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    METHOD FOR PRODUCING AROMATIC COMPOUND
    191.
    发明专利
    METHOD FOR PRODUCING AROMATIC COMPOUND 审中-公开

    公开(公告)号：JP2003261468A

    公开(公告)日：2003-09-16

    申请号：JP2002063034

    申请日：2002-03-08

    Applicant: DAICEL CHEM

    Inventor： ISHII YASUTAKA ,  NAKANO TATSUYA

    IPC: C07C2/84 ,  C07B61/00 ,  C07C15/14 ,  C07C41/30 ,  C07C43/205 ,  C07C67/333 ,  C07C69/76

    Abstract: PROBLEM TO BE SOLVED: To provide a method for producing an aromatic compound, capable of conducting an oxidative coupling reaction of starting aromatic compounds so as to effectively produce the aromatic compound having condensed rings corresponding to the starting aromatic compounds. SOLUTION: This method for producing the aromatic compound comprises contacting the starting aromatic compounds with molecular oxygen in the presence of catalysts, and making the starting compounds directly bond to each other through single bonds, so as to form the aromatic compound having the condensed rings corresponding to the starting aromatic compounds, wherein the catalyst is composed of (A) a palladium compound catalyst and (B) a catalyst comprising (B1) a heteropoly-acid or its salt or (B2) a mixture of oxoacids containing an element of P or Si, and at least one element selected from V, Mo, and W as a whole, or their salts. COPYRIGHT: (C)2003,JPO

    METHOD FOR PRODUCING KETONE COMPOUND
    194.
    发明专利
    METHOD FOR PRODUCING KETONE COMPOUND 失效

    公开(公告)号：JP2002173457A

    公开(公告)日：2002-06-21

    申请号：JP2000370207

    申请日：2000-12-05

    Applicant: DAICEL CHEM

    Inventor： ISHII YASUTAKA ,  NAKANO TATSUYA ,  SATO YASUSHI

    IPC: C07C45/30 ,  C07B61/00 ,  C07C41/56 ,  C07C43/315 ,  C07C49/17

    Abstract: PROBLEM TO BE SOLVED: To provide a ketone from the corresponding secondary alcohol at a high conversion and a high selectivity. SOLUTION: This ketone compound is obtained by oxidizing the corresponding secondary alcohol having at least secondary hydroxy group in the presence of a reducing inorganic compound or acid, with bromic acid or its salt, at >=40 deg.C to convert the secondary hydroxy group to oxo group. The ratio of the bromic acid or its salt is less than 1 chemical equivalent based on the secondary hydroxy group and the ratio of the reducing inorganic compound or acid is 0.01-0.9 chemical equivalent based on the bromic acid. When a polyhydric alcohol having a secondary hydroxy group and a primary hydroxy group (propylene glycol, glycerol or the like) is used as the alcohol, the corresponding hydroxyketone compound is produced. A sulfite, a hydrogensulfite, a pyrosulfite, a thiosulfate or the like can be used as the reducing inorganic compound.

    METHOD OF PRODUCING CYCLOALCANONE OXINE
    195.
    发明专利
    METHOD OF PRODUCING CYCLOALCANONE OXINE 失效

    公开(公告)号：JP2001335548A

    公开(公告)日：2001-12-04

    申请号：JP2000157356

    申请日：2000-05-26

    Applicant: DAICEL CHEM

    Inventor： ISHII YASUTAKA ,  NAKANO TATSUYA ,  TATSUMI JUNRO

    IPC: B01J31/02 ,  C07B61/00 ,  C07C249/06 ,  C07C251/44

    Abstract: PROBLEM TO BE SOLVED: To provide a method of simply and easily producing a cycloalkanone oxime from inexpensive raw materials. SOLUTION: In the presence of an imide catalyst represented by the following formula (1) (wherein R1 and R2 are identical or different from each other and is H, a halogen atom, an alkyl, an aryl, a cycloalkyl, hydroxyl, an alkoxy, carboxyl, an alkoxycarbonyl and an acyl where R1 and R2 may combine with each other for form a double bone or an aromatic or nonaromatic ring and further the R1 and the R2 or the double bond, aromatic or non-aromatic ring formed by binding with each other may bear an N-substituted ring imide shown in the formula one or more additionally), a cycloalkane is reacted with nitrogen monoxide whereby the cycloalkanone oxime is obtained.

