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公开(公告)号:CA1207939A
公开(公告)日:1986-07-15
申请号:CA437130
申请日:1983-09-20
Applicant: TORAY INDUSTRIES
Inventor: FUKUDA TADANORI , SAKAMOTO SADAYUKI
IPC: C08G18/67
Abstract: RESIN MATERIAL FOR PLASTIC LENS AND LENS COMPOSED THEREOF A polymer obtained by polymerizing a urethanized acrylic or methacrylic monomer obtained by reacting the hydroxyl group of an acrylic or methacrylic monomer having a nucleus-halogen-substituted aromatic ring and a hydroxyl group with the isocyanate group of a polyfunctional isocyanate is excellent and has a high refractive index. Accordingly, this polymer is valuable as a resin material for a plastic lens.
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公开(公告)号:DE3374869D1
公开(公告)日:1988-01-21
申请号:DE3374869
申请日:1983-09-22
Applicant: TORAY INDUSTRIES
Inventor: FUKUDA TADANORI , SAKAMOTO SADAYUKI
Abstract: A resin material (I) for a plastic lens, having a refractive index of at least 1.58. (I) is a homopolymer of a urethanised acrylic or methacrylic monomer (II) or a copolymer of (II) with another vinyl monomer (III) having an aromatic ring. (II) is produced by the reaction of an OH gp. of an acrylic or methacrylic monomer (IV) with an nNCO gp. of a polyfunctional isocyanate (V). (IV) has a nucleus-halogen-substd. aromatic ring and has the formula (a),(b) or (c): X=Cl, Br or I; each of R1 and R2=H or CH3;n=an integer 1-4; and 1 and m=integers 0-4, but 1 + m=0-4. The copolymer of (II) and (III) contains up to 70 wt.% (III).
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公开(公告)号:DE2924149A1
公开(公告)日:1979-12-20
申请号:DE2924149
申请日:1979-06-15
Applicant: TORAY INDUSTRIES
Inventor: NISHINO MASAKI , YASUHARA YUTAKA , FUKUDA TADANORI , SAKAMOTO SADAYUKI
IPC: C07C263/10 , C07C265/04 , C08G18/73 , C08G18/75 , C09D175/00 , C07C119/042 , C07C118/02 , C09D3/72
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公开(公告)号:HK92389A
公开(公告)日:1989-12-01
申请号:HK92389
申请日:1989-11-23
Applicant: TORAY INDUSTRIES
Inventor: FUKUDA TADANORI , SAKAMOTO SADAYUKI
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公开(公告)号:CA1125299A
公开(公告)日:1982-06-08
申请号:CA340881
申请日:1979-11-29
Applicant: TORAY INDUSTRIES
Inventor: NISHINO MASAKI , YASUHARA YUTAKA , FUKUDA TADANORI , SAKAMOTO SADAYUKI
IPC: C08G18/00 , C07C265/04 , C08G18/73 , C09D175/00 , C07C119/042
Abstract: There is provided a novel aliphatic triisocyanate, 1,6,11-undecanetriisocyanate having the formula, and a method for production of the same. The novel triisocyanate is produced by reacting 1.6,11-undecanetriamine or its salts with phosgene. A non-yellowing polyurethane prepared therefrom provide an excellent coating composition.
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公开(公告)号:CA1174398A
公开(公告)日:1984-09-11
申请号:CA333511
申请日:1979-08-10
Applicant: TORAY INDUSTRIES
Inventor: FUKUDA TADANORI , SAKAMOTO SADAYUKI , SAITO MASAMI
Abstract: Polyurethane resins with an excellent weather resistance are provided by the reaction of polyols with trifunctional isocyanates which are expressed by the following general formula: (R = a remnant of divalent hydrocarbon group with the carbon number of 2 or 3) The reaction between a polyol and a trifunctional isocyanate is effectuated at an NCO/OH mole percentage of 0.5 to 2.0 and adjustments are made so that the concentration of carbamide group will be 5 x 10-4 to 50 x 10-4 moles per gram of the reaction product and that the bridging parameter will be 150 to 1,500. The resins may be used to best advantage as polyurethane resin coatings excelling in weather resistance.
