TRICYCLIC BENZOYLCYCLOHEXANEDIONE DERIVATIVES
    12.
    发明申请
    TRICYCLIC BENZOYLCYCLOHEXANEDIONE DERIVATIVES 审中-公开
    三环benzoylcyclohexanedione衍生物

    公开(公告)号:WO0073311A3

    公开(公告)日:2001-04-19

    申请号:PCT/EP0004806

    申请日:2000-05-26

    CPC classification number: C07D495/04

    Abstract: The invention relates to tricyclic benzoylcyclohexanedione derivatives of formula (I), wherein the variables have the following meanings: X is oxygen, sulphur, S=O, S(=O)2, CR R , NR or a bond; y forms a saturated, partially saturated or unsaturated 5- or 6-membered heterocycle with the two carbons to which it is bonded; R , R , R , R is hydrogen, alkyl, alkyl halide, alkoxy or alkoxy halide; R is halogen, alkyl, alkyl halide, alkoxy or alkoxy halide; R is hydrogen, nitro, halogen, cyano, alkyl, alkyl halide, alkoxy, alkoxy halide, alkylthio, C1-C6- alkylthio halide, alkylsulfinyl, alkylsulfinyl halide, alkylsulfonyl, alkylsulfonyl halide, optionally substituted aminosulfonyl, or optionally substituted sulfonylamino; R is hydrogen, alkyl or halogen; m is 0, 1 or 2; R is hydrogen, alkyl, alkyl halide, alkylcarbonyl, formyl, alkoxycarbonyl, alkoxycarbonyl halide, alkylsulfonyl or alkylsulfonyl halide; and R is substituted (3-oxo-1-cyclohexen-2-yl)-carbonyl or substituted (1,3-dioxo-2-cyclohexyl)-methylidene; and to agriculturally useable salts thereof. The invention also relates to a method for producing the tricyclic benzoylcyclohexanedione derivatives, to products containing them and to the use of said derivatives or said products containing them for combating unwanted vegetation.

    Abstract translation: 式(I),其中各变量具有以下含义的三环benzoylcyclohexanedione衍生物:X是氧,硫,S = O,S(= O)2,CR <6> - [R <7>,NR <8>或键 ; Y共同与两个碳其所结合的,饱和,部分饱和或不饱和5或6元杂环; [R <1>,R <2>,R <6> - [R <7>是氢,烷基,卤代烷基,烷氧基或卤代烷氧基; [R <3>为卤素,烷基,卤代烷基,烷氧基或卤代烷氧基; [R <4>为氢,硝基,卤素,氰基,烷基,卤代烷基,烷氧基,卤代烷氧基,烷硫基,C1-C6卤代烷硫基,烷基亚磺酰基,卤代烷,烷基磺酰基,卤代烷基磺酰基,任选子氨基磺酰基,磺酰氨基或可能子..; [R <5>是氢,烷基或卤素; m是0,1或2; [R <8>是氢,烷基,卤代烷基,烷基羰基,甲酰基,烷氧基羰基,卤代烷氧基羰,烷基磺酰基或卤代烷基磺酰基; [R <9>取代的(3-氧代-1-环己烯-2-基) - 羰基,或取代的(1,3-二氧代-2-环己基)亚甲基; 及其可农用盐; 一种用于三环benzoylcyclohexanedione衍生物的制备方法; 含有它们并使用这些衍生物或包含它们用于控制不希望的植物的组合物的组合物。

    BENZYLIDENE PYRAZOLONES, PRODUCTION AND USE THEREOF
    14.
    发明申请
    BENZYLIDENE PYRAZOLONES, PRODUCTION AND USE THEREOF 审中-公开
    BENZYLIDENPYRAZOLONE,生产和使用

    公开(公告)号:WO9926930A2

    公开(公告)日:1999-06-03

    申请号:PCT/EP9807099

    申请日:1998-11-06

    Abstract: The invention relates to benzylidene pyrazolones of formula (I), wherein the substituents and index n have the following meanings: R = optionally substituted C1-C6 alkyl; R = optionally substituted C1-C6 alkyl, optionally substituted C1-C6 alkoxy, halogen, nitro, cyano; R = hydrogen, halogen, nitro, cyano, a group NR R , OCOR , NR COR ,CO2R , -COSR , -CONR R , C1-C4-alkoxyiminoalkyl, C1-C6 alkoxycarbonyl, optionally substituted C1-C6 alkyl, optionally substituted C1-C6 alkoxy, optionally substituted C1-C6 alkylthio, optionally substituted C2-C6 alkenyl, optionally substituted phenyl, optionally substituted phenoxy, an optionally substituted 5- or 6-membered saturated or unsaturated heterocycle which can contain up to 4 nitrogen atoms and/or up to 2 oxygen or sulphur atoms as ring members; R = C1-C6 alkyl, C1-C4 halogen alkyl; or R and R = an optionally substituted saturated or unsaturated 2- or 3-membered bridge which can contain one sulphur atom which can be oxidized into sulfoxide or sulfone, R = hydrogen or optionally substituted C1-C6 alkyl; R = hydrogen, C1-C6 alkyl or C1-C4 halogenalkyl; n = 0, 1 or 2; X = hydrogen, chlorine or bromine. The compounds to which claim is laid are available in both a trans and a cis form or can be a mixture of these isomers.

