公开(公告)号：US09803074B2

公开(公告)日：2017-10-31

申请号：US14645488

申请日：2015-03-12

Applicant: Equistar Chemicals, LP ,  Basell Poliolefine Italia S.r.l.

Inventor： Maged G. Botros ,  Enrico Costantini ,  Charles S. Holland ,  Chun Lee ,  Enrico Masarati

IPC: C08L23/10

CPC classification number: C08L23/10 ,  C08L23/14 ,  C08L23/16 ,  C08L51/06 ,  C08L2203/16 ,  C09J123/14 ,  C08L23/02

Abstract: The present disclosure provides a polyolefin-based composition suitable for use as adhesives and/or tie-layer adhesive compositions as well as a multi-layered structure made from and/or containing the polyolefin-based composition. The polyolefin-based composition is made from and/or contains (a) a grafted polyolefin composition, (b) a first polymer composition, (c) a polypropylene-containing blend composition, and (d) optionally, an additives composition having one or more additives.

公开(公告)号：US09752023B2

公开(公告)日：2017-09-05

申请号：US14358753

申请日：2012-11-07

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： Monica Galvan ,  Roberto Pantaleoni ,  Ofelia Fusco ,  Benedetta Gaddi ,  Andreas Neumann ,  Antonio Mazzucco ,  Gianni Collina ,  Marco Ciarafoni

IPC: C08L23/12 ,  C08F10/06

CPC classification number: C08L23/12 ,  C08F10/06 ,  C08F4/651 ,  C08F4/6543 ,  C08F2/00 ,  C08F210/16 ,  C08F210/06 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/21 ,  C08F2/001 ,  C08F110/06 ,  C08L23/16

Abstract: Preparing propylene polymer compositions comprising 50 to 90% by weight of a propylene (co)polymer, and 10 to 50% by weight of an ethylene copolymer. The polymerization process includes, in the presence of a catalyst system: (i) a first step of polymerizing propylene to produce the propylene (co)polymer; and (ii) a successive gas-phase polymerization step performed in the presence of the propylene (co)polymer, ethylene, and one or more α-olefins to produce the ethylene copolymer. The catalyst system contains the product obtained by contacting: (a) a solid catalyst component comprising at least two internal electron donor compounds, a succinate and a 1,3-diether; (b) an aluminum hydrocarbyl compound, and (c) optionally, an external electron donor compound.

公开(公告)号：US20170218100A1

公开(公告)日：2017-08-03

申请号：US15514871

申请日：2015-09-22

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： PEITRO BAITA ,  TIZIANO DALL'OCCO ,  MARIA DI DIEGO ,  DARIO LIGUORI ,  LORELLA MARTURANO ,  GABRIELE MEI ,  GIAMPIERO MORINI ,  ROBERTA PICA

IPC: C08F110/02

CPC classification number: C08F110/02 ,  C08F2410/02 ,  C08F2500/12 ,  C08F2500/18 ,  C08F4/6494 ,  C08F4/6493 ,  C08F4/6492 ,  C08F4/6543

Abstract: The present disclosure provides a catalyst system made from or containing: (A) a solid catalyst component made from or containing (i) a titanium compound supported on a magnesium dichloride; (B) an aluminum alkyl compound; and (C) a halogenated organic ester of formula A-COOR, wherein R is a C1-C10 hydrocarbon group and A is a C1-C15 saturated or unsaturated hydrocarbon group in which at least one of the hydrogen atoms is replaced by a chlorine atom. The present disclosure also provides a process for preparing an olefinic polymer, including a polymerization step of polymerizing an olefin in the presence of the catalyst system. The present disclosure also provides an olefinic polymer made therefrom.

