Scale inhibitors
    11.
    发明公开
    Scale inhibitors 失效
    Kesselsteinverhüter

    公开(公告)号:EP0877002A2

    公开(公告)日:1998-11-11

    申请号:EP98303438.0

    申请日:1998-05-01

    CPC classification number: C11D3/3757 C02F5/10

    Abstract: The invention relates to the inhibition of (poly)phosphate scale in aqueous systems involving the use of at least one copolymer comprising the following monomers in polymerized form:-

    (I) 50-08% by weight of one or more weak acids;
    (II) 2-50% by weight of one or more strong acids;
    (III) 0-30% by weight of one or more monoethylenically unsaturated C 4 -C 8 dicarboxylic acids; and
    (IV) 0-30% by weight of one or more monoethylenically unsaturated monomers polymerizable with (I), (II) and (III);
    wherein the total of monomers (I), (II), (III) and (IV) equals 100% by weight of copolymer.
    The invention is particularly suited to the inhibition of (poly)phosphate scale which occurs as a result of using low phosphate (STPP) containing detergent formulations.

    Abstract translation: 本发明涉及在含水体系中抑制(多)磷酸盐垢,包括使用至少一种共聚物,所述共聚物包含聚合形式的以下单体: - (I)50〜80%重量的一种或多种弱酸; (II)2-50重量%的一种或多种强酸; (III)0-30重量%的一种或多种单烯属不饱和C4-C8二羧酸; 和(IV)0-30重量%的与(I),(II)和(III)可聚合的一种或多种单烯属不饱和单体; 其中单体(I),(II),(III)和(IV)的总量等于共聚物的100重量%。 本发明特别适用于由于使用含有低磷酸盐(STPP)的洗涤剂配方而发生的(多)磷酸盐垢的抑制。

    Process for preparing water soluble polymers of monoethylenically unsaturated dicarboxylic acids
    13.
    发明公开
    Process for preparing water soluble polymers of monoethylenically unsaturated dicarboxylic acids 失效
    一种用于从Äthylänisch不饱和二羧酸制备水溶性聚合物的方法。

    公开(公告)号:EP0663408A3

    公开(公告)日:1995-12-13

    申请号:EP95300151.8

    申请日:1995-01-11

    CPC classification number: C08F22/02 C11D3/3757 H01L2924/01039

    Abstract: The present invention provides an efficient aqueous polymerization process of 6 hours or less for preparing water soluble polymer products formed from 50 to 100 weight percent of one or more monoethylenically unsaturated dicarboxylic acid monomers and 0 to 50 weight percent of one or more optional other water soluble monoethylenically unsaturated monomers. In this process, 1) an aqueous reaction mixture of dicarboxylic acid monomer is formed, 2) from about 0.9 to about 2.1 equivalent moles of base are added to the reaction mixture per mole dicarboxylic acid monomer, 3) at least one metal promoter is added to the reaction mixture, 4) one or more initiators and optional other water soluble monoethylenically unsaturated monomer are fed to the reaction mixture, 5) the weight percent reaction solids during the polymerization is between about 40 and about 65 weight percent, and 6) the reaction temperature is maintained at about 80 °C to about 140°C. The polymer product produced by the process of the present invention is useful as an additive in detergents, cleaning formulations, and water circulating systems.

    Process for efficient utilization of chain transfer agent
    14.
    发明公开
    Process for efficient utilization of chain transfer agent 失效
    Verfahren zur effizienten Verwendung einesKettenübertragungsmittels。

    公开(公告)号:EP0618240A1

    公开(公告)日:1994-10-05

    申请号:EP94300992.8

    申请日:1994-02-11

    CPC classification number: C08F2/38

    Abstract: A process for efficiently utilizing hypophosphorous acid or salts thereof as a chain transfer agent is provided wherein the polymerization is conducted to a final polymer solids level of at least about 50 percent by weight.
    The polymers produced are useful as dispersants for paint formulations, additives for laundry and machine dishwashing detergents, mineral dispersants, dispersants for kaolin clay slurries and scale inhibitors, dispersants and corrosion inhibitors for water treatment and oil production.

