公开(公告)号：US08263520B2

公开(公告)日：2012-09-11

申请号：US12956050

申请日：2010-11-30

Applicant: Joseph N. Coalter, III ,  Tak W. Leung ,  Tao Tao ,  Kuanqiang Gao

Inventor： Joseph N. Coalter, III ,  Tak W. Leung ,  Tao Tao ,  Kuanqiang Gao

IPC: C08F4/02 ,  C08F2/00 ,  B01J31/00

CPC classification number: C07C69/96 ,  B01J27/135 ,  B01J27/138 ,  B01J31/0201 ,  B01J31/0272 ,  B01J31/143 ,  B01J31/26 ,  B01J31/38 ,  C08F110/06 ,  C08F210/06 ,  Y02P20/52 ,  C08F4/651 ,  C08F4/6465 ,  C08F210/16 ,  C08F2500/12

Abstract: A solid, hydrocarbon-insoluble, catalyst component useful in polymerizing olefins, said catalyst component containing magnesium, titanium, and halogen, and further containing an internal electron donor having a structure: [R1—O—C(O)—O—]xR2 wherein R1 is independently at each occurrence, an aliphatic or aromatic hydrocarbon, or substituted hydrocarbon group containing from 1 to 20 carbon atoms; x is 2-4; and R2 is an aliphatic or aromatic hydrocarbon, or substituted hydrocarbon group containing from 1 to 20 carbon atoms, provided that there are 2 atoms in the shortest chain connecting a first R1—O—C(O)—O— group and a second R1—O—C(O)—O— group.

Abstract translation: 用于聚合烯烃的固体，不溶于烃的催化剂组分，所述催化剂组分含有镁，钛和卤素，并且还含有具有以下结构的内部电子给体：[R 1 -O-C（O）-O-] x R 2 其中R1在每次出现时独立地为含有1至20个碳原子的脂族或芳族烃或取代的烃基; x为2-4; 并且R2是含有1至20个碳原子的脂族或芳族烃或取代的烃基，条件是在连接第一个R1-O-C（O）-O-基团和第二个R1的最短链中有2个原子 -O-C（O）-O-基。

公开(公告)号：US20120065321A1

公开(公告)日：2012-03-15

申请号：US13322001

申请日：2010-06-24

Applicant: Werner M.A. Grootaert ,  Kim M. Vogel ,  Dennis E. Vogel

Inventor： Werner M.A. Grootaert ,  Kim M. Vogel ,  Dennis E. Vogel

IPC: C08L27/18 ,  C07F9/54 ,  C07C209/68 ,  B29C71/00 ,  C07C33/42 ,  C07C29/70 ,  C07C37/66 ,  C08F216/12 ,  C08F4/00 ,  C07C39/24

CPC classification number: C08F4/00 ,  B01J27/14 ,  B01J31/0201 ,  B01J31/0205 ,  B01J31/0234 ,  B01J31/0239 ,  B01J31/0268 ,  B01J2231/14 ,  C07C259/06 ,  C08F214/18 ,  C08F214/184 ,  C08K5/0025 ,  C08K5/05 ,  C08K5/19 ,  C08K5/29 ,  C08K5/315 ,  C08K5/50 ,  C08L27/12 ,  C08L27/18 ,  C08L2205/02

Abstract: A catalyst composition comprising a cation and an anion of the formula Anq−Qpm+, wherein m, n, p, and q are positive integers, wherein m*p=n*q, wherein Qm+ is an organo onium, and Aq− is an anion, provided that at least one Aq− is selected from the formula (I) wherein each R independently is H, halo, alkyl, aryl, aralkyl, or cycloalkyl, and which also may be halogenated, fluorinated, or perfluorinated, wherein two or more of R and R′ groups may together form a ring, wherein each R group independently may contain one or more heteroatom(s), wherein R′ can be the same as R, with the proviso that R′ cannot be halo, and wherein the catalyst composition is essentially free of hydrocarbon containing alcohol. Also provided are a fluoropolymer composition including this curative, a method of making a fluoropolymer, and fluoropolymer articles containing curable or cured fluoropolymer compositions

Abstract translation: 一种包含阳离子和式Anq-Qpm +的阴离子的催化剂组合物，其中m，n，p和q是正整数，其中m * p = n * q，其中Qm +是有机鎓，Aq-是 阴离子，条件是至少一个Aq-选自式（I），其中每个R独立地为H，卤素，烷基，芳基，芳烷基或环烷基，并且还可以是卤化，氟化或全氟化的，其中两个或 更多的R和R'基团可以一起形成环，其中每个R基团独立地可以含有一个或多个杂原子，其中R'可以与R相同，条件是R'不能是卤素，并且其中 催化剂组合物基本上不含含烃的醇。 还提供了包含该固化剂的含氟聚合物组合物，制备含氟聚合物的方法和含有可固化或固化的含氟聚合物组合物的含氟聚合物制品

