公开(公告)号：US11702572B2

公开(公告)日：2023-07-18

申请号：US16617412

申请日：2018-04-04

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Wenwen Li ,  Yinzhong Guo ,  Mai Chen

IPC: C09J175/08 ,  C08G18/50 ,  C08G18/10 ,  C08G18/32 ,  C08G18/38 ,  C08G18/66 ,  C08G18/80 ,  C08G18/48 ,  C08G18/75 ,  B32B7/12

CPC classification number: C09J175/08 ,  C08G18/10 ,  C08G18/3206 ,  C08G18/3885 ,  C08G18/4812 ,  C08G18/4825 ,  C08G18/4829 ,  C08G18/5084 ,  C08G18/6696 ,  C08G18/755 ,  C08G18/757 ,  C08G18/758 ,  C08G18/8054 ,  B32B7/12

Abstract: Two-component solventless polyurethane adhesive compositions comprising an isocyanate component and an isocyanate-reactive are disclosed, the compositions comprising an isocyanate component comprising an isocyanate-terminated prepolymer and an isocyanate-reactive component comprising a hydroxy-terminated polyurethane resin, a polyether polyol, a phosphate ester adhesion promoter, and, optionally, a bio-based polyol. Methods for forming laminate structures are also disclosed, the methods comprising forming an adhesive composition by mixing an isocyanate adhesive component comprising an isocyanate-terminated prepolymer and an isocyanate-reactive adhesive component comprising a hydroxy-terminated polyurethane resin, a polyether polyol, a phosphate ester adhesion promoter, and optionally, a bio-based polyol, applying the adhesive composition to a surface of a first substrate, and bringing a surface of a second substrate into contact with the adhesive composition on the surface of the first substrate, thereby forming the laminate structure. Laminate structures are also disclosed.

公开(公告)号：US11608457B2

公开(公告)日：2023-03-21

申请号：US16334646

申请日：2016-09-19

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  ROHM AND HAAS COMPANY

Inventor： Chenyan Bai ,  Mai Chen ,  Yinzhong Guo ,  Joseph J. Zupancic ,  Amira A. Marine

IPC: C09J175/06 ,  C08G18/12 ,  C08G18/40 ,  C08G18/42 ,  C08G18/48 ,  C08G18/50 ,  C08G18/72 ,  C08G18/76 ,  C08G18/78 ,  C09J175/08

Abstract: The present disclosure provides a two-component solventless adhesive composition comprising a polyol component and an isocyanate component. The polyol component comprises a phosphate functional compound, and at least one polyol selected from polyester, polyether, and the combination thereof; and the isocyanate component comprises isocyanate prepolymer that is the reaction product of at least one isocyanate monomer and at least one polyol selected from polyester, polyether, and the combination thereof.

公开(公告)号：US20220106505A1

公开(公告)日：2022-04-07

申请号：US17068348

申请日：2020-10-12

Applicant: Dow Global Technologies, LLC ,  Rohm and Haas Company ,  Dow Quimica De Colombia S.A.

Inventor： Yinzhong Guo ,  Juan Carlos Casarrubias ,  Kevin K. Miyake ,  Mateus Batista Torres Cipro ,  Elkin David Cardona Jimenez

IPC: C09J175/08 ,  C09J175/06 ,  B32B37/12 ,  B32B7/12 ,  B32B15/085 ,  B32B15/20

Abstract: A two-component solventless polyurethane adhesive composition including (A) at least one isocyanate component and (B) at least one polyol component. The isocyanate component (A) comprises an isocyanate prepolymer that is the reaction product of (Ai) a polyisocyanate and (Aii) an isocyanate-reactive component; wherein the isocyanate-reactive component comprises (Aiia) at least one polyol having a functionality greater than two, (Aiib) at least one aromatic polyester polyol having a functionality of greater than two, and (Aiic) at least one hydrophobic polyol. The polyol component (B) comprises (Bi) at least one polyether polyol having a functionality greater than two, (Bii) at least one aromatic polyester polyol transesterified with a natural oil, and (Biii) at least one phosphate ester polyol. A method for forming a laminate is also disclosed, the method comprising the steps of: (I) mixing the above reactants (components (A) and (B)) to form a solventless adhesive composition, (II) applying a layer of the solventless adhesive composition to a surface of a first substrate, (III) bringing the layer of the solventless adhesive composition on the first substrate into contact with a surface of a second substrate to form a laminate, and (IV) curing the solventless adhesive composition. A laminate comprising the above solventless adhesive composition is also disclosed.