    Abstract translation: 使用次磷酸或其盐作为链转移剂的方法包括聚合一种或多种单体,其中至少20wt。 %的单体是单烯属不饱和酸或其盐,在下列存在下:(a)水; (b)一种或多种水溶性引发剂; 和(c)次磷酸或其盐; 其中将80-100%的单烯属不饱和酸或其盐计量加入到聚合反应器中 水和0-100%的次磷酸或其盐,以提供至少50重量%的最终聚合物固体含量。

    Water-soluble addition polymers of cyclohexene anhydrides
    15.
    发明公开
    Water-soluble addition polymers of cyclohexene anhydrides 失效
    WasserlöslicheAdditionspolymere von Cyclohexenanhydrid。

    公开(公告)号:EP0606984A2

    公开(公告)日:1994-07-20

    申请号:EP94300100.8

    申请日:1994-01-07

    CPC classification number: C11D3/3769 C02F5/12 C02F5/14 C08F222/04 C11D3/3757

    Abstract: The present invention provides water-soluble polymers containing, as polymerized units: (a) from about 3 to about 95 percent by weight of one or more cyclohexene anhydrides or the alkali metal or ammonium salts thereof. The present further provides aqueous polymerization processes for making the polymers. The water-soluble polymers are useful as water-treatment additives for boiler waters and cooling towers and as detergent additives acting as builders, anti-filming agents, dispersants, sequestering agents and encrustation inhibitors.

    Abstract translation: 本发明提供了含有作为聚合单元的水溶性聚合物:(a)约3至约95重量%的一种或多种环己烯酸酐或其碱金属或铵盐。 本发明还提供了用于制备聚合物的水性聚合方法。 水溶性聚合物可用作锅炉水和冷却塔的水处理添加剂,以及用作助洗剂,抗成膜剂,分散剂,螯合剂和结垢抑制剂的洗涤剂添加剂。

    Stable reactive thermosetting formulations of reducing sugars and amines
    18.
    发明公开
    Stable reactive thermosetting formulations of reducing sugars and amines 无效
    Stabile reaktivewärmehärtendeFormulierungen aus reduzierenden Zuckern und Aminen

    公开(公告)号:EP2457943A1

    公开(公告)日:2012-05-30

    申请号:EP11186942.6

    申请日:2011-10-27

    CPC classification number: C08L79/02 C08J5/24 C08J2379/02

    Abstract: The invention provides table aqueous thermosetting binder compositions having a total solids content of 15 wt.% or higher, preferably, 20 wt.% or higher, and having extended shelf life comprising one or more reducing sugar, one or more primary amine compound, and one or more stabilizer acid or salt having a pKa of 8.5 or less. The total amount of stabilizer used may range from 5 to 200 mole%, based on the total moles of primary amine present in the binder. The stabilizer may be an organic stabilizer chosen from a monocarboxylic acid, a dicarboxylic acid , a C 12 to C 36 fatty acid, an acid functional C 12 to C 36 fatty acid ester, an acid functional C 12 to C 36 fatty acid ether, or an inorganic stabilizer chosen from a mineral acid, a mineral acid amine salt, a mineral acid ammonia salt, and a Lewis acid, and mixtures thereof. The compositions can be used to provide binders which are water resistant and to make articles from substrate materials including, for example, glass, glass fiber, wood, or woody materials.

    Abstract translation: 本发明提供具有15重量%或更高,优选20重量%或更高的总固体含量的表水性热固性粘合剂组合物,并且具有延长的保质期,其包含一种或多种还原糖,一种或多种伯胺化合物和 pKa为8.5以下的一种或多种稳定剂酸或盐。 基于存在于粘合剂中的伯胺的总摩尔数,所用稳定剂的总量可以为5-200摩尔%。 稳定剂可以是选自单羧酸,二羧酸,C 12〜C 36脂肪酸,酸官能C 12〜C 36脂肪酸酯,酸官能C 12〜C 36脂肪酸醚等的有机稳定剂, 或选自无机酸,无机酸胺盐,无机酸氨盐和路易斯酸的无机稳定剂及其混合物。 该组合物可用于提供耐水性的粘合剂,并且可以从基材(包括例如玻璃,玻璃纤维,木材或木质材料)制造制品。

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