    METHOD FOR PRODUCING NITRO COMPOUND
    196.
    发明专利
    METHOD FOR PRODUCING NITRO COMPOUND 失效

    公开(公告)号：JP2001247486A

    公开(公告)日：2001-09-11

    申请号：JP2000058054

    申请日：2000-03-02

    Applicant: DAICEL CHEM

    Inventor： ISHII YASUTAKA ,  NAKANO TATSUYA

    IPC: B01J31/02 ,  C07B43/02 ,  C07B61/00 ,  C07C201/08 ,  C07C205/05

    Abstract: PROBLEM TO BE SOLVED: To simply and easily produce a nitro compound under a milder condition. SOLUTION: An organic substrate is reacted with nitric acid, nitrous acid or one of their salts in the presence of an imide compound expressed by formula (1) [wherein R1 and R2 are each the same or different and express H, a halogen, an alkyl, an aryl, a cycloalkyl, OH, an alkoxy, COOH, an alkoxycarbonyl or an acyl and R1 and R2 may form a double bond, an aromatic or nonaromatic ring by mutually bonding; X expresses O or OH. In the double bond, aromatic or nonaromatic ring formed by mutual bonding of the aforesaid R1 and R2, further 1 or 2 imide groups expressed by formula (1) may be formed.] to produce the corresponding nitro compound.

    METHOD FOR PRODUCING beta-ACYLOXYCARBOXYLIC ACID OR beta- ACYLOXYLETONE
    197.
    发明专利
    METHOD FOR PRODUCING beta-ACYLOXYCARBOXYLIC ACID OR beta- ACYLOXYLETONE 失效

    公开(公告)号：JP2001192354A

    公开(公告)日：2001-07-17

    申请号：JP2000000648

    申请日：2000-01-06

    Applicant: DAICEL CHEM

    Inventor： ISHII YASUTAKA ,  NAKANO TATSUYA

    IPC: C07D307/20 ,  B01J31/02 ,  C07B41/12 ,  C07B61/00 ,  C07C67/42 ,  C07C67/44 ,  C07C69/06 ,  C07C69/14

    Abstract: PROBLEM TO BE SOLVED: To provide a method capable of producing a β-acyloxycarboxylic acid or a β-acylcarboxyketone under mild conditions from readily available raw materials. SOLUTION: An alcohol represented by formula (2) is reacted with an α,β-unsaturated carbonyl compound represented by formula (3) in the presence of an imide compound catalyst represented by formula (1) and oxygen to produce the objective β-acyloxycarboxlic acid or β-acyloxyketone compound represented by formula (4). In the above formulas, R1 and R2 are each hydrogen atom or the like or R1 and R2 may be bonded to form a double bond or an aromatic or non-aromatic ring; X is oxygen atom or hydroxyl group; Ra, Rb, Rc and Rd are each hydrogen atom, an organic group or the like; Re and Rf are each hydrogen atom, a hydrocarbon group or the like; Y is a hydroxyl group when Re is hydrogen atom and Y is Re when Re is the hydrocarbon group or the like excluding the above hydrogen atom.

    CATALYST COMPRISING NITROGEN-CONTAINING HETEROCYCLIC COMPOUND AND PRODUCTION OF ORGANIC COMPOUND USING THE SAME
    198.
    发明专利
    CATALYST COMPRISING NITROGEN-CONTAINING HETEROCYCLIC COMPOUND AND PRODUCTION OF ORGANIC COMPOUND USING THE SAME 失效

