公开(公告)号：JP2000169404A

公开(公告)日：2000-06-20

申请号：JP35254198

申请日：1998-12-11

Applicant: TOSOH CORP

Inventor： YOTSUYA TADAHIRO ,  SEKI KOJI ,  AWANO YUTAKA ,  KUBO MASAJI

IPC: B01J27/128 ,  C07B61/00 ,  C07C17/04 ,  C07C19/14

Abstract: PROBLEM TO BE SOLVED: To provide a method by which the bromination of a fluorine-containing olefin is performed without using light while suppressing byproduct. SOLUTION: Fluorine-containing olefins of the formula [R1 is F, CF3, CHF2, CH2F, CF2R5 or CHFR5; R2, R3 and R4 are each the same or different F, H or R6; R5 and R6 are each the same or different lower alkyl group (having a substituent)], [e.g. 3,3,3-trifluoropropene] is brominated to produce a fluorine- containing brominated hydrocarbons. A metal powder such as antimony or a Lewis acid is allowed to coexist with the reaction system.

公开(公告)号：JPH0611759B2

公开(公告)日：1994-02-16

申请号：JP30141286

申请日：1986-12-19

Applicant: TOSOH CORP

Inventor： TENMA HIROAKI ,  AWANO YUTAKA ,  TSUZUKI KENJI

IPC: C07D213/61

公开(公告)号：JPH0532629A

公开(公告)日：1993-02-09

申请号：JP21047291

申请日：1991-07-29

Applicant: TOSOH CORP

Inventor： AWANO YUTAKA ,  TENMA HIROAKI ,  TSUZUKI KENJI

IPC: C07D213/75

Abstract: PURPOSE:To produce O-(5,6,7,8-tetrahydro-2-naphthyl)-N-(6-methoxy-2-pyridyl)-N- methylthiocarbamate useful as a medicine in a high purity. CONSTITUTION:Crude O-(5,6,7,8-tetrahydro-2-naphthyl)-N-(6-methoxy-2-pyridyl)-N- methylthiocarbamate having a water content of 20-70% is prepared, treated with active carbon and subsequently recrystallized from an alcohol to produce thiocarbamate having a high purity of >=99.0%.

公开(公告)号：JPH02279687A

公开(公告)日：1990-11-15

申请号：JP9882489

申请日：1989-04-20

Applicant: TOSOH CORP

Inventor： AWANO YUTAKA ,  WATANABE HIROYUKI ,  TSUZUKI KENJI

IPC: A01N55/00 ,  C07F7/10

Abstract: NEW MATERIAL:A compound expressed by formula I (W represents methyne or N; A represents H, halogen, lower alkyl or lower alkoxy; X represents O or S; R1 and R2 represent H or trimethylsilyl, and R2 represents trimethylsilyl when R1 represents H, and R2 represents H when R1 represents trimethylsilyl). EXAMPLE:0-3-Trimethylsilylphenyl N-methyl-N-(6-methoxy-2-methylaminopyridine) thiocarbamate. USE:A herbicide. PREPARATION:A phenol derivative expressed by formula II (Y represents H or halocarbonyl) is reacted with an aromatic amine derivative expressed by formula III (Z represents halocarbonyl when group Y in formula II represents H, and represents H when Y represents halocarbonyl).

