公开(公告)号：US20190336930A1

公开(公告)日：2019-11-07

申请号：US16477283

申请日：2017-12-15

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： ENRICO BALESTRA ,  TIZIANA CAPUTO ,  MASSIMO COVEZZI ,  MAURIZIO DORINI ,  ANTONIO MAZZUCCO ,  GABRIELE MEI ,  RICARDO RINALDI

IPC: B01J8/24 ,  B01J8/18 ,  C08F2/01 ,  C08F2/44

Abstract: A fluid is fed into a polymer bed of a fluidized bed gas phase polymerization reactor by introducing the fluid into the polymer bed through a distributor protruding into the fluidized bed zone of the reactor and terminating with a discharge end positioned so that the following equation is fulfilled: d/D>0.002 wherein d is the distance of the distributor's discharge end from the wall of the reactor, and D is the diameter of the reactor in the fluidized bed zone.

公开(公告)号：US20180215845A1

公开(公告)日：2018-08-02

申请号：US15750469

申请日：2016-08-03

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： GIAMPIERO MORINI ,  MASSIMO COVEZZI ,  TIZIANO DALL'OCCO ,  DARIO LIGUORI ,  FABRIZIO PIEMONTESI ,  GIANNI VITALE

IPC: C08F10/06

Abstract: A gas-phase process for the homopolymerization or copolymerization of propylene with other olefins, including carrying out the polymerization in the presence of a catalyst system made from or containing: (a) a solid catalyst component made from or containing Mg, Ti, halogen, an electron donor selected from 1.3-diethers and an olefin polymer in a specific amount; (b) an aluminum alkyl compound and (c) an external electron donor (ED) compound, wherein components (b) and (c) being employed in amounts such that the Al/(ED) molar ratio ranges from about 2 to about 200.

公开(公告)号：US20190276566A1

公开(公告)日：2019-09-12

申请号：US16347124

申请日：2017-11-02

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： PIETRO BAITA ,  MASSIMO COVEZZI ,  MARIA DI DIEGO ,  LORELLA MARTURANO ,  ANTONIO MAZZUCCO ,  GABRIELE MEI ,  ROBERTA PICA

IPC: C08F10/02

Abstract: A gas-phase process for the homopolymerization or copolymerization of olefins carried out in the presence of a catalyst system formed by a contacting, in a liquid hydrocarbon and in the presence of hydrogen, (a) a solid catalyst component comprising Ti, Mg, and Cl, and optionally an internal electron donor compound, (b) an aluminum alkyl compound and optionally (c) an external donor compound.

公开(公告)号：US20180362748A1

公开(公告)日：2018-12-20

申请号：US16061258

申请日：2016-11-22

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： MASSIMO COVEZZI ,  PAOLA MASSARI ,  CLAUDIO CAVALIERI ,  ROBERTA MARZOLLA

IPC: C08L23/14 ,  C08J5/18 ,  B32B27/08 ,  B32B27/32

Abstract: A propylene polymer composition made from or containing: a) from about 40 wt % to about 80 wt % of a propylene 1-hexene copolymer containing from about 5.5 to about 9.0% by weight, based upon the total weight of the propylene 1-hexene copolymer, of 1-hexene derived units and having a Melt Flow Rate (MFR, measured according to ASTM D 1238 at 230° C., with a load of 2.16 kg) from about 3.5 to about 12.0 g/10 min; and b) from about 20 wt % to about 60 wt % of a propylene ethylene copolymer containing from about 1.5 wt % to about 6.5 wt % based upon the total weight of the propylene ethylene copolymer, of ethylene derived units, and having a Melt Flow Rate (MFR, measured according to ASTM D 1238, at 230° C., with a load of 2.16 kg) from about 3.5 to about 12.0 g/10 min; the sum of a) and b) being 100.

公开(公告)号：US20170114254A1

公开(公告)日：2017-04-27

申请号：US15400734

申请日：2017-01-06

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： MASSIMO COVEZZI ,  GABRIELE MEI ,  MARIA DI DIEGO ,  PIERO GESSI ,  PIETRO BAITA ,  ROBERTA PICA

IPC: C09J151/06 ,  C08L23/06 ,  C08L23/20 ,  B32B15/085 ,  C09J123/20 ,  C09J5/02 ,  B32B27/06 ,  B32B7/12 ,  C08L51/06 ,  C09J123/06

CPC classification number: C09J151/06 ,  B32B7/12 ,  B32B15/085 ,  B32B27/06 ,  B32B2307/718 ,  C08F10/00 ,  C08F110/02 ,  C08F2410/02 ,  C08L23/06 ,  C08L23/20 ,  C08L51/06 ,  C08L2205/02 ,  C08L2205/03 ,  C08L2207/062 ,  C09J5/02 ,  C09J123/06 ,  C09J123/20 ,  C09J2205/306 ,  C09J2400/166 ,  C09J2423/00 ,  C09J2423/04 ,  C09J2451/00 ,  C09J2463/008 ,  C08F2/005 ,  C08F2/007 ,  C08F2500/07 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/24 ,  C08F4/025 ,  C08F110/06 ,  C08F4/6492

Abstract: The present technology relates to a method of introducing a supported antistatic compound that does not comprise a transition-metal-based catalyst component for use in an olefin polymerization reactor. In some embodiments, the methods disclosed herein avoid the formation of polymer agglomerates in the reactor and minimize potentially negative effects on catalyst yield.