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公开(公告)号:CA2928874A1
公开(公告)日:2015-06-25
申请号:CA2928874
申请日:2014-12-12
Applicant: VALSPAR SOURCING INC
Inventor: HAYES GREGORY B , MELNYK THOMAS J , TAYLOR MELODY , LIEU D MICHELLE , LI SHU PEI
IPC: C08G63/695 , C07B41/02 , C07B41/04 , C07F7/18 , C08G63/40 , C08G63/668 , C08G77/14 , C08L67/02 , C09D167/02 , C09D183/06
Abstract: The present invention provides a coating composition having excellent weatherability and durability. The coating composition includes a binder system comprising a durable polyester resin and a siliconized polyester resin having up to about 45 wt% silicone content. Coated articles with the coating composition applied to at least a portion of a surface thereof are also provided.
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公开(公告)号:CA2715055A1
公开(公告)日:2009-08-20
申请号:CA2715055
申请日:2008-02-06
Applicant: VALSPAR SOURCING INC
Inventor: BRANDENBURGER LARRY B , MELNYK THOMAS J
IPC: C08G63/78
Abstract: Medium and high molecular weight polyester polymers are prepared in syrup form from an ester oligomer. The oligomer is converted to the polymer by polycondensation at atmospheric pressure and elevated temperature in a nonreactive carrier capable of forming an azeotrope with water. The ester oligomerization or polycondensation reactions desirably are monitored using a non-viscometric technique. The process has a rapid cycle time. The syrup contains the polymer and nonreactive carrier, and may more conveniently be used to make initially non-solid products such as polyester coatings than is the case when employing pelletized solid polyester resins.
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公开(公告)号:AU2009212386A1
公开(公告)日:2009-08-13
申请号:AU2009212386
申请日:2009-02-05
Applicant: VALSPAR SOURCING INC
Inventor: MELNYK THOMAS J , BRANDENBURGER LARRY B
IPC: A61L15/62 , C08F283/10 , C08G63/02
Abstract: Medium and high molecular weight polyester polymers are prepared in syrup form from an ester oligomer. The oligomer is converted to the polymer by polycondensation at elevated pressure and elevated temperature in a nonreactive carrier capable of forming an azeotrope with water. The ester oligomerization or polycondensation reactions desirably are monitored using a non-viscometric technique. The process has a rapid cycle time. The syrup contains the polymer and nonreactive carrier, and may more conveniently be used to make initially non-solid products such as polyester coatings than is the case when employing pelletized solid polyester resins.
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公开(公告)号:BRPI0810553A2
公开(公告)日:2014-10-21
申请号:BRPI0810553
申请日:2008-04-22
Applicant: VALSPAR SOURCING INC
Inventor: HAYES GREGORY B , MELNYK THOMAS J
Abstract: A primer/topcoat coil coating system employs crosslinkable branched hydroxyl-functional polyester-imide resins derived or derivable from a symmetric aromatic imide triol and a diacid or acid-producing derivative. The primer resin has a hydroxyl number greater than about 90 but not more than about 215, the topcoat resin has a hydroxyl number greater than about 100 but not more than about 215, and the primer and topcoat can each be hardened in 30 seconds or less to provide a coating having at least 0T flexibility with no tape off and at least 2H pencil hardness.
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公开(公告)号:MX2010008605A
公开(公告)日:2010-08-31
申请号:MX2010008605
申请日:2008-02-06
Applicant: VALSPAR SOURCING INC
Inventor: BRANDENBURGER LARRY B , MELNYK THOMAS J
IPC: C08G63/16
Abstract: Se preparan polímeros de poliéster de peso molecular medio y alto en forma de jarabe a partir de un oligómero de éster. El oligómero es convertido al polímero mediante policondensación a presión atmosférica y temperatura elevada en un portador no reactivo capaz de formar un azeótropo con agua. Las reacciones de oligomerización de éster o policondensación son monitoreadas deseablemente usando una técnica no viscométrica. El proceso tiene un tiempo de ciclo rápido. El jarabe contiene el polímero y portador no reactivo, y puede usarse más convenientemente para hacer productos no sólidos inicialmente, tales como recubrimientos de poliéster que es el caso cuando se emplean resinas de poliéster sólidas pelletizadas.
