PREPARATION OF ANTIPLASTICIZERS FOR THERMOPLASTIC POLYESTERS
    12.
    发明公开
    PREPARATION OF ANTIPLASTICIZERS FOR THERMOPLASTIC POLYESTERS 有权
    制造固化热固性聚酯

    公开(公告)号:EP2688950A2

    公开(公告)日:2014-01-29

    申请号:EP12765577.7

    申请日:2012-02-09

    Applicant: Stepan Company

    Abstract: A process for making bis(aryloxyalkyl)terephthalates useful as antiplasticizers for thermoplastic polyesters is disclosed. Dimethyl terephthalate is reacted with an excess of an aryloxyalkanol in the presence of a condensation catalyst to produce an intermediate mixture comprising a bis(aryloxyalkyl)terephthalate, a mono(aryloxyalkyl)terephthalate, and unreacted aryloxyalkanol. This mixture continues to react at reduced pressure while unreacted aryloxyalkanol is removed and the mono-ester content is reduced to less than 1 mole % based on the combined amounts of mono- and bis-esters. Both steps are performed substantially in the absence of oxygen. Additional unreacted aryloxyalkanol is then removed to provide a purified bis(aryloxyalkyl)terephthalate having an overall purity of at least 98 mole % and a yellowness index less than 10. Careful control over catalysis, exposure to air, and other process conditions enables the preparation of high yields of bis(aryloxyalkyl)terephthalates that have low color and other valuable attributes. A method of producing bis(aryloxyalkyl)terephthalate articles having improved compressive strength is also disclosed.

    DETERGENTS FOR COLD-WATER CLEANING
    14.
    发明公开
    DETERGENTS FOR COLD-WATER CLEANING 审中-公开
    凯恩斯堡的REINIGUNGSMITTELFÜRREINIGUNG

    公开(公告)号:EP3152286A2

    公开(公告)日:2017-04-12

    申请号:EP15730027.8

    申请日:2015-06-08

    Applicant: Stepan Company

    Abstract: Detergents useful for cold-water cleaning and mid-chain headgroup and alkylene-bridged surfactants useful therein are disclosed. The mid-chain headgroup surfactant has a C14-C30 alkyl chain and a polar group bonded to a central zone carbon of the alkyl chain. The alkylene-bridged surfactant has a C12-C18 alkyl chain, a polar group, and a C1-C2 alkylene group bonded to the polar group and a central zone carbon of the C12-C18 alkyl chain. Preferred surfactants in these classes are alcohol sulfates, alcohol ethoxylates, ether sulfates, sulfonates, arylsulfonates, alcohol phosphates, amine oxides, quaterniums, betaines, and sulfobetaines. Surprisingly, detergents formulated with the surfactants provide outstanding cold-water performance in removing greasy stains such as bacon grease, butter, cooked beef fat, or beef tallow from soiled articles.

    Abstract translation: 公开了可用于冷水清洗的洗涤剂和可用于其中的中链头团和亚烷基桥接表面活性剂。 中链头团表面活性剂具有C 14 -C 30烷基链和与烷基链的中心区碳键合的极性基团。 亚烷基桥连表面活性剂具有C12-C18烷基链,极性基团和与极性基团键合的C1-C2亚烷基和C12-C18烷基链的中心区碳。 这些类别中优选的表面活性剂是醇硫酸盐,醇乙氧基化物,醚硫酸盐,磺酸盐,芳基磺酸盐,醇磷酸盐,氧化胺,季铵盐,甜菜碱和磺基甜菜碱。 令人惊讶的是,用表面活性剂配制的洗涤剂提供出色的冷水性能,从去污的物品中除去培养油脂,黄油,熟牛肉或牛脂等油污。

    SURFACTANTS AND SOLVENTS CONTAINING DIELS-ALDER ADDUCTS
    16.
    发明公开
    SURFACTANTS AND SOLVENTS CONTAINING DIELS-ALDER ADDUCTS 审中-公开
    含有DIELS-ALDER增容剂的表面活性剂和溶剂

    公开(公告)号:EP2831139A1

    公开(公告)日:2015-02-04

    申请号:EP13769569.8

    申请日:2013-03-27

    Applicant: Stepan Company

    Abstract: Surfactants and solvents containing derivatized adducts formed from Diels-Aider reactions of terpenes and unsaturated carboxylic acids or their derivatives are disclosed. Processes for making and derivatizing the Diels-Aider adducts are also disclosed. In some embodiments, the Diels-Aider adducts are prepared by reacting farnesene or myrcene with an unsaturated carboxylic acid or its ester or anhydride. In other embodiments, the Diels-Aider adducts are prepared by reacting farnesene or myrcene with an unsaturated nitrile. The Diels-Aider adducts are then derivatized in a variety of ways to form the anionic, cationic, amine oxide, amphoteric or nonionic surfactants.

    Abstract translation: 公开了含有由萜烯和不饱和羧酸或其衍生物的狄尔斯 - 艾德反应形成的衍生化加合物的表面活性剂和溶剂。 还公开了制造和衍生Diels-Aider加合物的方法。 在一些实施方案中,Diels-Aider加合物通过使法呢烯或月桂烯与不饱和羧酸或其酯或酸酐反应来制备。 在其他实施方案中,Diels-Aider加合物通过使法呢烯或月桂烯与不饱和腈反应来制备。 然后以各种方式衍生Diels-Aider加合物,以形成阴离子,阳离子,氧化胺,两性或非离子表面活性剂。

Patent Agency Ranking