公开(公告)号：DE69026752D1

公开(公告)日：1996-06-05

申请号：DE69026752

申请日：1990-05-24

Applicant: STANDARD OIL CO OHIO

Inventor： CABLE THOMAS L ,  MAZANEC TERRY J ,  FRYE JOHN G

IPC: C04B35/00 ,  B01D53/32 ,  B01D71/02 ,  B01J4/04 ,  B01J8/00 ,  B01J12/00 ,  B01J19/00 ,  B01J19/08 ,  B01J19/24 ,  B01J23/10 ,  B01J23/26 ,  B01J23/63 ,  B01J23/76 ,  B01J23/86 ,  B01J35/00 ,  B01J35/06 ,  C01B3/24 ,  C01B3/36 ,  C01B3/38 ,  C01B13/02 ,  C01B13/14 ,  C01C3/02 ,  C01G45/00 ,  C01G49/00 ,  C01G51/00 ,  C25B3/23 ,  C25B5/00 ,  H01M8/12

Abstract: Solid membranes comprising an intimate, gas-impervious, multi-phase mixture of an electronically-conductive material and an oxygen ion-conductive material and/or a mixed metal oxide of a perovskite structure are described. Electrochemical reactor cells and reactors are also described for transporting oxygen from any oxygen-containing gas to any gas that consumes oxygen. The reactor cells generally comprise first and second zones separated by the solid membrane. The reactor cell may further comprise a catalyst in the first zone. Processes described which may be conducted with the disclosed reactor cells and reactors include, for example, the partial oxidation of methane to produce unsaturated compounds or synthesis gas, the partial oxidation of ethane, extraction of oxygen from oxidized gases, ammoxidation of methane, etc. The extraction of oxygen from oxidized gases may be used for flue or exhaust gas clean-up.

公开(公告)号：DE3854757D1

公开(公告)日：1996-01-18

申请号：DE3854757

申请日：1988-09-29

Applicant: STANDARD OIL CO OHIO

Inventor： CABLE THOMAS L ,  MAZANEC TERRY J ,  FRYE JOHN G

IPC: H01M8/22 ,  B01J19/00 ,  C25B3/00 ,  H01M4/90 ,  H01M8/12 ,  C25B5/00 ,  C25B1/00

Abstract: An electrocatalytic process is described for producing synthesis gas from light hydrocarbons such as methane or natural gas. The process generally comprises the steps of (A) providing an electrochemical cell comprising a solid electrolyte having a first surface coated with conductive metal, metal oxide or mixtures thereof capable of facilitating the reduction of oxygen to oxygen ions, and a second surface coated with conductive metal, metal oxide or mixtures thereof, provided that both coatings are stable at the operating temperatures, (B) heating the cell to a temperature of at least 1000 DEG C, (C) passing an oxygen-containing gas in contact with the first conductive coating, (D) passing methane, natural gas or other light hydrocarbons in contact with the second conductive coating, and (E) recovering synthesis gas.

公开(公告)号：ZA9010408B

公开(公告)日：1991-10-30

申请号：ZA9010408

申请日：1990-12-27

Applicant: STANDARD OIL CO OHIO

Inventor： MAZANEC TERRY J ,  TERRY J MAZANEC ,  CABLE THOMAS L ,  THOMAS L CABLE ,  FRYE JOHN G JR ,  JOHN G FRYE JR ,  KLIEWER WAYNE R ,  WAYNE R KLIEWER