    Abstract translation: 式(I)的Benzylidenpyrazolone其中取代基和指数n具有以下含义:R t <1>是未取代的或取代的。 C1-C6烷基; [R <2>是未取代的或取代的。 C1-C6烷基,未取代或取代的。 C1-C6烷氧基,卤素,硝基,氰基; [R <3>是氢,卤素,硝基,氰基,基团NR <5> - [R <6>,OCOR <5>,NR <5> COR <6>,CO 2 <5>,-COSR <5>,-CONR <5> - [R <6>,C1-C4-alkoxyiminoalkyl,C1-C6烷基羰基,未取代的或取代的。 C1-C6烷基,未取代或取代的。 C1-C6烷氧基,未取代的或取代的。 C1-C6烷硫基,未取代或取代的。 C2-C6链烯基,未取代的或取代的。 C2-C6炔基,未取代的或取代的。 苯基,未取代的或取代的。 苯氧基,未取代的或取代的。 5-或6-元饱和或可含有至多4个氮原子和/或至多2个氧或硫原子作为环成员的不饱和的杂环; [R <4> C1-C6-烷基,C1-C4卤代烷基; 或R <3>,R <4>为可以含有可被氧化为亚砜或砜硫原子的任选取代的饱和或不饱和2-或3-元桥; [R <5>为氢或未取代或取代的。 C1-C6烷基; [R <6>是未取代的或取代的。 C1-C6烷基; [R <7>是氢,C1-C6烷基或C1-C4卤代烷基; n为0.1或2; X是氢,氯或溴; 其中要求保护的化合物在跨及在所述顺式 - 形式两者呈现,或者可以是这些异构体的混合物。

    TRICYCLIC PYRAZOLONE DERIVATIVES
    17.
    发明申请
    TRICYCLIC PYRAZOLONE DERIVATIVES 审中-公开
    三环吡唑啉酮

    公开(公告)号:WO0059910A3

    公开(公告)日:2001-04-26

    申请号:PCT/EP0002564

    申请日:2000-03-23

    CPC classification number: C07D495/04 A01N43/90

    Abstract: The invention relates to tricyclic pyrazolone derivatives of the formula (I) in which the variables have the following meaning: R is hydrogen, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy, C1-C6-alkylthio, C1-C6-haloalkylthio, C1-C6-alkylsulfinyl, C1-C6-haloalkylsulfinyl, C1-C6-alkylsulfonyl, C1-C6-haloalkylsulfonyl, halogen, cyano or nitro; X is O or NR ; R is hydrogen, C1-C6-alkyl, C1-C6-alkoxy, C1-C6-haloalkyl, C1-C6-haloalkoxy, phenyl possibly substituted with C1-C3-alkyl, halogen, cyano, nitro or C1-C3-alkylsulfonyl, phenylsulfonyl possibly substituted with C1-C3-alkyl, halogen, cyano, nitro; R , R are hydrogen, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy, C1-C6-alkylthio, C1-C6-haloalkylthio, C1-C6-alkylsulfinyl, C1-C6-haloalkylsulfinyl, C1-C6-alkylsulfonyl, C1-C6-haloalkylsulfonyl, NR R , C2-C6-alkoxyalkyl, C1-C6-alkoxycarbonyl, C1-C6-alkylcarbonyl, halogen, cyano, nitro, phenyl possibly substituted with C1-C3-alkyl, halogen, cyano or nitro; R is hydrogen or C1-C4-alkyl; R is hydrogen, C1-C6-alkyl or halogen; R is hydrogen or C1-C6-alkyl; R is C1-C6-alkyl or C1-C6-alkoxy; l is 0, 1 or 2; n is 1 or 2; R is a rest of the formulas (IIa) or (IIb), in which the variables have the meanings stated in claim I. The invention also relates to methods for the preparation of said tricyclic pyrazolone derivatives, preparations containing same and the use of said derivatives or of preparations containing same as herbicides.