公开(公告)号：US20210284886A1

公开(公告)日：2021-09-16

申请号：US16334646

申请日：2016-09-19

Applicant: ROHM AND HAAS COMPANY

Inventor： Chenyan Bai ,  Mai Chen ,  Yinzhong Guo ,  Joseph J. Zupancic ,  Amira A. Marine

IPC: C09J175/06 ,  C09J175/08 ,  C08G18/12 ,  C08G18/40 ,  C08G18/42 ,  C08G18/48 ,  C08G18/50 ,  C08G18/72 ,  C08G18/76 ,  C08G18/78

Abstract: The present disclosure provides a two-component solventless adhesive composition comprising a polyol component and an isocyanate component. The polyol component comprises a phosphate functional compound, and at least one polyol selected from polyester, polyether, and the combination thereof; and the isocyanate component comprises isocyanate prepolymer that is the reaction product of at least one isocyanate monomer and at least one polyol selected from polyester, polyether, and the combination thereof.

公开(公告)号：US20200157393A1

公开(公告)日：2020-05-21

申请号：US16617427

申请日：2018-04-24

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Wenwen Li ,  Yinzhong Guo ,  Mai Chen

IPC: C09J175/08 ,  C08G18/10 ,  C08G18/32 ,  C08G18/38 ,  C08G18/48 ,  C08G18/50 ,  C08G18/75

Abstract: Two-component solventless polyurethane adhesive compositions comprising an isocyanate component and an isocyanate-reactive component are disclosed, the compositions comprising an isocyanate component comprising an isocyanate-terminated prepolymer, and an isocyanate-reactive component comprising a polyether polyol, a phosphate ester adhesion promoter, and, a bio-based polyol. Methods for forming laminate structures are also disclosed, the methods comprising forming an adhesive composition by mixing an isocyanate adhesive component comprising an isocyanate-terminated prepolymer and an isocyanate-reactive adhesive component comprising a polyether polyol, a phosphate ester adhesion promoter, and a bio-based polyol, applying the adhesive composition to a surface of a first substrate, and bringing a surface of a second substrate into contact with the adhesive composition on the surface of the first substrate, thereby forming the laminate structure. Laminate structures are also disclosed.

公开(公告)号：US11981767B2

公开(公告)日：2024-05-14

申请号：US17294127

申请日：2019-11-13

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Yinzhong Guo ,  Mai Chen

IPC: C08G18/38 ,  B32B27/40 ,  C08G18/10 ,  C08G18/42 ,  C08G18/50 ,  C08J5/12 ,  C09J175/08

CPC classification number: C08G18/10 ,  B32B27/40 ,  C08G18/3885 ,  C08G18/42 ,  C08G18/5045 ,  C08J5/128 ,  C09J175/08 ,  B32B2375/00

Abstract: The present disclosure provides a process comprising providing an isocyanate component A comprising a blend of (i) an aromatic isocyanate prepolymer and (ii) an aliphatic isocyanate prepolymer; providing a polyol component B comprising a blend of; (i) a phosphate-functional polyol, (ii) a polyether polyol, and (iii) an element selected from the group consisting of a polyurethane polyol, a polyester polyol and a combination thereof; mixing component A and component B to form a solventless adhesive (SLA) composition, wherein a weight ratio of component A to component B is from 2:1 to 1:1, the SLA composition having a pot life from 30 min to 60 min at 40 C; applying the SLA composition between a first film and a second film to form a raw laminate; and curing the raw laminate to form a laminate product.

公开(公告)号：US20230174835A1

公开(公告)日：2023-06-08

申请号：US17999005

申请日：2021-04-23

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Tuoqi Li ,  Joseph J. Zupancic ,  Yinzhong Guo ,  Jie Wu

IPC: C09J167/00 ,  C08G18/58 ,  C08K3/32

CPC classification number: C09J167/00 ,  C08G18/587 ,  C08K3/32 ,  C08K2003/329 ,  C09J2475/00

Abstract: Provided is a composition comprising one or more epoxy phosphate esters wherein the structure comprises two or more polyester linkages. Also provided is a method of making the epoxy phosphate esters that comprises reacting one or more epoxy-terminated polyesters with one or more phosphoric acids. Further provided is an adhesive composition that comprises one or more epoxy phosphate esters, one or more multifunctional isocyanate prepolymers, and one or more multifunctional isocyanate-reactive compounds.

公开(公告)号：US20220056324A1

公开(公告)日：2022-02-24

申请号：US17414584

申请日：2018-12-21

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Rui Shi ,  Zhaohui Qu ,  Yinzhong Guo

IPC: C09J175/06 ,  C09J175/08 ,  C08G18/12 ,  C08G18/76 ,  C08G18/42 ,  C08G18/48 ,  C08G18/40

Abstract: The present disclosure provides a two-component solvent-less adhesive composition. The two-component solvent-less adhesive composition contains the reaction product of (A) an isocyanate component containing the reaction product of (i) an isocyanate monomer and (ii) a first dimer acid polyester polyol; and (B) a polyol component containing (i) a second dimer acid polyester polyol and (ii) optionally, a polyol selected from a polyether polyol, a polyester polyol, and combinations thereof. The two-component solvent-less adhesive composition contains from 15 wt % to 45 wt % units derived from dimer acid, based on the total weight of the two-component solvent-less adhesive composition.