公开(公告)号：JPS63179861A

公开(公告)日：1988-07-23

申请号：JP899087

申请日：1987-01-20

Applicant: TOSOH CORP

Inventor： TENMA HIROAKI ,  AWANO YUTAKA ,  TSUZUKI KENJI

IPC: C07D213/61

Abstract: PURPOSE:To obtain the titled compound in high selectivity and yield, using chlorine in high efficiency, by reacting pyridine with chlorine in a water- containing halogenated hydrocarbon solvent under irradiation with ultraviolet ray, wherein the chlorination is carried out by blasting chlorine in two steps at specific rates. CONSTITUTION:Pyridine is made to react with chlorine in a water-containing halogenated hydrocarbon solvent (e.g. chloroform, carbon tetrachloride, etc.) under irradiation with ultraviolet ray to obtain 2,6-dichloropyridine. In the above process, chlorine is blown into the system at a rate of 1.5-4.0mol./hr per 1mol. of pyridine, the produced pyridine hydrochloride is removed from the system and again chlorine is blown into the system at a rate of 0.3-0.5mol./ hr, thereby carrying out the chlorination in two steps. 2,6-Dichloropyridine is useful as an intermediate for pharmaceuticals and agricultural chemicals.

公开(公告)号：JP2014043501A

公开(公告)日：2014-03-13

申请号：JP2012185851

申请日：2012-08-24

Applicant: Tosoh Corp ,  東ソー株式会社

Inventor： AWANO YUTAKA

IPC: C08G61/12

Abstract: PROBLEM TO BE SOLVED: To provide a novel conductive polymer usable as an overcurrent protection element.SOLUTION: A copolymer comprises a repeating unit derived from 3,4-bis(carbamoyloxy)thiophenes represented by the specified general formula (1) or general formula (2), and a repeating unit derived from a thiophene monomer. [In the specified formula (1), Rand Reach independently represent a C1-C12 alkyl group.] [In the specified formula (2), Rto Rrepresent a hydrogen atom or a C1-C3 hydrocarbon group.]

Abstract translation: 要解决的问题：提供可用作过电流保护元件的新型导电聚合物。解决方案：共聚物包含衍生自由特定通式（1）或通式（1）表示的3,4-双（氨基甲酰氧基）噻吩的重复单元 2）和衍生自噻吩单体的重复单元。 [在规定的式（1）中，Rand Reach独立地表示C1-C12烷基。] [在规定式（2）中，R-R表示氢原子或C1-C3烃基。

公开(公告)号：JP2012255049A

公开(公告)日：2012-12-27

申请号：JP2011127527

申请日：2011-06-07

Applicant: Tosoh Corp ,  東ソー株式会社

Inventor： HARA YASUSHI ,  AWANO YUTAKA

IPC: C08G61/12

Abstract: PROBLEM TO BE SOLVED: To provide a copolymer to be used as an overcurrent protective element.SOLUTION: This copolymer comprises 0.01-20 mol% unit represented by general formula (1) and 99.99-80 mol% unit represented by general formula (2), wherein Rand Reach independently represents a hydrogen atom or a 1-8C alkoxy group or malonate group.

Abstract translation: 要解决的问题：提供用作过电流保护元件的共聚物。 解决方案：该共聚物包含0.01-20摩尔％的由通式（1）表示的单元和99.99-80摩尔％的由通式（2）表示的单元，其中R 1 且R 2 各自独立地表示氢原子或1-8C烷氧基或丙二酸酯基团。 版权所有（C）2013，JPO＆INPIT

公开(公告)号：JP2012224721A

公开(公告)日：2012-11-15

申请号：JP2011092405

申请日：2011-04-18

Applicant: Tosoh Corp ,  東ソー株式会社

Inventor： HARA YASUSHI ,  ODA YASUHIRO ,  AWANO YUTAKA

IPC: C08L65/00 ,  C08F12/30 ,  C08G61/12 ,  C08L25/00 ,  C08L63/00 ,  C09D5/02 ,  C09D5/24 ,  C09D7/12 ,  C09D125/08 ,  C09D141/00 ,  C09D151/06

Abstract: PROBLEM TO BE SOLVED: To provide a composite of a polystyrenesulfonic acid or its salt and a polythiophene derivative, capable of forming a highly conductive film at low cost; and to provide a coating composition including a water-dispersion of the composite.SOLUTION: The composite comprises: a polystyrenesulfonic acid or its salt obtained by polymerizing styrenesulfonic acid or its salt; and a polythiophene derivative obtained by polymerizing a thiophene derivative in the presence of the polystyrenesulfonic acid or its salt. Here, the composite is preferably the one made by polymerization of the polystyrenesulfonic acid or its salt in the presence of aminosulfonic acid, or the one obtained by mixing aminosulfonic acid after polymerization of the polystyrenesulfonic acid or its salt.