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公开(公告)号:FR2437402A1
公开(公告)日:1980-04-25
申请号:FR7915585
申请日:1979-06-18
Applicant: TORAY INDUSTRIES
Inventor: NISHINO MASAKI , YASUHARA YUTAKA , FUKUDA TADANORI , SAKAMOTO SADAYUKI
IPC: C07C263/10 , C07C265/04 , C08G18/73 , C08G18/75 , C09D175/00 , C07C119/042 , C07C118/02 , C08G18/72 , C09D3/72
Abstract: (I), having formula OCN-(CH2)5-CH(NCO)-(CH2)5-NCO, is new. (I) is prepd. by reacting 1,6,11-undecane-triamine, (II), or a salt thereof, with phosgene in an inert organic medium, either (i) at 60-230 degrees C., or (pref.) (ii) at 40 degrees C. with pyrolysis of the carbamoyl chloride obtd. in the presence of phosgene at 60-230 degrees C. (I) is used for preparing polyurethanes, esp. for coating compsns., by reaction with a polyol. Paint media can be used for cars, railways, containers, aeroplanes, seamless floors, coils, ships, railways, containers, aeroplanes, seamless (I) is less toxic than other aliphatic isocyanates, e.g. hexamethylene diisocyanate; is stable to alkali; boils at 166-177 degrees C./0.2 Torr; is easily purified by vacuum distn. and causes no irritating smell or vapour; and has low viscosity. The polyurethanes obtd. are glossy, stable to water, acids, bases, solvents and light.
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公开(公告)号:JPH02283731A
公开(公告)日:1990-11-21
申请号:JP10425389
申请日:1989-04-24
Applicant: TORAY INDUSTRIES
Inventor: MORI KAORU , SAKAMOTO SADAYUKI , OKA KOICHIRO
Abstract: PURPOSE:To obtain an optical resin being free from the problem of a pot life and having a high refractive index and sufficient heat resistance by using a polymerizable prepolymer prepared by reacting divinylbenzene or a specified compound with an aliphatic polythiol compound. CONSTITUTION:This optical resin contains a polymeriable component comprising at least a polymerizable prepolymer obtained by the addition reaction of divinylbenzene and/or a compound of formula I (wherein X is H or CH3) with an aliphatic polythiol compound of formula II [wherein (n) is 1-3; and R is a group formed by bonding at least one kind of a residue selected from among residues of formulas III, IV and V with an S residue within the scope in which the number of carbon atoms, alpha, is 3-10, the number of sulfur atoms, beta, is 2-9, and alpha
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公开(公告)号:JPH02229808A
公开(公告)日:1990-09-12
申请号:JP938989
申请日:1989-01-17
Applicant: TORAY INDUSTRIES
Inventor: IGUCHI YUICHIRO , SAKAMOTO SADAYUKI , OKA KOICHIRO
IPC: G02B1/04 , C07C321/10 , C07C321/28 , C07C327/10 , C08F20/10 , C08F20/38 , C08F28/00 , C08F28/02
Abstract: PURPOSE:To obtain the subject monomer giving an optical resin useful as optical material having high refractive index and heat resistance by reacting specific compound having benzene ring and SH group and halogenated allyl, etc. CONSTITUTION:A compound expressed by formula I (X is methyl or ethyl, etc.; R3 and R4 are CH2 or CH2S, etc.; n is integer; p and q are 0-2; r is 1-4; with a proviso n+r
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公开(公告)号:JPS6246573B2
公开(公告)日:1987-10-02
申请号:JP8036785
申请日:1985-04-17
Applicant: TORAY INDUSTRIES
Inventor: FUKUDA TADANORI , SAKAMOTO SADAYUKI , NISHINO MASAKI , YASUHARA YUTAKA
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