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公开(公告)号:JP2002069751A
公开(公告)日:2002-03-08
申请号:JP2001160602
申请日:2001-05-29
Applicant: TORAY INDUSTRIES , TORAY MONOFILAMENT CO
Inventor: MASUDA TOYOHIKO , MAEDA YUHEI , AONO SHOJI , KINOSHITA AKIRA , YAMAGAMI TAKAYUKI
Abstract: PROBLEM TO BE SOLVED: To provide a polyester monofilament improved in hydrolytic resistance and life under high temperature and high humidity and an industrial woven fabric typified by papermaking drier canvas using its monofilament. SOLUTION: This polyester monofilament is characterized in that the monofilament comprises >=80 wt.% saturated polyester (A) containing 0.2-15 wt.% styrene-2-isopropenyl-2-oxazoline random copolymer (B) and >=0.02 wt.% unreacted monocarbodiimide compound and the terminal carboxyl group concentration is
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公开(公告)号:JPH09118814A
公开(公告)日:1997-05-06
申请号:JP24147696
申请日:1996-09-12
Applicant: TORAY INDUSTRIES
Inventor: SHIMIZU YUZO , AONO SHOJI , SUZUKI MASARU
Abstract: PROBLEM TO BE SOLVED: To obtain the subject composition containing a large amount of calcium carbonate having specific particle diameter, not, containing aggregate particles, having high whiteness, hardly becoming yellowish color, excellent in hiding power and capable of providing white film excellent in hiding power. SOLUTION: In this composition, a polyester contains >50wt.% calcium carbonate having 0.05-5.0μm average particle diameter and comprises an ethylene terephthalate having at least 80mol% of recurring unit and a ratio of P content to Ca content in the particles separated from the polyester by a prescribed method is 0.002-0.05. Furthermore, e.g. a method for adding o-chlorophenol to the polyester, dissolving the polyester into o-chlorophenol at 150 deg.C under stirring, cooling the solution to 25 deg.C, adding acetone to the resultant separated particles and similarly repeating ultra-centrifugation is preferably used as the method for separating particles from the polyester.
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公开(公告)号:JPH06179741A
公开(公告)日:1994-06-28
申请号:JP33147992
申请日:1992-12-11
Applicant: TORAY INDUSTRIES
Inventor: AONO SHOJI , SHIMIZU YUZO , SUZUKI MASARU
IPC: B29C55/12 , B29K67/00 , B29L7/00 , B41N1/24 , C08G63/16 , C08G63/181 , C08G63/199 , C08J5/18
Abstract: PURPOSE:To obtain a polyester for heat-sensitive stencil printing base paper, comprising an acid component composed of an aromatic dicarboxylic acid, etc., and a glycol component composed of an aliphatic glycol, etc., having a specific melting point, excellent in perforating properties by heat and brightness in printing and useful for facsimile, etc. CONSTITUTION:The objective polyester comprises a principal acid component composed of an aromatic dicarboxylic acid and/or an alicyclic dicarboxylic acid (preferably terephthalic acid, isophthalic acid or 2,6-naphthalenedicarboxylic acid) and a principal glycol component composed of a 6-10C aliphatic glycol and/or a 6-l6C alicyclic glycol (preferably 1,6-hexandiol or 1,4- cyclohexandimethanol) and has 100-220 deg.C (preferably 150-200 deg.C) melting point. Furthermore, a titanium compound is preferably used as a reaction catalyst in an amount of 0.001-0.05wt.% based on the resultant polyester.
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公开(公告)号:JPH0584880A
公开(公告)日:1993-04-06
申请号:JP25210491
申请日:1991-09-30
Applicant: TORAY INDUSTRIES
Inventor: SHIMIZU YUZO , AONO SHOJI , SUZUKI MASARU
IPC: B32B27/36 , C08G63/66 , C08G63/672 , C08G63/688 , C08J5/18 , C08L67/00
Abstract: PURPOSE:To obtain an easily adhering film which has excellent adhesion and anti-blocking properties, and also can be applied as a base film such as a magnetic recording material by laminating a specific watersoluble copolymerized polyester as an easily adherable layer on the one surface of a polyester film. CONSTITUTION:A specific water-soluble copolymerized polyester is laminated as an easily adhering layer on the one surface of a polyester film to constitute an easily adhering polyester film. In this case, the water-soluble copolymerized polyester is composed of higher than 50mol% of an aromatic dicarboxylic acid component and 5 to 50mol% of an ester-forming alkali metal sulfonate and glycol component. Further, the 2,2' bis(4'-hydroxyphenyl)propane derivative shown in a separately described formula is copolymerized by a ratio of 5 to 90mol% for a total glycol component (in the formula, R is a divalent hydrocarbon group and R' is phenylene. In addition, m, n are an integer of 1 or higher respectively and m+n is an integer of 2 or higher).
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公开(公告)号:JPH03231960A
公开(公告)日:1991-10-15
申请号:JP2783790
申请日:1990-02-07
Applicant: TORAY INDUSTRIES
Inventor: SHIMIZU YUZO , AONO SHOJI , SUZUKI MASARU
Abstract: PURPOSE:To provide a polyester composition having excellent transparency and antistaticity by compounding a sulfonate metal soft compound and a specific metal element in speficied amounts, respectively with a polyester. CONSTITUTION:100 pts.wt. of a polyester (e.g. polyethylene terephthalate) is compounded with (A) 0.01-20 pts.wt., preferably 0.1-10 pts.wt. of a sulfonic and metal soft compound of the formula [R is alkyl, alkylaryl, aryl; M is alkali (earth) metal; m is 1 or 1/2] or a sulfonic acid metal salt derivative containing 0.01-10wt.%, preferably 0.01-5wt.%, of are kind or more of metal elements selected from alkali (earth) metals different from the metal element of the compound, Mn, Zn and Co and (B) 0.01-20 pts.wt., preferably 0.5-8 pts.wt., of a polyoxyalkylene glycol to provide the objective composition.
