公开(公告)号：CA1197229A

公开(公告)日：1985-11-26

申请号：CA431131

申请日：1983-06-24

Applicant: STANDARD OIL CO OHIO

Inventor： BREMER NOEL J ,  DRIA DENNIS E ,  BLUM PATRICIA R ,  MILBERGER ERNERST C ,  NICHOLAS MARK L

IPC: C07D307/60 ,  B01J27/198 ,  C07B61/00 ,  C07C51/215 ,  C07C51/25

Abstract: ATTRITION RESISTANT MICROSPHEROIDAL FLUID BED CATALYSTS CONTAINING THE MIXED OXIDES OF VANADIUM AND PHOSPHORUS A process is provided for the preparation of attrition resistant, microspheroidal fluid bed catalysts comprising the mixed oxides of vanadium and phosphorus in which a vanadium phosphorus mixed oxided catalyst precursor is densified, comminuted, formed into fluidizable particles and calcined under fluidization-type conditions. The present invention further provides the attrition resistant fluidizable catalysts prepared by the inventive process, and further provides a process for utilizing such attrition resistant catalysts in the production of maleic anhydride in the vapor phase by the oxidation of 4 carbon atom hydrocarbons.

公开(公告)号：CA2143042A1

公开(公告)日：1995-08-23

申请号：CA2143042

申请日：1995-02-21

Applicant: STANDARD OIL CO OHIO

Inventor： BLUM PATRICIA R ,  PAPARIZOS CHRISTOS ,  CIRJAK LARRY M ,  PEPERA MARC A ,  LEMANSKI MICHAEL F ,  SURESH DEVASIRVATHAM D

IPC: B01J21/08 ,  B01J23/44 ,  B01J23/52 ,  B01J23/56 ,  B01J23/58 ,  B01J23/60 ,  B01J23/62 ,  B01J23/63 ,  B01J23/644 ,  B01J23/648 ,  B01J23/66 ,  B01J23/68 ,  B01J32/00 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  B01J37/04 ,  C07B61/00 ,  C07C67/04 ,  C07C67/055 ,  C07C69/15

Abstract: A process for the preparation of a fluid bed vinyl acetate (VAM) catalyst comprising impregnating a support comprising a mixture of substantially inert microspheroidal particles with a solution comprising a halide-free metal salt of Pd and M, wherein M comprises Ba, Au, La, Nb, Ce, Zn, Pb, Ca, Sr, Sb or mixtures thereof, reducing the metal salts to form a deposit of Pd and M on the support surface and impregnating the support with at least one halide-free alkali metal salt. At least 50% of the particles used for the microspheroidal support have a particle size below 100 microns, preferably below 60 microns.

公开(公告)号：DE69106681D1

公开(公告)日：1995-02-23

申请号：DE69106681

申请日：1991-11-21

Applicant: STANDARD OIL CO OHIO

Inventor： LEMANSKI MICHAEL F ,  HAZEN JOSEPH B ,  BLUM PATRICIA R

IPC: B01J27/18 ,  B01J27/185 ,  C07B61/00 ,  C07C51/25 ,  C07C53/08

Abstract: Disclosed is making acetic acid by reacting in a reaction zone ethylene and molecular oxygen in the presence of a solid catalyst containing the elements and proportions indicated by the empirical formula PdaMbTiPcOx (formula 1> where M is selected from Cd, Au, Zn, Tl, alkali metals and alkaline earth metals, a is from 0.0005 to 0.2 b is from zero to 3a c is 0.5 to 2.5, and x is a value sufficient to satisfy the valence requirements of the other elements present, and wherein such catalyst contains crystalline TiP2O7.

公开(公告)号：MX9102457A

公开(公告)日：1993-02-01

申请号：MX9102457

申请日：1991-12-09

Applicant: STANDARD OIL CO OHIO

Inventor： LEMANSKI MICHAEL F ,  HAZEN JOSEPH B ,  BLUM PATRICIA R

IPC: B01J27/18 ,  B01J27/185 ,  C07B61/00 ,  C07C51/25 ,  C07C53/08

Abstract: Disclosed is making acetic acid by reacting in a reaction zone ethylene and molecular oxygen in the presence of a solid catalyst containing the elements and proportions indicated by the empirical formula PdaMbTiPcOx (formula 1> where M is selected from Cd, Au, Zn, Tl, alkali metals and alkaline earth metals, a is from 0.0005 to 0.2 b is from zero to 3a c is 0.5 to 2.5, and x is a value sufficient to satisfy the valence requirements of the other elements present, and wherein such catalyst contains crystalline TiP2O7.

