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公开(公告)号:FI841767A
公开(公告)日:1984-11-08
申请号:FI841767
申请日:1984-05-03
Applicant: HOECHST AG
Inventor: STAENDEKE HORST , HEYMER GERO , ELSNER GEORG
IPC: A62D1/00 , C08L1/00 , C01B25/40 , C08G18/00 , C08K3/32 , C08K9/04 , C08K9/08 , C08K9/10 , C08L75/00 , C08L75/04 , C09K21/02 , C09K21/04 , C09K21/12 , D06M11/00 , D06M11/72 , D06M15/423 , D06M23/12 , D06M101/00 , D06M101/02 , D06M101/06 , D06M101/08 , D21H17/10 , D21H17/47 , D21H17/51 , D21H17/63 , D21H21/34 , D21H27/00 , C01B
Abstract: The disclosure relates to a process for making a particulate agent stable to hydrolysis based on free-flowing, pulverulent ammonium polyphosphate by treating the ammonium polyphosphate with a thermosetting, artificial resin being water-insoluble when cured. More specifically, the disclosure provides for the ammonium polyphosphate, an aliphatic alcohol as a diluent, and a melamine/formaldehyde-resin or phenol/formaldehyde-resin to be placed in an autoclave and intimately mixed at room temperature; for the mixture to be heated to a temperature of about 80 DEG to about 180 DEG C. and allowed to remain over a period of 15 to 240 minutes at that temperature and under the pressure corresponding to the vapor pressure of the diluent; for the diluent to be separated and for the product so obtained to be dried.
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公开(公告)号:FI841767A0
公开(公告)日:1984-05-03
申请号:FI841767
申请日:1984-05-03
Applicant: HOECHST AG
Inventor: STAENDEKE HORST , HEYMER GERO , ELSNER GEORG
IPC: A62D1/00 , C08L1/00 , C01B25/40 , C08G18/00 , C08K3/32 , C08K9/04 , C08K9/08 , C08K9/10 , C08L75/00 , C08L75/04 , C09K21/02 , C09K21/04 , C09K21/12 , D06M11/00 , D06M11/72 , D06M15/423 , D06M23/12 , D06M101/00 , D06M101/02 , D06M101/06 , D06M101/08 , D21H17/10 , D21H17/47 , D21H17/51 , D21H17/63 , D21H21/34 , D21H27/00 , C01B
Abstract: The disclosure relates to a process for making a particulate agent stable to hydrolysis based on free-flowing, pulverulent ammonium polyphosphate by treating the ammonium polyphosphate with a thermosetting, artificial resin being water-insoluble when cured. More specifically, the disclosure provides for the ammonium polyphosphate, an aliphatic alcohol as a diluent, and a melamine/formaldehyde-resin or phenol/formaldehyde-resin to be placed in an autoclave and intimately mixed at room temperature; for the mixture to be heated to a temperature of about 80 DEG to about 180 DEG C. and allowed to remain over a period of 15 to 240 minutes at that temperature and under the pressure corresponding to the vapor pressure of the diluent; for the diluent to be separated and for the product so obtained to be dried.
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公开(公告)号:DD207209A5
公开(公告)日:1984-02-22
申请号:DD24865483
申请日:1983-03-09
Applicant: HOECHST AG
Inventor: STAENDEKE HORST , DANY FRANZ-JOSEF , KANDLER JOACHIM
IPC: C08G18/00 , C08G101/00 , C08J9/00 , C08K3/32 , C08L75/00 , C08L75/04 , C08K5/16 , C08K5/49 , C08G18/28
Abstract: The disclosure relates to a storable polyol pre-mixture for making flame-retardant polyurethane foam plastics consisting of a mixture of a polyester polyol or polyether polyol and an ammonium polyphosphate as a flame-retardant agent. The pre-mixture contains more particularly an ammonium polyphosphate which corresponds to the general formula (I) H(n-m)+2(NH4)mPnO3n+1 (I) in which n stands for an integral average value of 100 to 1000, m stands for a whole number of up to n+2 and m/n stands for a value of about 1, has an acid number of 0.01 to about 5 mg KOH/g, contains 0.01 to 0.5 mass % water and 0.5 to about 15 mass % water-soluble fractions in water at 25 DEG C.
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公开(公告)号:DK116583D0
公开(公告)日:1983-03-10
申请号:DK116583
申请日:1983-03-10
Applicant: HOECHST AG
Inventor: STAENDEKE HORST , DANY FRANZ-JOSEF , KANDLER JOACHIM
Abstract: The disclosure relates to a storable polyol pre-mixture for making flame-retardant polyurethane foam plastics consisting of a mixture of a polyester polyol or polyether polyol and an ammonium polyphosphate as a flame-retardant agent. The pre-mixture contains more particularly an ammonium polyphosphate which corresponds to the general formula (I) H(n-m)+2(NH4)mPnO3n+1 (I) in which n stands for an integral average value of 100 to 1000, m stands for a whole number of up to n+2 and m/n stands for a value of about 1, has an acid number of 0.01 to about 5 mg KOH/g, contains 0.01 to 0.5 mass % water and 0.5 to about 15 mass % water-soluble fractions in water at 25 DEG C.
