公开(公告)号：JP2014201545A

公开(公告)日：2014-10-27

申请号：JP2013078338

申请日：2013-04-04

Applicant: 東ソー株式会社 ,  Tosoh Corp

Inventor： AWANO YUTAKA ,  NISHIYAMA SHOICHI ,  YANO YUICHI

IPC: C07D495/04

Abstract: 【課題】2−ヒドロキシメチル−2,3−ジヒドロ−チエノ[3,4−b][1,4]ジオキシン−5,7−ジカルボン酸ジアルキルエステルを選択的に収率良く製造する方法の提供。【解決手段】3,4−ジヒドロキシチオフェン−2,5−ジカルボン酸エステルと、ジハロゲン化プロパノールとを、ヨウ化物と塩基の存在下で反応させて次式(3)[式中、Rは各々独立して、炭素数1〜4のアルキル基を表す]で示される2−ヒドロキシメチル−2,3−ジヒドロ−チエノ[3,4−b][1,4]ジオキシン−5,7−ジカルボン酸ジアルキルエステルを得る。【選択図】なし

Abstract translation: 要解决的问题：提供以选择性和产率良好的2-羟甲基-2,3-二氢 - 噻吩并[3,4-b] [1,4]二恶英-5,7-二羧酸二烷基酯的制备方法。 解决方案：在碘化物和碱的存在下，使3,4-二羟基噻吩-2,5-二羧酸酯和二卤代丙醇反应，得到2-羟甲基-2,3-二氢 - 噻吩并[3,4-b] 1,4]二恶英-5,7-二羧酸二烷基酯，R表示各自独立地为具有1〜4个碳原子的烷基。

公开(公告)号：JP2014074007A

公开(公告)日：2014-04-24

申请号：JP2013078336

申请日：2013-04-04

Applicant: Tosoh Corp ,  東ソー株式会社

Inventor： YANO YUICHI ,  NISHIYAMA SHOICHI ,  AWANO YUTAKA

IPC: C07D495/04 ,  C08G61/12

Abstract: PROBLEM TO BE SOLVED: To provide novel water-soluble thiophene compounds and polythiophenes used for conductive materials.SOLUTION: There are provided thiophene compounds represented by the formula (1) and its polymers. (1), where Rrepresents a hydrogen atom, or an alkyl group having 1 to 6 carbon atoms which may have a substituent, an aryl group having 6 to 20 carbon atoms, or -X-SOM, X represents an alkylene group having 1 to 6 carbon atoms may have a substituent, or an arylene group having 6 to 20 carbon atoms, m represents an integer of 0 to 3, n represents an integer of 0 to 12, and n+m≥1.

Abstract translation: 要解决的问题：提供用于导电材料的新型水溶性噻吩化合物和聚噻吩。解决方案：提供由式（1）表示的噻吩化合物及其聚合物。 （1）中，R表示氢原子或可具有取代基的碳原子数1〜6的烷基，碳原子数6〜20的芳基或-X-SOM，X表示具有1〜 6个碳原子可以具有取代基，或具有6〜20个碳原子的亚芳基，m表示0〜3的整数，n表示0〜12的整数，n +m≥1。

公开(公告)号：JP2013249308A

公开(公告)日：2013-12-12

申请号：JP2013167798

申请日：2013-08-12

Applicant: Tosoh Corp ,  東ソー株式会社

Inventor： HARA YASUSHI ,  AWANO YUTAKA ,  KAWAHATA KOUJI

IPC: C07C209/60 ,  C07C211/62

Abstract: PROBLEM TO BE SOLVED: To provide a simple method for easily obtaining in high yield an N,N,N-trimethyladamantaneammonium salt.SOLUTION: A method comprises: reacting a 1-halogenated adamantane and dimethylamine with each other in the presence of iodine as catalyst to obtain N,N-dimethyl-1-aminoadamantane followed by reacting the N,N-dimethyl-1-aminoadamantane and dimethyl carbonate with each other.

