Abstract:
A process for producing a silicone pressure sensitive adhesive is shown and described herein. The process comprises reacting a MQ silicone resin with a polydiorganosiloxane in the absence of a solvent. The MQ silicone resin is a solid, solventless MQ resin. The reaction may be conducted in the presence of a catalyst, a chain extension reagent, or a combination thereof, and the resulting pressure sensitive adhesive can be dissolved in a solvent and the solids content adjusted. The present method provides a manner to provide a cleaner adhesive material that is free of unwanted materials such as aromatic solvents and also substantially free of cyclic siloxane impurities.
Abstract:
Provided is a silicone polymer of the Formula (I): M1aM2bM3cD1dD2eD3fT1gT2hT3iQj. wherein: M1=R1R2R3SiO1/2 M2=R4R5R6SiO1/2 M3=R7R8R9SiO1/2 D1=R10R11SiO2/2 D2=R12R13SiO2/2 D3=R14R15SiO2/2 T1=R16SiO3/2 T2=R17SiO3/2 T3=R18SiO3/2 Q=SiO4/2 where R1, R2, R3, R5, R6, R8, R9, R10, R11, R13, R15, R16 are independently chosen from a hydrogen, a C1-C60 aliphatic or aromatic group or C1-C60 alkoxy group; R4, R12, R17 are independently chosen from a C1-C60 alkyl, a C1-C60 alkoxy, or R19-A-R20— where A is chosen from a group comprising an unsaturated cyclic moiety chosen from an aromatic group, a fused aromatic group, an unsaturated alicyclic group, an unsaturated heterocyclic group, or a combination of two or more thereof; R19 is chosen from a —H, a C1-C60 alkyl, allyl, vinyl, alkoxy, allyloxy, vinyloxy, acrylate, or methacrylate; and R20 is chosen from a divalent organic group; R7, R14, R18 are independently selected from hydrogen or OR22 or unsaturated monovalent radicals or radicals containing heteroatom such as oxygen, nitrogen, sulfur or radicals containing organosilane groups; and the subscripts a, b, c, d, e, f, g, h, i, j are zero or positive subject to the following limitations: 2≤a+b+c+d+e+f+g+h+i+j≤1000, b+e+h>0 and c+f+i≥0.
Abstract:
A thermally conductive silicone composition is shown and described herein. The thermally conductive silicone composition comprises (A) an ionically modified siloxane, and (B) a thermally conductive filler comprising a first filler and a second filler, where the first filler and/or the second filler comprises a plurality of filler types, the plurality of filler types differing from one another in terms of particle size and/or morphology. The ionically modified siloxane may function as a dispersing aid or wetter for efficient dispersion of thermal conducting organic and inorganic fillers to achieve high thermal conductivity.
Abstract:
A hydrophilic siloxane copolymer of siloxane and hydrophilic organic monomer/s The copolymers can be functionalized to make them capable of undergoing further polymerization by thermal or actinic radiations. The hydrophilicity of these polymers can be varied by varying the siloxane versus organic monomer ratio thereby going from water dispersible to soluble states. The siloxane content can be tuned accordingly in order to provide moderate to high oxygen permeability. These copolymers can be used as a single component curable composition which results in hydrogels to minimize the presence of leachable components thus by reducing the processing cost. The polymers may also find applications in personal care formulations as copolymers, film-formers, hydrogels, coating, emulsions/latex etc.
Abstract:
A novel hydrophylically modified silicone and a composition for forming a hydrophylically modified silicone pressure sensitive adhesive is shown and described herein. The comprises comprises (i) a MQ silicone resin, (ii) a polyorganosiloxane, and (iii) a siloxane comprising a range of hydrophilic functional groups. The mixture of (i), (ii), and (iii) is self-catalyzing and does not require an external condensation catalyst. The composition is suitable for forming a cured silicone material such as, for example, a pressure sensitive adhesive compatible with polar additives or actives used in various applications.
