PREPARATION OF 4-BROMO-o-XYLENE
    203.
    发明申请
    PREPARATION OF 4-BROMO-o-XYLENE 审中-公开
    4-BROMO-o-XYLENE的制备

    公开(公告)号:WO1991013047A1

    公开(公告)日:1991-09-05

    申请号:PCT/US1991001020

    申请日:1991-02-14

    CPC classification number: C07C17/12 C07C25/125

    Abstract: A regioselective process is provided for preparing 4-bromo-o-xylene in an isomer mixture of 4-bromo-o-xylene and 3-bromo-o-xylene by combining a molar excess of bromine with o-xylene. The produced 3-bromo-o-xylene isomer preferentially reacts with the excess bromine to produce dibromo-o-xylenes. The weight ratio of the 4-bromo-o-xylene to the 3-bromo-o-xylene in the product isomer mixture can be as high as about 97:3. Concurrent production of alpha-bromo-o-xylene is avoided by conducting the admixing in either darkness or in sulfur dioxide solution. The dibromo-o-xylene by-products are easily separated by subsequent vacuum distillation or similar expedients. The use of small amounts of sulfur dioxide also provides for enhanced selectivity for the formation of 4-bromo-o-xylene relative to 3-bromo-o-xylene even when the mole ratio of bromine to o-xylene is 1:1 and lower.

    Abstract translation: 提供了一种区域选择性方法,通过将摩尔过量的溴与邻二甲苯组合,在4-溴 - 邻 - 二甲苯和3-溴 - 邻二甲苯的异构体混合物中制备4-溴 - 邻二甲苯。 所产生的3-溴 - 邻二甲苯异构体优先与过量的溴反应生成二溴 - 二甲苯。 产物异构体混合物中4-溴 - 邻二甲苯与3-溴 - 邻 - 二甲苯的重量比可以高达约97:3。 通过在黑暗或二氧化硫溶液中混合来避免同时生产α-溴代邻二甲苯。 通过随后的真空蒸馏或类似的方法容易地分离出二溴邻二甲苯副产物。 即使当溴与邻二甲苯的摩尔比为1:1时,使用少量的二氧化硫也提供了相对于3-溴 - 邻二甲苯形成4-溴 - 邻二甲苯的增强的选择性 。

    AN ASSEMBLY FOR ARRANGING OPTICAL COMPONENTS OF A LASER
    206.
    发明申请
    AN ASSEMBLY FOR ARRANGING OPTICAL COMPONENTS OF A LASER 审中-公开
    用于安装激光的光学部件的组件

    公开(公告)号:WO1990009689A1

    公开(公告)日:1990-08-23

    申请号:PCT/US1990000542

    申请日:1990-01-30

    CPC classification number: H01S3/025 H01S3/061 H01S3/09415

    Abstract: This invention relates to an assembly (30) for arranging the optical components (80, 84, 87) of a laser, comprising a plurality of support structures (32, 34) having an indentation defining an inner surface (36) including means (64) for supporting a lens (80) and means (58) for supporting a lasant material (84) the support structure further including an intermediate surface (66) adjacent to the inner surface (36), and interlocking means (70, 72) positioned on the intermediate surface (66) for interlocking the plurality of support structures (32, 34).

    BLENDS OF LIQUID CRYSTALLINE POLYMERS OF HYDROQUINONE POLY(ISO-TEREPHTHALATES) p-HYDROXYBENZOIC ACID POLYMERS AND ANOTHER LCP CONTAINING OXYBISBENZENE AND NAPHTHALENE DERIVATIVES
    209.
    发明申请
    BLENDS OF LIQUID CRYSTALLINE POLYMERS OF HYDROQUINONE POLY(ISO-TEREPHTHALATES) p-HYDROXYBENZOIC ACID POLYMERS AND ANOTHER LCP CONTAINING OXYBISBENZENE AND NAPHTHALENE DERIVATIVES 审中-公开
    水解聚合物(ISO-庚二酸盐)对羟基苯甲酸聚合物的液晶聚合物的混合物和含有氧化苯乙烯和萘甲酸衍生物的其他LCP

    公开(公告)号:WO1990004002A1

    公开(公告)日:1990-04-19

    申请号:PCT/US1989004330

    申请日:1989-10-10

    CPC classification number: C08G63/83 C08G63/605 C08L67/00

    Abstract: This invention relates to a blend comprising a first LCP polyester polymer consisting essentially of units (I), (II), (III), and (IV), having a melting point under about 420 DEG C, p is approximately equal to r+q, r is from about 0.05 to about 0.9, q is from about 0.95 to about 0.1 and s is from about 0.05 to about 9, and a second LCP polyester polymer comprising at least one moiety selected from the group consisting of hydroxybenzoic acid, hydroxynaphthalene carboxylic acid, dihydroxy naphthalene, naphthalene dicarboxylic acid, oxybisbenzoic acid and substituted hydroquinones wherein the said moiety or moieties comprise(s) at least about 5 mole percent of the units in said second LCP polyester.

    Abstract translation: 本发明涉及包含基本上由单元(I),(II),(III)和(IV)组成)的第一LCP聚酯聚合物的共混物,其熔点在约420℃,p约等于r + q,r为约0.05至约0.9,q为约0.95至约0.1,s为约0.05至约9,第二LCP聚酯聚合物包含至少一个选自羟基苯甲酸,羟基萘 羧酸,二羟基萘,萘二甲酸,氧基双苯甲酸和取代的氢醌,其中所述部分或部分包含至少约5摩尔%的所述第二LCP聚酯中的单元。

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