公开(公告)号：US20170198125A1

公开(公告)日：2017-07-13

申请号：US15321321

申请日：2015-06-08

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： TAKESHI TSUKAHARA ,  NOBUYUKI TSURUMI ,  SHITOSHI KANNO ,  KUNIO YAMAMOTO ,  TAKESHI NAKAJIMA

IPC: C08L23/12

Abstract: The present disclosure generally relates to a heterophasic polypropylene composition comprising 68-76% by weight of a propylene homopolymer or copolymer matrix, 24-32% by weight of an ethylene-propylene copolymer, and a nucleating agent. In some embodiments, the composition has an intrinsic viscosity of the xylene soluble (XSIV) fraction at room temperature of up to 1.3 dl/g and a melt flow rate (230° C., 2.16 kg) of 30 to 70 g/10 min. The compositions disclosed herein can be used in molded articles, using techniques such as thin wall injection molding, that are endowed with excellent impact behavior.

公开(公告)号：US20170183485A1

公开(公告)日：2017-06-29

申请号：US15313482

申请日：2015-04-28

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： CLAUDIO CAVALIERI ,  MICHELE GRAZZI ,  ROBERTO PANTALEONI

IPC: C08L23/06 ,  C08L23/08 ,  C08F210/02

CPC classification number: C08L23/06 ,  C08F210/02 ,  C08L23/08 ,  C08L2205/025 ,  C08L2207/02 ,  C08L23/16

Abstract: Ethylene polymer composition having a fusion enthalpy ΔHfus, measured by Differential Scanning calorimetry with a heating rate of 20° C. per minute, of 60 J/g or more, comprising, all per cent amounts being by weight: A) 25-55% of an ethylene polymer containing 10% or less, referred to the weight of A), of a fraction XSA soluble in xylene at 25° C.; B) 45-75% of a copolymer of ethylene and propylene containing from 45% to 70%, of ethylene and 60% or more of a fraction XSB soluble in xylene at 25° C., both the ethylene of the copolymer and XSB amounts being referred to the weight of B); wherein the amounts of A) and B) are referred to the total weight of A)+B).

公开(公告)号：US20170166667A1

公开(公告)日：2017-06-15

申请号：US15428940

申请日：2017-02-09

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： Alessandro Mignogna ,  Reynald Chevalier ,  Igor Kashulin ,  Ilya Nifant'ev ,  Giampiero Morini ,  Martin Schneider

IPC: C08F110/06

CPC classification number: C08F110/06 ,  C07C327/26 ,  C07C327/28 ,  C07C329/10 ,  C07C333/04 ,  C08F4/651 ,  C08F2500/12 ,  C08F2500/15 ,  C08F4/6545

Abstract: Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor of formula (I) In which X and Y are selected from, R1, and —OR1 and —NR2, B is oxygen or sulphur S is sulphur, R1 is selected from C1-C15 hydrocarbon groups, optionally contain a heteroatom selected from halogen, P, S, N, O and Si, which can be fused together to form one or more cycles, R is hydrogen or R1 and A is a bivalent bridging group with chain length between the two bridging bonds being 1-10 atoms.

公开(公告)号：US20170145200A1

公开(公告)日：2017-05-25

申请号：US15425759

申请日：2017-02-06

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： DIETER LANGENFELDER ,  Jurgen Rohrmann

IPC: C08L23/14 ,  C08J9/00

Abstract: The present invention relates to a new polypropylene composition for molded articles, such as finished parts for the automotive industry. A composition comprising: (A) from 40 to 85% by weight of a first propylene-based component being selected from propylene homopolymers, propylene copolymers and heterophasic propylene polymer, such first propylene-based component having a flexural modulus higher than 800 MPa; (B) from 5 to 20% by weight of a second propylene-based component being a heterophasic propylene polymer comprising: (B1) from 20 to 90% by weight of a crystalline polypropylene, and (B2) from 10 to 80% by weight of a copolymer of ethylene and at least one C3-C10 alpha-olefin, such copolymer containing from 10 to 70% by weight of ethylene, being soluble in xylene at room temperature, and having an intrinsic viscosity in tetrahydronaphtalene at 135° C. of higher than 3.5 dl/g; and (C) from 10 to 40% by weight of glass fibers.