    公开(公告)号：JP2001070798A

    公开(公告)日：2001-03-21

    申请号：JP24808499

    申请日：1999-09-01

    Applicant: DAICEL CHEM

    Inventor： ISHII YASUTAKA ,  NAKANO TATSUYA

    IPC: B01J31/02 ,  C07B41/00 ,  C07B61/00 ,  C07D249/18 ,  C07D253/04 ,  C07D253/08

    Abstract: PROBLEM TO BE SOLVED: To provide a catalyst capable of introducing oxygen atom-containing groups into an organic substrate under a moderate condition. SOLUTION: This catalyst is a catalyst for reactions using an oxygen atom- containing reactant, and is composed of a nitrogen-containing heterocyclic compound represented by the formula (wherein R1 and R2 are identical or different and represent a hydrogen atom, a halogen atom, an alky group, a haloalkyl group, an aryl group, a cycloalkyl group, a hydroxyl group, an alkoxy group, a carboxyl group, an alkoxycarbonyl group, or an acyl group, R1 and R2 may be bound to each other to form a double bond or an aromatic or nonaromatic ring together with two neighboring carbon atoms, one or two heterocyclic rings containing three nitrogen atoms, shown in the formula, may be additionally formed in R1, R2, or the double bond or the aromatic or nonaromatic ring formed by binding R1 and R2 mutually; X represents an oxygen atom or a hydroxy group; Y represents a single bond, a methylene group, or a carbonyl group).

    PRODUCTION OF AZIRIDINE COMPOUND
    199.
    发明专利
    PRODUCTION OF AZIRIDINE COMPOUND 失效

    公开(公告)号：JP2000256310A

    公开(公告)日：2000-09-19

    申请号：JP6244299

    申请日：1999-03-09

    Applicant: DAICEL CHEM

    Inventor： ISHII YASUTAKA ,  NAKANO TATSUYA

    IPC: B01J23/46 ,  C07B61/00 ,  C07D203/08 ,  C07D203/14

    Abstract: PROBLEM TO BE SOLVED: To efficiently produce the subject compound useful as a precursor of an amino acid, or the like, according to a simple means by reacting an imine with a diazoacetic acid derivative in the presence of an iridium compound. SOLUTION: (A) An imine represented by formula I (R1 to R3 are each H or an unreactive organic group; R1 and R2 may mutually be bonded to form a ring together with the adjacent C) is reacted with (B) a diazoacetic acid derivative represented by the formula N2CHR4 [R4 is cyano, COOR5 or CONR6 R7 (R5 is a hydrocarbon group, or the like; R6 and R7 are each H, a hydrocarbon group, or the like)] in the presence of an iridium compound, e.g. di-μ- chlorotetrakis(cyclooctene)diiridium (I) to produce an aziridine compound represented by formula II, e.g. 1-butyl-2-ethoxycarbonyl-3-propylaziridine. Furthermore, the reactional temperature is within the range of, e.g. -20 to +150 deg.C and the above reaction may be carried out under atmospheric pressure or under a pressurization.

    PRODUCTION OF ALDEHYDE
    200.
    发明专利
    PRODUCTION OF ALDEHYDE 失效

    公开(公告)号：JP2000256247A

    公开(公告)日：2000-09-19

    申请号：JP6244499

    申请日：1999-03-09

    Applicant: DAICEL CHEM

    Inventor： ISHII YASUTAKA ,  NAKANO TATSUYA

    IPC: B01J31/24 ,  B01J21/18 ,  C07B61/00 ,  C07C45/39 ,  C07C47/02 ,  C07C47/055 ,  C07C47/07 ,  C07C47/12 ,  C07C47/54

    Abstract: PROBLEM TO BE SOLVED: To efficiently obtain the corresponding aldehyde by subjecting 1,2-diol to oxidative cleavage with oxygen. SOLUTION: 1,2-Diol (vic-diol) is reacted with oxygen in the presence of a support-carried type ruthenium catalyst. Thereby, two carbon atoms to which a hydroxyl group is bonded are oxidatively cleaved to produce the corresponding aldehyde. The support includes activated carbon. An organic ruthenium complex or the like such as dichlorotris(triphenyl phosphine) ruthenium (II) can be used as the catalyst component carried on the support.

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