Abstract translation: 要解决的问题：提供能够以低成本形成高导电膜的聚苯乙烯磺酸或其盐和聚噻吩衍生物的复合物; 并提供包含复合物的水分散体的涂料组合物。 解决方案：该复合材料包括：通过聚合苯乙烯磺酸或其盐得到的聚苯乙烯磺酸或其盐; 和通过在聚苯乙烯磺酸或其盐的存在下聚合噻吩衍生物而获得的聚噻吩衍生物。 这里，该复合材料优选是在氨基磺酸存在下聚聚苯乙烯磺酸或其盐而得的复合物，或聚苯乙烯磺酸或其盐聚合后通过混合氨基磺酸得到的复合物。 版权所有（C）2013，JPO＆INPIT

公开(公告)号：JP2010254535A

公开(公告)日：2010-11-11

申请号：JP2009109541

申请日：2009-04-28

Applicant: Tosoh Corp ,  東ソー株式会社

Inventor： AWANO YUTAKA ,  KAWAHATA KOUJI ,  HARA YASUSHI

IPC: C01B39/48 ,  C07C211/62

Abstract: PROBLEM TO BE SOLVED: To provide a structure-directing agent for zeolite production composed of an N, N, N-trimethyladamantane ammonium salt in which zeolite is obtained with good economical efficiency, and to provide a method for producing zeolite using the same.
SOLUTION: When zeolite is produced by hydrothermal synthesis of a synthetic raw material mixture containing a silica source, an aluminum source, an alkali source, water, and a structure-directing agent, a compound represented by formula (1) is used as a structure-directing agent.
COPYRIGHT: (C)2011,JPO&INPIT

Abstract translation: 待解决的问题：提供一种沸石生产的结构导向剂，其由经济效率高的沸石获得的N，N，N-三甲基金刚烷铵盐组成，提供一种使用 相同。 解决方案：当通过水热合成含有二氧化硅源，铝源，碱源，水和结构导向剂的合成原料混合物制备沸石时，使用由式（1）表示的化合物 作为结构导向剂。 版权所有（C）2011，JPO＆INPIT

公开(公告)号：JP2010138087A

公开(公告)日：2010-06-24

申请号：JP2008314476

申请日：2008-12-10

Applicant: Tosoh Corp ,  東ソー株式会社

Inventor： AWANO YUTAKA ,  KAWAHATA KOUJI ,  HARA YASUSHI

IPC: C07C209/20 ,  C07C211/62

Abstract: PROBLEM TO BE SOLVED: To provide a method capable of simply and easily producing an N,N,N-trialkyladamantane ammonium salt useful as a mold compound in industrially producing zeolite. SOLUTION: This method for producing the N,N,N-trialkyladamantane ammonium salt is provided by reacting an N,N-dialkyl-1-aminoadamantane expressed by general formula (1) with a dialkyl carbonate compound under the condition of presence or absence of solvent by making COPYRIGHT: (C)2010,JPO&INPIT

Abstract translation: 待解决的问题：提供一种能够简单且容易地制造用作工业生产沸石中的模制化合物的N，N，N-三烷基金刚烷铵盐的方法。 解决方案：用于制备N，N，N-三烷基金刚烷铵盐的方法是通过使通式（1）表示的N，N-二烷基-1-氨基金刚烷与碳酸二烷基酯化合物在存在的条件下反应而提供的 或不存在溶剂，根据N，N-二烷基氨基金刚烷的量，在反应时间内使系统中的含水量<10重量％。 版权所有（C）2010，JPO＆INPIT