Abstract translation: 要解决的问题：提供一种容易地高产率地获得N，N，N-三甲基金刚烷铵盐的简单方法。方法：一种方法包括：在碘作为催化剂存在下使1-卤代金刚烷和二甲胺彼此反应 得到N，N-二甲基-1-氨基金刚烷，然后使N，N-二甲基-1-氨基金刚烷和碳酸二甲酯彼此反应。

公开(公告)号：JP2013108006A

公开(公告)日：2013-06-06

申请号：JP2011254870

申请日：2011-11-22

Applicant: Tosoh Corp ,  東ソー株式会社

Inventor： HARA YASUSHI ,  AWANO YUTAKA ,  ODA YASUHIRO

IPC: C08L65/00 ,  C08G61/12 ,  C08K5/20

Abstract: PROBLEM TO BE SOLVED: To provide an amide-based dispersant that can disperse PEDOT-PSS that is an excellent electrically conductive material, and to provide a method that disperses a poly(3,4- ethylenedioxythiophene) powder that contains polystyrenesulfonic acid as a poly anion by using the dispersant.SOLUTION: If a dispersant including N-methylformamide, especially a dispersant in which the content of N-methylformamide is 50-100 wt.% based on the entire dispersant is used, a poly(3,4-ethylenedioxythiophene) powder including polystyrenesulfonic acid can be dispersed again.

Abstract translation: 要解决的问题：提供可以分散作为优异的导电材料的PEDOT-PSS的酰胺类分散剂，并且提供分散含有聚苯乙烯磺酸的聚（3,4-亚乙基二氧噻吩）粉末的方法 通过使用分散剂作为聚阴离子。 解决方案：如果使用包含N-甲基甲酰胺的分散剂，特别是其中N-甲基甲酰胺的含量基于整个分散剂为50-100重量％的分散剂，则可以使用聚（3,4-亚乙基二氧噻吩）粉末，其包括 聚苯乙烯磺酸可再次分散。 版权所有（C）2013，JPO＆INPIT

公开(公告)号：JP2010047492A

公开(公告)日：2010-03-04

申请号：JP2008211008

申请日：2008-08-19

Applicant: Tosoh Corp ,  東ソー株式会社

Inventor： KAWAHATA KOUJI ,  AWANO YUTAKA ,  HARA YASUSHI

IPC: C07C29/62 ,  C07B61/00 ,  C07C31/36

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing dichloropropanol by which water-containing glycerol can efficiently be chlorinated by the reaction with hydrogen chloride gas in the presence of a chlorination catalyst having high activity without using a special reaction apparatus in the production of the dichloropropanol. SOLUTION: The method for producing dichloropropanol includes chlorinating the hydroxy groups of the glycerol and/or a glycerol derivative in the presence of the hydrogen chloride gas by using a metal chloride and/or a mixed catalyst of a metal oxide and a ≥9C aliphatic carboxylic acid and/or a derivative of the aliphatic carboxylic acid. COPYRIGHT: (C)2010,JPO&INPIT

Abstract translation: 待解决的问题：提供一种制备二氯丙醇的方法，其中含水甘油可以通过与活性高的氯化催化剂的反应与氯化氢气体反应而有效地氯化，而不需要使用特殊的反应装置 生产二氯丙醇。 解决方案：制备二氯丙醇的方法包括在氯化氢气体存在下，通过使用金属氯化物和/或金属氧化物的混合催化剂和≥0.5的氯化氢来氯化甘油和/或甘油衍生物的羟基 9C脂族羧酸和/或脂族羧酸的衍生物。 版权所有（C）2010，JPO＆INPIT

公开(公告)号：JPH11130708A

公开(公告)日：1999-05-18

申请号：JP29829597

申请日：1997-10-30

Applicant: TOSOH CORP

Inventor： AWANO YUTAKA ,  SHIMODA ATSUSHI ,  KUBO MASAJI

IPC: B01J31/02 ,  C07B39/00 ,  C07B61/00 ,  C07C17/14 ,  C07C22/08 ,  C07C25/02 ,  C07C63/70 ,  C07C201/12 ,  C07C205/11 ,  C07C255/50

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing a monobromomethylated aromatic compound, capable of solving a problem that the selectivity of the monobromomethylated product is low by conventional methods, and capable of efficiently obtaining the monobromomethylated aromatic compound by an industrially simple method without using a special device such as a photoreactor or the like. SOLUTION: This method for producing a monobromomethylated aromatic compound comprises brominating a methyl group bound to the aromatic ring of a substituted aromatic compound of the formula (R is at least one electron- attracting substituent selected from nitro group, a halogen atom, trifluoromethyl group, cyano group, carboxyl group, an alkoxycarbony group and phenoxy group). Therein, the reaction is carried out in the presence of water and one or more kinds of radical initiators selected from the group consisting of dialkyl peoxides, diacyl peroxide and azo compounds.