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公开(公告)号:CA2715262A1
公开(公告)日:2009-08-13
申请号:CA2715262
申请日:2009-02-05
Applicant: VALSPAR SOURCING INC
Inventor: BRANDENBURGER LARRY B , MELNYK THOMAS J
IPC: A61L15/62 , C08F283/10 , C08G63/02
Abstract: Medium and high molecular weight polyester polymers are prepared in syrup form from an ester oligomer. The oligomer is converted to the polymer by polycondensation at elevated pressure and elevated temperature in a nonreactive carrier capable of forming an azeotrope with water. The ester oligomerization or polycondensation reactions desirably are monitored using a non-viscometric technique. The process has a rapid cycle time. The syrup contains the polymer and nonreactive carrier, and may more conveniently be used to make initially non-solid products such as polyester coatings than is the case when employing pelletized solid polyester resins.
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公开(公告)号:CA2993164A1
公开(公告)日:2017-01-26
申请号:CA2993164
申请日:2016-07-14
Applicant: VALSPAR SOURCING INC
Inventor: MELNYK THOMAS J
IPC: C09D167/02 , C08L67/02
Abstract: A novel linear polyester resin is made by condensation of one or more aliphatic or cycloaliphatic polyols with one or more aliphatic or cycloaliphatic polyfunctional acids derived from biobased materials or a biological feedstock. Coating compositions and coated substrates using the novel linear polyester resin are also described.
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公开(公告)号:CA2928214A1
公开(公告)日:2015-06-25
申请号:CA2928214
申请日:2014-12-09
Applicant: VALSPAR SOURCING INC
Inventor: HAYES GREGORY B , MELNYK THOMAS J
IPC: C08G63/695 , C08L67/02 , C09D143/04 , C09D167/02
Abstract: A silicone-modified polyester resin and methods for making the resin are described herein. The method includes production of a siliconized intermediate which is then esterified to give a silicone-modified polyester resin. Coating compositions including the silicone- modified polyester resin are provided, and coated articles with the coating composition applied to at least a portion of a surface thereof are also provided.
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公开(公告)号:MX2010008607A
公开(公告)日:2010-09-07
申请号:MX2010008607
申请日:2009-02-05
Applicant: VALSPAR SOURCING INC
Inventor: BRANDENBURGER LARRY B , MELNYK THOMAS J
IPC: A61L15/62 , C08F283/10 , C08G63/02
Abstract: Se describen polímeros de poliéster de peso molecular promedio y alto preparados en forma de suspensión de un oligómero de éster. El oligómero se convierte a polímero por policondensación a presión elevada y temperatura elevada en un portador no reactivo capaz de formar un azeótropo con agua. Las reacciones de oligomerización o policondensación de éster deseablemente se supervisan usando una técnica no viscosimétrica. El proceso tiene un tiempo de ciclo rápido. La suspensión contiene el polímero y el portador no reactivo, y puede utilizarse más convenientemente para hacer inicialmente productos no sólidos tal como recubrimientos de poliéster que es el caso cuando se usa en resinas de poliéster sólidas granuladas.
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公开(公告)号:CA2683900A1
公开(公告)日:2008-11-06
申请号:CA2683900
申请日:2008-04-22
Applicant: VALSPAR SOURCING INC
Inventor: HAYES GREGORY B , MELNYK THOMAS J
Abstract: A primer/topcoat coil coating system employs crosslinkable branched hydro xyl-functional polyester-imide resins derived or derivable from a symmetric aromatic imide triol and a diacid or acid-producing derivative. The primer r esin has a hydroxyl number greater than about 90 but not more than about 215 , the topcoat resin has a hydroxyl number greater than about 100 but not mor e than about 215, and the primer and topcoat can each be hardened in 30 seco nds or less to provide a coating having at least OT flexibility with no tape off and at least 2H pencil hardness.
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