公开(公告)号：NO914824A

公开(公告)日：1992-06-11

申请号：NO914824

申请日：1991-12-06

Applicant: STANDARD OIL CO OHIO

Inventor： LEMANSKI MICHAEL F ,  HAZEN JOSEPH B ,  BLUM PATRICIA R

IPC: B01J27/18 ,  B01J27/185 ,  C07B61/00 ,  C07C51/25 ,  C07C53/08 ,  B01J23/54

CPC classification number: C07C51/25 ,  C07C53/08

公开(公告)号：CA2055836A1

公开(公告)日：1992-06-11

申请号：CA2055836

申请日：1991-11-19

Applicant: STANDARD OIL CO OHIO

Inventor： LEMANSKI MICHAEL F ,  HAZEN JOSEPH B ,  BLUM PATRICIA R

IPC: B01J27/18 ,  B01J27/185 ,  C07B61/00 ,  C07C51/25 ,  C07C53/08 ,  B01J21/06 ,  B01J23/38

Abstract: CSL-P-4191 Disclosed is making acetic acid by reacting in a reaction zone ethylene and molecular oxygen in the presence of a solid catalyst containing the elements and proportions indicated by the empirical formula PdaMbTiPcox (formula 1) where M is selected from Cd, Au, Zn, Tl, alkali metals and alkaline earth metals, a is from 0.0005 to 0.2 b is from zero to 3a c is 0.5 to 2.5, and x is a value sufficient to satisfy the valence requirements of the other elements present, and wherein such catalyst contains crystalline TiP207. Applns.AZ9

公开(公告)号：AU8881091A

公开(公告)日：1992-06-11

申请号：AU8881091

申请日：1991-12-03

Applicant: STANDARD OIL CO OHIO

Inventor： LEMANSKI MICHAEL F ,  HAZEN JOSEPH B ,  BLUM PATRICIA R

IPC: B01J27/18 ,  B01J27/185 ,  C07B61/00 ,  C07C51/25 ,  C07C53/08

Abstract: Disclosed is making acetic acid by reacting in a reaction zone ethylene and molecular oxygen in the presence of a solid catalyst containing the elements and proportions indicated by the empirical formula PdaMbTiPcOx (formula 1> where M is selected from Cd, Au, Zn, Tl, alkali metals and alkaline earth metals, a is from 0.0005 to 0.2 b is from zero to 3a c is 0.5 to 2.5, and x is a value sufficient to satisfy the valence requirements of the other elements present, and wherein such catalyst contains crystalline TiP2O7.

公开(公告)号：RU2043987C1

公开(公告)日：1995-09-20

申请号：SU5010589

申请日：1991-12-09

Applicant: STANDARD OIL CO OHIO

Inventor： LEMANSKI MICHAEL F ,  HAZEN JOSEPH B ,  BLUM PATRICIA R

IPC: B01J27/18 ,  B01J27/185 ,  C07B61/00 ,  C07C51/25 ,  C07C53/08

Abstract: Disclosed is making acetic acid by reacting in a reaction zone ethylene and molecular oxygen in the presence of a solid catalyst containing the elements and proportions indicated by the empirical formula PdaMbTiPcOx (formula 1> where M is selected from Cd, Au, Zn, Tl, alkali metals and alkaline earth metals, a is from 0.0005 to 0.2 b is from zero to 3a c is 0.5 to 2.5, and x is a value sufficient to satisfy the valence requirements of the other elements present, and wherein such catalyst contains crystalline TiP2O7.

公开(公告)号：GR3015643T3

公开(公告)日：1995-07-31

申请号：GR950400787

申请日：1995-04-03

Applicant: STANDARD OIL CO OHIO

Inventor： LEMANSKI MICHAEL F ,  HAZEN JOSEPH B ,  BLUM PATRICIA R

IPC: B01J27/18 ,  B01J27/185 ,  C07B61/00 ,  C07C51/25 ,  C07C53/08

Abstract: Disclosed is making acetic acid by reacting in a reaction zone ethylene and molecular oxygen in the presence of a solid catalyst containing the elements and proportions indicated by the empirical formula PdaMbTiPcOx (formula 1> where M is selected from Cd, Au, Zn, Tl, alkali metals and alkaline earth metals, a is from 0.0005 to 0.2 b is from zero to 3a c is 0.5 to 2.5, and x is a value sufficient to satisfy the valence requirements of the other elements present, and wherein such catalyst contains crystalline TiP2O7.

公开(公告)号：DE69106681T2

公开(公告)日：1995-05-11

申请号：DE69106681

申请日：1991-11-21

Applicant: STANDARD OIL CO OHIO

Inventor： LEMANSKI MICHAEL F ,  HAZEN JOSEPH B ,  BLUM PATRICIA R

IPC: B01J27/18 ,  B01J27/185 ,  C07B61/00 ,  C07C51/25 ,  C07C53/08

Abstract: Disclosed is making acetic acid by reacting in a reaction zone ethylene and molecular oxygen in the presence of a solid catalyst containing the elements and proportions indicated by the empirical formula PdaMbTiPcOx (formula 1> where M is selected from Cd, Au, Zn, Tl, alkali metals and alkaline earth metals, a is from 0.0005 to 0.2 b is from zero to 3a c is 0.5 to 2.5, and x is a value sufficient to satisfy the valence requirements of the other elements present, and wherein such catalyst contains crystalline TiP2O7.