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公开(公告)号:JPH01225626A
公开(公告)日:1989-09-08
申请号:JP5165888
申请日:1988-03-07
Applicant: TORAY INDUSTRIES
Inventor: SHIMIZU YUZO , AONO SHOJI , SUZUKI MASARU
Abstract: PURPOSE:To inhibit the sedimentation and agglomeration of particles and the deterioration of the color tone of a polymer, and to improve the whiteness, by adding a specific slurry at an arbitrary stage during the reaction of a dicarboxylic acid (derivatives capable of forming esters) with ethylene glycol. CONSTITUTION:10-80wt.% CaCO3 (a) having a mean particle diameter of 0.05-5mum, preferably 0.2-2mum, is dispersed in ethylene glycol (b), and the dispersion is subjected to heat treatment at 50 deg.C - the boiling point, preferably 70-150 deg.C to obtain an ethylene glycol slurry (C) containing the components (a). While a dicarboxylic acid (derivatives capable of forming esters) (A) (e.g., dimethyl terephthalate) is reacted with ethylene glycol (B), and the component (C) is added at an arbitrary stage of the reaction of the components (A) and (B) with the amount of the component (C) such that the content of the component (b) of the polyester which will be obtained will be 5-60wt.%, thereby producing the polyester. The obtained polyester is molded into a sheet, stretched biaxially 2.5-4.0-fold respectively and thermally fixed at 150 deg.C or over, thereby producing a white polyester film having a density of 0.90-1.38g/cm .
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公开(公告)号:JP2003213589A
公开(公告)日:2003-07-30
申请号:JP2002061252
申请日:2002-03-07
Applicant: TORAY INDUSTRIES , TORAY MONOFILAMENT CO
Inventor: MASUDA TOYOHIKO , MAEDA YUHEI , AONO SHOJI , KINOSHITA AKIRA , YAMAGAMI TAKAYUKI
Abstract: PROBLEM TO BE SOLVED: To provide a fabric for paper machine for papermaking wired, papermaking dryer canvases and the like having high soil-proofness to adhesive soils such as gummed tape adhesive paste. SOLUTION: This fabric for paper machine, made by weaving synthetic fibers, has a cloth adhesive tape peel stress of ≤300 cN/2.5 cm. COPYRIGHT: (C)2003,JPO
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公开(公告)号:JP2002348735A
公开(公告)日:2002-12-04
申请号:JP2001161061
申请日:2001-05-29
Applicant: TORAY INDUSTRIES , TORAY MONOFILAMENT CO
Inventor: AONO SHOJI , MASUDA TOYOHIKO , KINOSHITA AKIRA
Abstract: PROBLEM TO BE SOLVED: To provide a polyester monofilament improved with its hydrolysis resistance and excellent in life under a high temperature and high humidity condition, and an industrial woven fabric. SOLUTION: This polyester monofilament consists of a polyester composition containing >=80 wt.% saturated polyester (A), 0.2-15 wt.% random copolymer (B) of styrene.acrylonitrile.2-isopropenyl-2-oxazoline, and >=0.02 wt.% un-reacted monocarbodiimide compound (C), and having g monofilament.
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公开(公告)号:JP2002275730A
公开(公告)日:2002-09-25
申请号:JP2001180954
申请日:2001-06-15
Applicant: TORAY INDUSTRIES , TORAY MONOFILAMENT CO
Inventor: MASUDA TOYOHIKO , AONO SHOJI , KINOSHITA AKIRA , SAKUGI AKIRA
Abstract: PROBLEM TO BE SOLVED: To provide a polyamide monofilament having a low compression strain rate, and further having improved flexing abrasion resistance and flexing fatigue resistance, and further to provide an industrial woven fabric exemplified by a woven fabric to be attached to a paper machine such as a paper machine press felt, using the monofilament and having good squeezing efficiency. SOLUTION: In this polyamide monofilament the compression strain rate is =2.2×10 . The industrial woven fabric uses the monofilament at least as a part.
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公开(公告)号:JP2000212834A
公开(公告)日:2000-08-02
申请号:JP1304199
申请日:1999-01-21
Applicant: TORAY INDUSTRIES
Inventor: KONNO YOSHIHIRO , AONO SHOJI
IPC: D01F8/14
Abstract: PROBLEM TO BE SOLVED: To obtain an antistatic polyester fiber having a good antistatic property and capable of being dyed into various kinds of colors by forming a sheath component having a specific thickness and containing a matting agent on the periphery of a core component containing an antistatic agent and a matting agent. SOLUTION: This antistatic polyester fiber is a sheath-core type conjugate antistatic polyester fiber. Therein, the core component contains a matting agent such as titanium dioxide in an amount of 0.6-10 wt.% and an antistatic agent such as a blocked polyetheramide containing 1-10 wt.% of R-SO3M groups [R is an 8-15C alkyl; M is an alkali (earth) metal] in an amount of 0.2-3 wt.% based on the total weight of the fiber. The antistatic agent and the matting agent are preferably adjusted in a weight ratio of 0.3-2.0. The sheath component contains a matting agent in an amount of =1.5 μm in the diameter direction of the fiber. The antistatic polyester is preferably cut in a length of
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