公开(公告)号：US09650457B2

公开(公告)日：2017-05-16

申请号：US14402262

申请日：2013-05-21

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： Roberta Marzolla ,  Monica Galvan ,  Tiziana Caputo

IPC: C08F210/06 ,  C08F210/16 ,  C08J5/18 ,  C08L23/14

CPC classification number: C08F210/06 ,  C08F210/16 ,  C08J5/18 ,  C08J2323/12 ,  C08J2323/14 ,  C08L23/14 ,  C08L23/142 ,  C08F210/08 ,  C08F2500/12 ,  C08F2500/26

Abstract: A propylene, ethylene, 1-butene terpolymer containing from 0.5 wt % to 2.2 wt % of ethylene derived units and from 6.0 wt % to 20.0 wt % of 1 butene derived units; wherein: i) the ratio C2 wt %/C4 wt % ranges from 0.09 to 0.06; wherein C2 wt % is the weight percent of ethylene derived units and C4 wt % is the weight percent of 1-butene derived units; ii) the Melt flow rate ranges from 0.4 to 54 g/10 min; iii) the xylene soluble fraction at 25° C. is lower than 15.0 wt % the minimum value being 5.0 wt %.

公开(公告)号：US20170114254A1

公开(公告)日：2017-04-27

申请号：US15400734

申请日：2017-01-06

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： MASSIMO COVEZZI ,  GABRIELE MEI ,  MARIA DI DIEGO ,  PIERO GESSI ,  PIETRO BAITA ,  ROBERTA PICA

IPC: C09J151/06 ,  C08L23/06 ,  C08L23/20 ,  B32B15/085 ,  C09J123/20 ,  C09J5/02 ,  B32B27/06 ,  B32B7/12 ,  C08L51/06 ,  C09J123/06

CPC classification number: C09J151/06 ,  B32B7/12 ,  B32B15/085 ,  B32B27/06 ,  B32B2307/718 ,  C08F10/00 ,  C08F110/02 ,  C08F2410/02 ,  C08L23/06 ,  C08L23/20 ,  C08L51/06 ,  C08L2205/02 ,  C08L2205/03 ,  C08L2207/062 ,  C09J5/02 ,  C09J123/06 ,  C09J123/20 ,  C09J2205/306 ,  C09J2400/166 ,  C09J2423/00 ,  C09J2423/04 ,  C09J2451/00 ,  C09J2463/008 ,  C08F2/005 ,  C08F2/007 ,  C08F2500/07 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/24 ,  C08F4/025 ,  C08F110/06 ,  C08F4/6492

Abstract: The present technology relates to a method of introducing a supported antistatic compound that does not comprise a transition-metal-based catalyst component for use in an olefin polymerization reactor. In some embodiments, the methods disclosed herein avoid the formation of polymer agglomerates in the reactor and minimize potentially negative effects on catalyst yield.

公开(公告)号：US20170073444A1

公开(公告)日：2017-03-16

申请号：US15309042

申请日：2015-05-06

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： FABRIZIO PIEMONTESI ,  CAROLINE CATHELIN ,  SIMONA GUIDOTTI ,  DARIO LIGUORI ,  GIAMPIERO MORINI ,  DAVIDE TARTARI ,  GIANNI VITALE

IPC: C08F210/06

CPC classification number: C08F210/06 ,  C08F210/16 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/26 ,  C08F4/6574

Abstract: The present disclosure relates to propylene-ethylene copolymers comprising an ethylene content of 0.1-10% by weight, a molecular weight distribution (MWD), expressed in terms of Mw/Mn, of greater than 3.0 and a xylene soluble (XS) fraction content defined by values that fall below the line given by the equation XS=1.0296·e0.435C2. The propylene-ethylene copolymers advantageously exhibit high transparency and low melting temperatures.

Abstract translation: 本公开内容涉及丙烯 - 乙烯共聚物，其包含乙烯含量为0.1-10重量％，分子量分布（MWD），以Mw / Mn表示，大于3.0，二甲苯可溶（XS）部分含量 由低于由公式XS = 1.0296·e0.435C2给出的线的值定义。 丙烯 - 乙烯共聚物有利地表现出高透明度和低熔融温度。