Abstract:
Provided is a silicone polymer of the Formula (I): M1aM2bM3cD1dD2eD3fT1gT2hT3iQj. wherein: M1=R1R2R3SiO1/2 M2=R4R5R6SiO1/2 M3=R7R8R9SiO1/2 D1=R10R11SiO2/2 D2=R12R13SiO2/2 D3=R14R15SiO2/2 T1=R16SiO3/2 T2=R17SiO3/2 T3=R18SiO3/2 Q=SiO4/2 where R1, R2, R3, R5, R6, R8, R9, R10, R11, R13, R15, R16 are independently chosen from a hydrogen, a C1-C60 aliphatic or aromatic group or C1-C60 alkoxy group; R4, R12, R17 are independently chosen from a C1-C60 alkyl, a C1-C60 alkoxy, or R19-A-R20— where A is chosen from a group comprising an unsaturated cyclic moiety chosen from an aromatic group, a fused aromatic group, an unsaturated alicyclic group, an unsaturated heterocyclic group, or a combination of two or more thereof; R19 is chosen from a —H, a C1-C60 alkyl, allyl, vinyl, alkoxy, allyloxy, vinyloxy, acrylate, or methacrylate; and R20 is chosen from a divalent organic group; R7, R14, R18 are independently selected from hydrogen or OR22 or unsaturated monovalent radicals or radicals containing heteroatom such as oxygen, nitrogen, sulfur or radicals containing organosilane groups; and the subscripts a, b, c, d, e, f, g, h, i, j are zero or positive subject to the following limitations: 2≤a+b+c+d+e+f+g+h+i+j≤1000, b+e+h>0 and c+f+i≥0.
Abstract:
Provided is a composition comprising: (A) a silicone polymer of the Formula (I): M1aM2bM3cD1dD2eD3fT1gT2hT3iQj. wherein: M1=R1R2R3SiO1/2 M2=R4R5R6SiO1/2 M3=R7R8R9SiO1/2 D1=R10R11SiO2/2 D2=R12R13SiO2/2 D3=R14R15SiO2/2 T1=R16SiO3/2 T2=R17SiO3/2 T3=R18SiO3/2 Q=SiO4/2 where R1, R2, R3, R5, R6, R8, R9, R10, R11, R13, R15, R16 are independently chosen from a hydrogen, a C1-C60 aliphatic or aromatic group or C1-C60 alkoxy group; R4, R12, R17 are independently chosen from a C1-C10 alkyl, a C1-C10 alkoxy, or R19-A-R20— where A is chosen from a group comprising an unsaturated cyclic moiety chosen from an aromatic group, a fused aromatic group, an unsaturated alicyclic group, an unsaturated heterocyclic group, or a combination of two or more thereof; R19 is chosen from a —H, a C1-C10 alkyl, allyl, vinyl, alkoxy, allyloxy, vinyloxy, acrylate, or methacrylate; and R20 is chosen from a divalent organic group; R7, R14, R18 are independently selected from hydrogen or OR22 or unsaturated monovalent radicals or radicals containing heteroatom such as oxygen, nitrogen, sulfur or radicals containing organosilane groups; and the subscripts a, b, c, d, e, f, g, h, i, j are zero or positive subject to the following limitations: 2≤a+b+c+d+e+f+g+h+i+j≤1000, b+e+h>0 and c+f+i≥0 and B) a thermally conductive filler.
Abstract:
A hydrophobic hybrid organosiloxane nano latex is provided as the copolymerizate of: (a) organosiloxane monomer of the general formula MaMvbDcDvdTeTvfQg wherein: M=R1R2R3SiO1/2, Mv=R4R5RuSiO1/2, D=R6R7SiO2/2, Dv=R8RuSiO2/2, T=R9SiO3/2, Tv=RuSiO3/2, and Q=SiO4/2 in which R1, R2, R3, R4, R5, R6, R7, R8 and R9 each independently is hydrogen, a hydroxyl group, a hydrocarbyl group having up to 100 carbon atoms and optionally containing at least one hetroatom; Ru is a free-radical polymerizable group; subscripts a, b, c, d, e, f and g each independently range from 0 to 10,000 subject to the limitation that b+d+f is at least 1, p, q and r are integers independently selected from 0 to 100 and subscript h is 0 or 1; and, (b) monomer possessing a group which is free-radical copolymerizable with group Ru of organosiloxane monomer (a).
Abstract:
A composition including an actinic radiation or thermally curable polyorganosiloxane ionomer having one or more reactive groups, for example, vinyl, acrylate, epoxy groups.
Abstract:
A composition including an actinic radiation or thermally curable polyorganosiloxane ionomer having one or more reactive groups, for example, vinyl, acrylate, epoxy groups.