 90 parts by weight of units derived from ethylene, the total number of parts by weight of the various units in the copolymer being 100. The copolymerizable carboxylic acid may be acrylic, methacrylic or a mixture thereof and the plates may be of steel. The graft polymer may be applied to the plates by travelling, brushing or pouring at elevated temperature and the system is cooled under pressure between rollers, or a gel of the copolymer in styrene or the styrene/carboxylic acid mixture containing a polymerization initiator is applied between the plates and the resulting system is heated to form the graft polymer in situ.
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Patent Agency Ranking
公开(公告)号：SE330985B
公开(公告)日：1970-12-07
申请号：SE558467
申请日：1967-04-20
Applicant: HOECHST AG
Inventor： SCHOMMER A , EBIGT J , DUVE G , OBERST H , REIHS L
Abstract: Vibration damped sandwich systems having an improved damping effect within a broad range of temperature and consisting of hard plates and a vibration damping interlayer, said interlayer comprising a copolymer of vinyl acetate, ethylene and a mixture of isononane-, isodecane- and isoundecane-carboxylic acid vinyl esters and acrylic and/or methacrylic acid.
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公开(公告)号：NO128163B
公开(公告)日：1973-10-08
申请号：NO476568
申请日：1968-11-28
Applicant: HOECHST AG
Inventor： OBERST H , EBIGT J , DUVE G , SCHOMMER A
Abstract: 1,252,895. Vibration damping laminated systems. FARBWERKE HOECHST A.G. 3 Dec., 1968 [5 Dec., 1967], No. 57350/68. Heading B5N. [Also in Divisions B2 and C3] A vibration damping laminated system comprises two plates, e.g. of metal such as steel, bonded together with an interlayer comprising a graft polymer of 55-90% by weight of an equimolar mixture of styrene and acrylonitrile on 45-10% by weight of a copolymer of 30-- 50% by weight of vinyl acetate and 50-70% by weight of ethylene. The graft polymer may contain minor amounts of fillers, e.g. heavy spar, silicic acid, graphite, soot or a mixture thereof, and one or more plasticizers. The total thickness of the laminated system may be 1-6 mm., the thickness of the interlayer being 0À1-1 mm. and the ratio of the thicknesses of the plates being from 1 : 1 to 4 : 1. The graft polymer may be applied to the plates by trowelling, brushing or pouring at elevated temperature and the system cooled under pressure between rollers. A gel of the copolymer in the styrene/acrylonitrile mixture to be grafted on which contains a polymerization initiator, e.g. tertiary butyl hydroperoxide, may be applied between the plates and the laminated system subjected to heating at 60-180 C. to effect grafting.
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公开(公告)号：NO128160B
公开(公告)日：1973-10-08
申请号：NO478368
申请日：1968-11-29
Applicant: HOECHST AG
Inventor： OBERST H , EBIGT J , DUVE G , SCHOMMER A
Abstract: 1,245,470. Laminates. FARBWERKE HOECHST A.G. 4 Dec., 1968 [5 Sept., 1967], No. 67605/68. Heading B5N. [Also in Divisions B2 and F2] A vibration damping laminated system comprises two sheets and bonded to the sheets an interlayer comprising a graft polymer of 40 to 80% by weight of methylmethacrylate or a mixture of methylmethacrylate with from 0À1 to 10% by weight of a copolymerizable carboxylic acid, or 60 to 20% by weight of a copolymer formed from a monomer mixture of 30 to 40% by weight of vinyl acetate, 30 to 40% by weight of n-butyl acrylate, 10 to 30% by weight of dibutyl maleate and 5 to 15% by weight of a copolymerizable unsaturated carboxylic acid. Specified carboxylic acids in admixture with methylmethacrylate are acrylic, methacrylic or a mixture thereof and crotonic acid is specified as the carboxylic acid present in the copolymer. The sheets may be of metal. Also disclosed is a plate applied to one surface of which is a layer of a graft polymer as specified above.
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公开(公告)号：SE360090B
公开(公告)日：1973-09-17
申请号：SE1649368
申请日：1968-12-03
Applicant: HOECHST AG
Inventor： OBERST H , EBIGT J , DUVE G , SCHOMMER A
Abstract: 1,245,470. Laminates. FARBWERKE HOECHST A.G. 4 Dec., 1968 [5 Sept., 1967], No. 67605/68. Heading B5N. [Also in Divisions B2 and F2] A vibration damping laminated system comprises two sheets and bonded to the sheets an interlayer comprising a graft polymer of 40 to 80% by weight of methylmethacrylate or a mixture of methylmethacrylate with from 0À1 to 10% by weight of a copolymerizable carboxylic acid, or 60 to 20% by weight of a copolymer formed from a monomer mixture of 30 to 40% by weight of vinyl acetate, 30 to 40% by weight of n-butyl acrylate, 10 to 30% by weight of dibutyl maleate and 5 to 15% by weight of a copolymerizable unsaturated carboxylic acid. Specified carboxylic acids in admixture with methylmethacrylate are acrylic, methacrylic or a mixture thereof and crotonic acid is specified as the carboxylic acid present in the copolymer. The sheets may be of metal. Also disclosed is a plate applied to one surface of which is a layer of a graft polymer as specified above.
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公开(公告)号：DK122181B
公开(公告)日：1972-01-31
申请号：DK592868
申请日：1968-12-04
Applicant: HOECHST AG
Inventor： SCHOMMER A , EBIGT J , DUVE G , OBERST H
Abstract: 1,246,996. Vibration damping laminates. FARBWERKE HOECHST A.G. 4 Dec., 1968 [ 6 Dec., 1967], No. 57603/68. Heading B5N. [Also in Divisions B2 and C3] A vibration damping laminated system comprises two plates, e.g. of metal such as steel, bonded together with an interlayer comprising a graft polymer of 40-80% by weight of styrene or a mixture thereof with 0À1-10% by weight based on the styrene of a copolymerizable carboxylic acid, e.g. acrylic and/or methacrylic acid, an 60-20% by weight of a copolymer of 30-40% by weight of vinyl acetate, 30-40% by weight of n-butyl acrylate, 10-30% by weight of di-n-butyl maleate and 5-15% by weight of a copolymerizable unsaturated carboxylic acid, e.g. crotonic acid. The graft polymer may be cross-linked with a compound containing a plurality of epoxide or isocyanate groups. The graft polymer may contain minor amounts of fillers, e.g. heavy spar, silicic acid, graphite, soot or a mixture thereof, and one or more plasticizers. The total thickness of the laminated system may be 1-6 mm., the thickness of the interlayer being 0À1-1 mm. and the ratio of the thickness of the plates being from 1 : 1 to 4 : 1. The graft polymer may be applied to the plates by trowelling, brushing or pouring at an elevated temperature and the system cooled under pressure between rollers. A solution of the copolymer in styrene or styrene and acrylic and/or methacrylic acid mixture containing a polymerization initiator, e.g. tertiary butyl hydroperoxide may be applied between the plates and the laminated system subjected to heating at 60-180‹ C. to effect grafting.
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