公开(公告)号：JPH04128263A

公开(公告)日：1992-04-28

申请号：JP24635390

申请日：1990-09-18

Applicant: TOSOH CORP

Inventor： TENMA HIROAKI ,  AWANO YUTAKA ,  TSUZUKI KENJI

IPC: C07C329/02

Abstract: PURPOSE:To obtain the subject highly purified compound useful as an intermediate of an agricultural chemical or a modicine in high yield by washing the subject crude compound with an aqueous solution of dehalogenating hydrogen reagent and distilling under reduced pressure in a nitrogen atmosphere in the presence of an antioxidant. CONSTITUTION:5,6,7,8-tetrahydronaphthol is reacted with carbon dithiochloride in the presence of a dehalogenating hydrogen reagent (e.g. alkali metal hydroxide) and resultant crude 0-2-(5,6,7,8-tetrahydronaphthoxy)-chlorothioformate is washed with an aqueous solution of dehalogenating hydrogen reagent having 1-10 N, preferably 2-5N concentration, and added to said compound in an amount of 0.1-20wt.%, preferably 5-10wt.% mixture is distilled under

公开(公告)号：JP2019001858A

公开(公告)日：2019-01-10

申请号：JP2017115865

申请日：2017-06-13

Applicant: TOSOH CORP

Inventor： TAKEMOTO ARIMITSU ,  AWANO YUTAKA

IPC: C10M133/40 ,  C10M125/10 ,  C10M137/10 ,  C10M159/12 ,  C10M159/18 ,  C10M169/04

Abstract: 【課題】硫黄及びリンを含まず、かつ摩擦低減性に優れる摩擦低減剤、及びそれを用いた潤滑油組成物を提供する。【解決手段】下記式(1)で示されるアミン化合物とモリブデン化合物とを含み、当該アミン化合物1モルに対してモリブデン化合物を、モリブデン化合物中のモリブデン原子として、0.1〜3モルの範囲で含むことを特徴とする摩擦低減剤。【化1】[上記式(1)中、R1は炭素数aの炭化水素基を表し、R6は炭素数bの炭化水素基を表す(ここで、a、bは各々独立して1〜30の整数を表し、かつa+b≧8を満たす)。R2〜R5は各々独立して、水素原子又は炭素数30以下の炭化水素基を表す。]【選択図】なし

公开(公告)号：JP2012211297A

公开(公告)日：2012-11-01

申请号：JP2011164831

申请日：2011-07-27

Applicant: Tosoh Corp ,  東ソー株式会社

Inventor： HARA YASUSHI ,  AWANO YUTAKA ,  YANO YUICHI

IPC: C08G73/02

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing a new sulfonated triarylamine polymer easily dissolvable in water and alcohol through a few steps by using inexpensive raw materials stably industrially available.SOLUTION: A sulfonating agent is reacted with a triarylamine polymer expressed by formula (7) in a basic polar solvent, where in formula, Arrepresents a 6-20C aromatic group which may have a substitutent; m is an integer of 1 or more; Arrepresents a benzene ring optionally including a substituent selected from a halogen atom, alkyl, alkoxy, alkenyl, aryl, arylamine or heteroaryl group.

Abstract translation: 要解决的问题：提供一种通过使用稳定工业上可利用的廉价原料，通过几步来制备容易溶于水和醇的新的磺化三芳基胺聚合物的方法。 解决方案：将磺化剂与由式（7）表示的三芳基胺聚合物在碱性极性溶剂中反应，其中在式中，Ar 1 表示6-20C芳族 可能有替代的组; m为1以上的整数， Ar 5表示任选地包括选自卤素原子，烷基，烷氧基，烯基，芳基，芳基胺或杂芳基的取代基的苯环。 版权所有（C）2013，JPO＆INPIT

公开(公告)号：JP2011213688A

公开(公告)日：2011-10-27

申请号：JP2010085149

申请日：2010-04-01

Applicant: Tosoh Corp ,  東ソー株式会社

Inventor： AWANO YUTAKA ,  KAWAHATA KOUJI

IPC: C07C215/14 ,  C07B61/00 ,  C07C213/02 ,  C07D241/04 ,  C07D295/08 ,  C07D487/08

Abstract: PROBLEM TO BE SOLVED: To provide a method for synthesizing hydroxy(alkyl)triethylenediamines and a mixture of N-((dihydroxyalkyl)2-aminoethyl)ethanolamines as a raw material.SOLUTION: The method includes dehydrative intramolecular condensation reaction of a compound of formula (1) and a compound of formula (2). In the formulas, R represents a hydrogen atom or a 1-4C alkyl group; and n is 0 to 6.

Abstract translation: 要解决的问题：提供一种合成羟基（烷基）三亚乙基二胺的方法和作为原料的N - （（二羟基烷基）2-氨基乙基）乙醇胺的混合物。方法：该方法包括下式化合物的脱水分子内缩合反应 （1）和式（2）的化合物。 在该式中，R表示氢原子或1-4C烷基; n为0〜6。