    Abstract translation: 式(I),其中,所述Viarablen具有以下含义的吡唑啉酮三环衍生物; [R <1>是氢,C1-C6烷基,C1-C6卤代烷基,C1-C6-烷氧基,C1-C6卤代烷氧基,C1-C6烷硫基,C1-C6卤代烷硫基,C1-C6烷基亚磺酰基,C 1 -C C6-卤代烷基亚磺酰,C 1 -C 6 - 烷基磺酰基,C1-C6卤代烷基亚磺酰,卤素,氰基或硝基; X是O或NR <2>; [R <2>的氢,C1-C6烷基,C1-C6-烷氧基,C1-C6卤代烷基,C1-C6-卤代烷氧基,任选地被C1-C3烷基,卤素,氰基,硝基或C1-C3烷基磺酰基取代的取代的 苯基或任选地被C1-C3烷基,卤素,氰基或硝基取代的苯磺酰基; [R <3>,R <4>为氢,C1-C6烷基,C1-C6卤代烷基,C1-C6-烷氧基,C1-C6卤代烷氧基,C1-C6烷硫基,C1-C6卤代烷硫基,C1-C6 烷基亚磺酰基,C1-C6-卤代烷基亚磺酰,C 1 -C 6 - 烷基磺酰基,C1-C6卤代烷基磺酰基,NR <7> - [R <8>,C2-C6烷氧基烷基,C1-C6烷氧羰基,C1-C6烷基羰基,卤素, 氰基,硝基,任选地被C1-C3烷基,卤素,氰基或硝基subsitutiertes; [R <5>是氢或C1-C4烷基; [R <6>为氢,C1-C6烷基或卤素; [R <7>是氢或C1-C6烷基; [R <8> C1-C6烷基或C1-C6烷氧基; 1 0,1或2; n是1或2; [R <9>为基团(IIa)或(IIb)中,其中的变量具有权利要求1中所示的含义,用于制备三环吡唑啉酮衍生物,包含它们和使用这些衍生物或包含它们用于控制杂草的组合物的组合物的方法。

    N-CYCLOALKYL-3-ALKENYLBENZOYL-PYRAZOLE DERIVATIVES
    18.
    发明申请
    N-CYCLOALKYL-3-ALKENYLBENZOYL-PYRAZOLE DERIVATIVES 审中-公开
    N-环烷基-3- ALKENYLBENZOYL-吡唑衍生物

    公开(公告)号:WO0104096A2

    公开(公告)日:2001-01-18

    申请号:PCT/EP0005860

    申请日:2000-06-23

    CPC classification number: A01N43/56 C07D231/20

    Abstract: The invention relates to cycloalkyl-substituted benzoyl pyrazoles of formula (I) wherein said variables can, for example, have the following meanings: R = hydrogen, nitro, halogen, cyano, rhodano or an optionally substituted aliphatic radical; R = an optionally substituted aliphatic radical, halogen, nitro, in addition to substituted sulfonyl or amino groups; R = hydrogen, halogen, C1-C6-alkyl, C1-C6-halogenalkyl, C1-C6-alkoxy, C2-C6-alkenyl or C2-C6-alkinyl; R , R = hydrogen, nitro, halogen, cyano, rhodano, an optionally substituted aliphatic radical or substituted sulfonyl or amino groups; R = hydrogen, halogen, C1-C6-alkyl, C1-C6-alkoxy, C3-C8-cycloalkyl; R = a cyclic ring system with 3 - 14 ring atoms; R = hydroxy or a substituted hydroxy group; in addition to tautomers or agriculturally useful salts thereof. The invention also relates to methods for the production of compounds of formula (I), agents containing said compounds, the use of compounds of formula (I) and agents containing said compounds as pesticides.

    Abstract translation: 本发明的目的是式(I),其中变量具有环烷基取代的benzoylpyrazoles,例如,以下的含义:R t <1>为氢,硝基,卤素,氰基,氰硫基或任选取代的脂族基团; [R <2>是任选取代的脂族基,卤素,硝基,和取代的磺酰基或氨基; [R <3>是氢,卤素,C1-C6烷基,C1-C6卤代烷基,C1-C6-烷氧基,C2-C6烯基或C2-C6炔基; [R <4>,R <5>为氢,硝基,卤素,氰基,氰硫基,任选取代的脂族基或取代的磺酰基或氨基基团; [R <6>是氢,卤素,C1-C6烷基,C1-C6烷氧基,C3-C8环烷基; [R <7>具有3-14个环原子的环状环体系; [R <16>为羟基或取代羟基; 和互变异构体或可农用盐。 此外,本发明提供了制备式(I)的化合物的方法,是指含有它们,并使用式(I)和组合物的化合物的包含它们用于控制有害植物而言。

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