IPC: B01B20060101 ,  C01B20060101 ,  C25B20060101 ,  C25C20060101 ,  C25C ,  B01B ,  C01B ,  C25B

公开(公告)号：AU608068B2

公开(公告)日：1991-03-21

申请号：AU2344288

申请日：1988-10-05

Applicant: STANDARD OIL CO OHIO

Inventor： MAZANEC TERRY J ,  CABLE THOMAS L ,  FRYE JOHN G JR

IPC: H01M8/22 ,  B01J19/00 ,  C25B3/00 ,  H01M4/90 ,  H01M8/12 ,  C25B1/00 ,  C01B3/26

Abstract: An electrocatalytic process is described for producing synthesis gas from light hydrocarbons such as methane or natural gas. The process generally comprises the steps of (A) providing an electrochemical cell comprising a solid electrolyte having a first surface coated with conductive metal, metal oxide or mixtures thereof capable of facilitating the reduction of oxygen to oxygen ions, and a second surface coated with conductive metal, metal oxide or mixtures thereof, provided that both coatings are stable at the operating temperatures, (B) heating the cell to a temperature of at least 1000 DEG C, (C) passing an oxygen-containing gas in contact with the first conductive coating, (D) passing methane, natural gas or other light hydrocarbons in contact with the second conductive coating, and (E) recovering synthesis gas.

公开(公告)号：CA2017243A1

公开(公告)日：1990-11-25

申请号：CA2017243

申请日：1990-05-22

Applicant: STANDARD OIL CO OHIO

Inventor： MAZANAC TERRY J ,  CABLE THOMAS L ,  FRYE JOHN G JR ,  KLIEWER WAYNE R

IPC: C04B35/00 ,  B01D53/32 ,  B01D71/02 ,  B01J4/04 ,  B01J8/00 ,  B01J12/00 ,  B01J19/00 ,  B01J19/08 ,  B01J19/24 ,  B01J23/10 ,  B01J23/26 ,  B01J23/63 ,  B01J23/76 ,  B01J23/86 ,  B01J35/00 ,  B01J35/06 ,  C01B3/24 ,  C01B3/36 ,  C01B3/38 ,  C01B13/02 ,  C01B13/14 ,  C01C3/02 ,  C01G45/00 ,  C01G49/00 ,  C01G51/00 ,  C25B3/23 ,  C25B5/00 ,  H01M8/12 ,  C25B1/00 ,  C25B9/00 ,  C25B15/08 ,  H01M8/10 ,  C25B11/20

Abstract: RFK-3088 (CIP) Title: NOVEL SOLID MULTI-COMPONENT MEMBRANES, ELECTRO CHEMICAL REACTOR AND USE OF MEMBRANES AND REAC TOR FOR OXIDATION REACTIONS Solid membranes comprising an intimate, gasimpervious, multi-phase mixture of an electronically-con-ductive material and an oxygen ion-conductive material and/or a mixed metal oxide of a perovskite structure are described. Electrochemical reactor cells and reactors are also described for transporting oxygen from any oxygen-containing gas to any gas that consumes oxygen. The reactor cells generally comprise first and second zones separated by the solid membrane. The reactor cell may further comprise a catalyst in the first zone. Processes described which may be conducted with the disclosed reactor cells and reactors include, for example, the partial oxidation of methane to produce unsaturated compounds or synthesis gas, the partial oxidation of ethane, extraction of oxygen from oxidized gases, ammoxidation of methane, etc. The extraction of oxygen from oxidized gases may be used for flue or exhaust gas cleanup.

公开(公告)号：AU3833197A

公开(公告)日：1999-04-01

申请号：AU3833197

申请日：1997-09-17

Applicant: STANDARD OIL CO OHIO

Inventor： MAZANEC TERRY J ,  CABLE THOMAS L

IPC: B01D71/02

公开(公告)号：ES2100877T3

公开(公告)日：1997-07-01

申请号：ES90314083

申请日：1990-12-20

Applicant: STANDARD OIL CO OHIO

Inventor： CABLE THOMAS L ,  FRYE JOHN G JR ,  KLIEWER WAYNE R ,  MAZANEC TERRY J

IPC: B01D53/32 ,  B01D71/02 ,  B01J4/04 ,  B01J8/00 ,  B01J12/00 ,  B01J19/00 ,  B01J19/24 ,  B01J23/86 ,  C01B3/36 ,  C01B3/38 ,  C01B13/02 ,  C01C3/02 ,  C01G45/00 ,  C01G49/00 ,  C01G51/00 ,  C25B3/23 ,  C25B5/00 ,  H01M4/86 ,  H01M8/02 ,  H01M8/12 ,  H01M8/10 ,  C25B3/00 ,  C25B1/00

Abstract: An element for use in an electrochemical cell has a first zone for introducing an oxygen-containing gas and a second zone separated from first zone by the element, which has a membrane with first and second surfaces, conducts oxygen ions therebetween, and has a catalyst exposed to at least the first zone. The element may be used to separate oxygen.