公开(公告)号：US20110251352A1

公开(公告)日：2011-10-13

申请号：US13120459

申请日：2009-09-17

Applicant: Gianni Collina ,  Anna Fait ,  Ofelia Fusco ,  Giampiero Morini ,  Lorella Pedriali ,  Rosa Spoto ,  Paolo Vincenzi

Inventor： Gianni Collina ,  Anna Fait ,  Ofelia Fusco ,  Giampiero Morini ,  Lorella Pedriali ,  Rosa Spoto ,  Paolo Vincenzi

IPC: C08F4/654 ,  C08F10/02 ,  C08F255/02

CPC classification number: C08F10/02 ,  B01J31/0201 ,  B01J31/0235 ,  B01J31/0272 ,  B01J31/143 ,  B01J31/2208 ,  B01J31/26 ,  B01J31/38 ,  C08F10/06 ,  C08F210/16 ,  C08F4/6492 ,  C08F4/651 ,  C08F2/34 ,  C08F210/06 ,  C08F2500/18 ,  C08F2500/12 ,  C08F2500/17

Abstract: Prepolymerized catalyst component for the polymerization of olefins CH2═CHR, wherein R is hydrogen or a C1-C12 hydrocarbyl group, comprising a solid catalyst component characterized by comprising Mg, Ti halogen and an electron donor (ID) selected from the alkyl esters of aromatic dicarboxylic acids in such an amount that the molar ratio ID/Mg ranges from 0.025 to 0.07 and the Mg/Ti molar ratio is higher than 13, said prepolymerized catalyst component containing an amount of ethylene pre-polymer up to 50 g per g of said solid catalyst component.

Abstract translation: 用于烯烃聚合的预聚合催化剂组分CH 2 = CHR，其中R是氢或C 1 -C 12烃基，其包含固体催化剂组分，其特征在于包含Mg，Ti卤素和选自芳族的烷基酯的电子给体（ID） 二羧酸的量使得ID / Mg的摩尔比为0.025〜0.07，Mg / Ti的摩尔比高于13，所述预聚合的催化剂组分含有一定量的乙烯预聚物，每克所述的 固体催化剂组分。

公开(公告)号：US07964526B2

公开(公告)日：2011-06-21

申请号：US12432728

申请日：2009-04-29

Applicant: Theodorus Maesen ,  Alexander E. Kuperman ,  Dennis Dykstra ,  Soy Uckung ,  Darren Fong

Inventor： Theodorus Maesen ,  Alexander E. Kuperman ,  Dennis Dykstra ,  Soy Uckung ,  Darren Fong

IPC: B01J27/04 ,  B01J27/045 ,  B01J27/047 ,  B01J27/051 ,  B01J27/049 ,  B01J31/00

CPC classification number: B01J31/2226 ,  B01J23/002 ,  B01J23/24 ,  B01J23/652 ,  B01J23/85 ,  B01J23/8885 ,  B01J31/0201 ,  B01J31/04 ,  B01J35/0026 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1071 ,  B01J35/1085 ,  B01J37/0009 ,  B01J37/0018 ,  B01J37/0045 ,  B01J37/031 ,  B01J37/20 ,  B01J2523/00 ,  B01J2531/64 ,  B01J2531/66 ,  B01J2531/847 ,  C10G45/04 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/847

Abstract: A method for preparing a bulk multi-metallic suitable for hydrotreating heavy oil feeds is provided. In the process of preparing the catalyst precursor which is subsequently sulfided to form the bulk catalyst, a catalyst precursor filter cake is treated with at least a chelating agent, resulting in a catalyst precursor with optimum porosity with at least 90% of the pores being macropores, and having a total pore volume of at least 0.12 g/cc.

Abstract translation: 提供了一种制备适用于加氢处理重油进料的散装多金属的方法。 在制备随后硫化以形成本体催化剂的催化剂前体的过程中，用至少一种螯合剂处理催化剂前体滤饼，得到具有最佳孔隙率的催化剂前体，至少90％的孔是大孔 ，并且具有至少0.12g / cc的总孔体积。

公开(公告)号：US20110094939A1

公开(公告)日：2011-04-28

申请号：US12974435

申请日：2010-12-21

Applicant: Marcel Adriaan JANSEN ,  Franciscus Wilhelmus VAN HOUTERT ,  Toshiyuki ADO ,  Tetsuro KAMO ,  Naohiro NISHIMOTO

