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    11.
    发明专利
    未知

    公开(公告)号：DE1668729A1

    公开(公告)日：1972-03-23

    申请号：DE1668729

    申请日：1967-10-03

    Applicant: TORAY INDUSTRIES

    Inventor： HATA GO ,  AOYAMA MASAHIRO ,  NISHINO MASAKI ,  MIYAKE AKIHISA

    IPC: C07C2/04

    Abstract: 1,150,848. Condensation catalysts. TOYO RAYON K.K. 3 Oct., 1967 [4 Oct., 1966], No. 44905/67. Heading B1E [Also in Division C5] Catalysts used in the co-dimerisation of ethylene and a conjugated diene (see Division C5) comprise:- a) a cobalt salt (including inorganic and organic salts, and chelate compounds), b) a sulphur-containing tertiary phosphine having one 'of the formulae where the R's are organic groups and n is 2 or 3, and c) an organo-aluminium compound of formula where R 4 and R 5 are C 1-10 hydrocarbon groups and X is halogen or a C 1 _ 10 hydrocarbon group.

    REDUCTIVE ADDITION REACTION OF AROMATIC HYDROCARBON
    13.
    发明专利
    REDUCTIVE ADDITION REACTION OF AROMATIC HYDROCARBON 失效

    公开(公告)号：JPS55162727A

    公开(公告)日：1980-12-18

    申请号：JP4876080

    申请日：1980-04-15

    Applicant: TORAY INDUSTRIES

    Inventor： YASUHARA YUTAKA ,  NISHINO MASAKI ,  MATSUHISA SEIKICHI

    IPC: C07C69/03 ,  B01J23/00 ,  B01J23/40 ,  C07B61/00 ,  C07C27/00 ,  C07C29/00 ,  C07C29/19 ,  C07C35/08 ,  C07C67/00 ,  C07C67/04

    Abstract: PURPOSE:To prepare a cyclohexanol derivative useful as a solvent and a raw material of polymer, in one step, by the reductive addition reaction of an aromatic hydrocarbon with hydrogen in the presence of a mixture containing a strong acid, water, and if necessary, an organic acid, using a noble metal of VIII group of the periodic table as a catalyst. CONSTITUTION:The preparation of cyclohexanol derivative of formula (Ac is H, organic acid residue or strong acid residue; R is alkyl; n is 0, 1 or 2) by the hydrogenation of an aromatic hydrocarbon (e.g. benzene) using a noble metal of the VIII group of the periodic table (pref. Ru or Rh) as a catalyst, is carried out in the presence of a strong acid, and water and/or an organic acid. The presence of the strong acid is essential, and its amount is >=2% of the sum of the strong acid and water and/or an organic acid. The strong acid is, e.g. sulfuric acid, phosphoric acid, etc., and the organic acid is, preferably acetic acid.

    PREPARATION OF ALIPHATIC TRIISOCYANATE
    14.
    发明专利
    PREPARATION OF ALIPHATIC TRIISOCYANATE 失效

    公开(公告)号：JPS5519202A

    公开(公告)日：1980-02-09

    申请号：JP8297078

    申请日：1978-07-10

    Applicant: TORAY INDUSTRIES

    Inventor： NISHINO MASAKI ,  YASUHARA YUTAKA

    IPC: C07D223/04 ,  C07C67/00 ,  C07C209/00 ,  C07C209/26 ,  C07C211/13 ,  C07C213/00 ,  C07C225/06 ,  C07C225/28 ,  C07C241/00 ,  C07C265/10 ,  C07C265/14

    Abstract: NEW MATERIAL:An aliphatic triisocyanate I (n is integer of >= 4). EXAMPLE:1,6,11-Undecatriisocyanate. USE:A raw material for polymers, e.g. coatings, films, foams, elastomers, adhesives, fibers, etc., Excellent in light stability, weather resistance and solvent resistance. Coating film prepared from the compound has excellent quick-drying characteristics, surface hardness, etc. PREPARATION:The compound I is prepared by (1) decarboxylating and dimerizing an aliphatic lactam, an alpha,omega-aminocarboxylic acid or their polymer in the presence of a strong base, (2) converting the resulted amino shiff base II or diaminoketon III to a triamine IV by the catalytic reduction with hydrogen in the presence of ammonia, and (3) reacting the triamine IV with phosgene. The compound II and III are in equilibrium in the presence of water.

    PREPARATION OF 1*6*111UNDECANETRIAMINE
    20.
    发明专利
    PREPARATION OF 1*6*111UNDECANETRIAMINE 失效

    公开(公告)号：JPS55153750A

    公开(公告)日：1980-11-29

    申请号：JP6086779

    申请日：1979-05-17

    Applicant: TORAY INDUSTRIES

    Inventor： YASUHARA YUTAKA ,  NISHINO MASAKI

    IPC: C07B61/00 ,  B01J23/00 ,  B01J23/74 ,  C07C67/00 ,  C07C209/00 ,  C07C209/26 ,  C07C209/52 ,  C07C209/62 ,  C07C211/13

    Abstract: PURPOSE:To prepare 1,6,11-undecanetriamine, economically, without using water, by catalytically reducing aminopentyl-tetrahydroazepin with hydrogen gas in the presence of a small amount of ammonia and reduced nickel catalyst. CONSTITUTION:7-(5'-Aminopentyl)-3,4,5,6-tetrahydro-2H-azepin I is catalytically reduced with hydrogen gas in the presence of ammonia and a reduced nickel catalyst to give 1,6,11-undecanetriamine II. Preferably the amount of ammonia is 1.2- 2.5mol on the basis of 1mol of the azepin I and the amount of water is 0-1pts.wt. on the basis of 1pt.wt. of the azepin.

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