公开(公告)号：DE69030651D1

公开(公告)日：1997-06-12

申请号：DE69030651

申请日：1990-12-20

Applicant: STANDARD OIL CO OHIO

Inventor： CABLE THOMAS L ,  FRYE JOHN G ,  KLIEWER WAYNE R ,  MAZANEC TERRY J

IPC: B01D53/32 ,  B01D71/02 ,  B01J4/04 ,  B01J8/00 ,  B01J12/00 ,  B01J19/00 ,  B01J19/24 ,  B01J23/86 ,  C01B3/36 ,  C01B3/38 ,  C01B13/02 ,  C01C3/02 ,  C01G45/00 ,  C01G49/00 ,  C01G51/00 ,  C25B5/00 ,  H01M4/86 ,  H01M8/02 ,  H01M8/12 ,  H01M8/10 ,  C25B3/00 ,  C25B1/00

Abstract: An element for use in an electrochemical cell has a first zone for introducing an oxygen-containing gas and a second zone separated from first zone by the element, which has a membrane with first and second surfaces, conducts oxygen ions therebetween, and has a catalyst exposed to at least the first zone. The element may be used to separate oxygen.

公开(公告)号：DE3854757T2

公开(公告)日：1996-04-25

申请号：DE3854757

申请日：1988-09-29

Applicant: STANDARD OIL CO OHIO

Inventor： CABLE THOMAS L ,  MAZANEC TERRY J ,  FRYE JOHN G

IPC: H01M8/22 ,  B01J19/00 ,  C25B3/00 ,  H01M4/90 ,  H01M8/12 ,  C25B5/00 ,  C25B1/00

Abstract: An electrocatalytic process is described for producing synthesis gas from light hydrocarbons such as methane or natural gas. The process generally comprises the steps of (A) providing an electrochemical cell comprising a solid electrolyte having a first surface coated with conductive metal, metal oxide or mixtures thereof capable of facilitating the reduction of oxygen to oxygen ions, and a second surface coated with conductive metal, metal oxide or mixtures thereof, provided that both coatings are stable at the operating temperatures, (B) heating the cell to a temperature of at least 1000 DEG C, (C) passing an oxygen-containing gas in contact with the first conductive coating, (D) passing methane, natural gas or other light hydrocarbons in contact with the second conductive coating, and (E) recovering synthesis gas.

公开(公告)号：CA2158607A1

公开(公告)日：1996-03-24

申请号：CA2158607

申请日：1995-09-19

Applicant: STANDARD OIL CO OHIO

Inventor： MAZANEC TERRY J ,  CABLE THOMAS L

IPC: B01D53/22 ,  B01D53/32 ,  B01D71/02 ,  B01J8/00 ,  B01J19/00 ,  B01J19/24 ,  C01B3/38 ,  C01B13/02 ,  C01G51/00 ,  C01G53/00 ,  C04B35/01

Abstract: The present invention relates to novel solid state mixed conductor membranes and their use for separating oxygen from oxygen-containing feeds at elevated temperatures. The membranes comprise a multicomponent metallic oxide of substantially cubic perovskite structure, stable in air over the temperature range of 25-950.degree.C, having no connected through porosity wherein the membrane is of a composition represented by the formula ¢A1-xA'x!¢Co1-y-zByB'z!O3-.delta., where A - Ca, Sr, Ba, and mixtures thereof; A' - La, Y, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Th, U, and mixtures thereof; B = Fe, Mn, Cr, V, Ti, and mixtures thereof; B' - Cu, Ni, and mixtures thereof; ?0.0001 ?0.0005 metals.