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公开(公告)号:CA1072983A
公开(公告)日:1980-03-04
申请号:CA253977
申请日:1976-06-03
Applicant: HOECHST AG
Inventor: STAENDEKE HORST
IPC: C07F9/53
Abstract: PRODUCTION OF TERTIARY PHOSPHINE OXIDES. Production of tertiary phosphine oxides of the general formula R1R2R3P(O), in which R1, R2 and,R3 each stand for identical or different, substituted or unsubstituted alkyl, aryl or aralkyl groups. The tertiary phosphine oxides are produced by oxidizing at temperatures higher than 200.degree.C one or more quaternary phosphonium halides of the general formula ¢R1R2R3R4P! X, in which R1 through R3 have the meanings given above, R4 has the same meaning as R1 through R3, and X stands for a halogen atom.
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公开(公告)号:CA2136768A1
公开(公告)日:1995-06-17
申请号:CA2136768
申请日:1994-11-28
Applicant: HOECHST AG
Inventor: SICKEN MARTIN , STAENDEKE HORST
Abstract: The flame-resistant polyurethanes of the invention comprise, as flameproofing agents, mixtures of oligomeric phosphoric acid esters which carry hydroxyalkoxy groups, of the formula I (I) in which ? denotes an average chain length of 0.5 to 10, R1 is a hydroxyl-containing radical of the formula II a, R2 is a radical of the formula III (II a: R7 = H) (III) (II b: R7 = C1-C6) R3 is a radical of the formula II b, R4 is R1 or R3; R5, R6 and R7 are an H atom or an alkyl radical having 1 to 6 carbon atoms, m is 0 to 4 and n is 1 to 4.
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公开(公告)号:CA2056022A1
公开(公告)日:1992-06-15
申请号:CA2056022
申请日:1991-11-22
Applicant: HOECHST AG
Inventor: STAENDEKE HORST , KOLKMANN FRIEDRICH
IPC: B01J2/00 , C01B25/00 , C01B25/023
Abstract: HOE 90/H 035 Stabilized red phosphorus, and processes for the preparation thereof of the disclosure: In, a stabilized, pulverulent red phosphorus comprising phosphorus particles having a maximum particle size of 2 mm whose surface is covered with a thin coating of an oxidation stabilizer, the oxidation stabilizer comprises an uncured epoxy resin in a proportion of from 0.2 to less than 5% by weight. The red phosphorus stabilized in this way may additionally be covered by a thin coating of di-2-ethylhexyl phthalate as phlegmatizing agent. In addition, processes for the preparation of the stabilized and possibly additionally phlegmatized red phosphorus are described.
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公开(公告)号:CA1281147C
公开(公告)日:1991-03-05
申请号:CA502034
申请日:1986-02-17
Applicant: HOECHST AG
Inventor: STAENDEKE HORST
Abstract: SELF-EXTINGUISHING POLYMERIC COMPOSITIONS Self-extinguishing polymeric composition based on a polyolefin, especially polypropylene, of improved thermal stability containing an intumescent fire-retardant system comprised of a phosphorus constituent and a carbonaceous nitrogen constituent. The composition contains more particularly, as the phosphorus constituent, a product consisting substantially of a) 75 - 99.5 wgt % pulverulent free flowing ammonium polyphosphate of the following general formula H(n-m)+2(NH4)mPnO3n+1 in which n stands for an integer having an average value of from about 20 to 800 and the ratio of m/n is about 1, and b) about 0.5 - 25 wgt % of a water-insoluble, optionally cured artificial resin encapsulating the individual ammonium polyphosphate particles.
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公开(公告)号:CA1258009A
公开(公告)日:1989-08-01
申请号:CA489188
申请日:1985-08-21
Applicant: HOECHST AG
Inventor: STAENDEKE HORST , MICHELS EDUARD
Abstract: FLAME-RETARDANT AGENTS STABLE TO HYDROLYSIS, BASED ON AMMONIUM POLYPHOSPHATE A flame-retardant agent based on free flowing, pulverulent ammonium polyphosphate of the general formula H(n-m)+2(NH4)mpn03n+1 in which n stands for an integer with an average value of about 20 to 800 and the ratio of m/n is about 1, consists substantially of a) about 75 to 99.5 mass % ammonium polyphosphate and b) about 0.5 to 25 mass % of a reaction product of a polyisocynate and a carbodiimidization catalyst, the polycarbodiimide encapsulating the individual ammonium polyphosphate particles.
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公开(公告)号:DD269374A5
公开(公告)日:1989-06-28
申请号:DD31403888
申请日:1988-03-25
Applicant: HOECHST AG
Inventor: STAENDEKE HORST , THUEMMLER URSUS , ADAM WILHELM
IPC: C01B25/00 , C08K9/02 , C08K9/08 , C01B25/023
Abstract: Stabilized pulverulent red phosphorus consisting substantially of particles with a size of at most 2 mm, encapsulated in a thin layer of an oxidation stabilizer consisting of at least one scarcely water-soluble or water-insoluble metal hydroxide and a melamine/formaldehyde-polycondensation product.
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