Inventor： Marcel Adriaan JANSEN ,  Franciscus Wilhelmus VAN HOUTERT ,  Toshiyuki ADO ,  Tetsuro KAMO ,  Naohiro NISHIMOTO

IPC: C10G45/04 ,  B01J23/24

CPC classification number: B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J23/94 ,  B01J31/0201 ,  B01J37/0203 ,  B01J38/52 ,  B01J38/60 ,  B01J38/62 ,  C10G45/08 ,  C10G2300/703

Abstract: The invention pertains to a process for activating an hydrotreating catalyst comprising a Group VIB metal oxide and a Group VIII metal oxide which process comprises contacting the catalyst with an acid and an organic additive which has a boiling point in the range of 80-500° C. and a solubility in water of at least 5 grams per liter (20° C., atmospheric pressure), optionally followed by drying under such conditions that at least 50% of the additive is maintained in the catalyst. The hydrotreating catalyst may be a fresh hydrotreating catalyst or a used hydrotreating catalyst which has been regenerated.

Abstract translation: 本发明涉及一种活化加氢处理催化剂的方法，该催化剂包含VIB族金属氧化物和VIII族金属氧化物，该方法包括使催化剂与沸点在80-500℃范围内的酸和有机添加剂接触 和在水中的溶解度至少为5克/升（大气压），任选地在使至少50％的添加剂保持在催化剂中的条件下进行干燥。 加氢处理催化剂可以是新鲜的加氢处理催化剂或已经再生的使用的加氢处理催化剂。

公开(公告)号：US20110000824A1

公开(公告)日：2011-01-06

申请号：US12496442

申请日：2009-07-01

Applicant: Bi-Zeng Zhan ,  Theodorus Maesen ,  Janine Lichtenberger ,  Andrew Rainis ,  Hye-Kyung Timken

Inventor： Bi-Zeng Zhan ,  Theodorus Maesen ,  Janine Lichtenberger ,  Andrew Rainis ,  Hye-Kyung Timken

IPC: C10G25/03 ,  B01J29/04

CPC classification number: B01J31/0209 ,  B01J21/12 ,  B01J29/084 ,  B01J29/106 ,  B01J29/126 ,  B01J29/146 ,  B01J29/166 ,  B01J31/0201 ,  B01J31/0207 ,  B01J31/0237 ,  B01J31/0238 ,  B01J31/0244 ,  B01J31/0249 ,  B01J31/04 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/1066 ,  B01J37/0203 ,  B01J2229/20 ,  B01J2229/34 ,  B01J2229/42 ,  B01J2231/641 ,  C10G45/00 ,  C10G45/04 ,  C10G45/12 ,  C10G45/54 ,  C10G47/06 ,  C10G47/12 ,  C10G47/14 ,  C10G49/04 ,  C10G49/06 ,  C10G49/08 ,  C10G2300/4018 ,  C10G2400/04

Abstract: The present invention is directed to a hydroprocessing catalyst containing at least one catalyst support, one or more metals, optionally one or more molecular sieves, optionally one or more promoters, wherein deposition of at least one of the metals is achieved in the presence of a modifying agent.

Abstract translation: 本发明涉及一种加氢处理催化剂，其包含至少一种催化剂载体，一种或多种金属，任选的一种或多种分子筛，任选的一种或多种助催化剂，其中至少一种金属的沉积在 改性剂。

公开(公告)号：US20100292419A1

公开(公告)日：2010-11-18

申请号：US12735278

申请日：2008-12-22

Applicant: Gianni Collina ,  Ofelia Fusco

Inventor： Gianni Collina ,  Ofelia Fusco

IPC: C08F4/10 ,  B01J31/02 ,  C08F4/602

CPC classification number: C08F110/06 ,  B01J27/135 ,  B01J27/138 ,  B01J31/0201 ,  B01J31/0272 ,  B01J31/143 ,  B01J31/26 ,  B01J31/38 ,  C08F4/651 ,  C08F4/6492 ,  C08F2500/12 ,  C08F2500/18

Abstract: Prepolymerized catalyst component for the polymerization of olefins CH2═CHR in which R is hydrogen or a hydrocarbyl radical with 1-12 carbon atoms, having average particle size equal to or lower than 30 μm comprising a solid catalyst component comprising magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being selected from 1,3-diethers and the other one being selected from esters of aromatic mono or dicarboxylic acids, said solid catalyst component being prepolymerized with an olefin, having from 2 to 10 carbon atoms, to such an extent that the amount of the olefin prepolymer is equal to or lower than 50 g per g of solid catalyst component.

Abstract translation: 用于烯烃CH 2 = CHR聚合的预聚合催化剂组分，其中R是氢或具有1-12个碳原子的烃基，平均粒度等于或小于30μm，包括包含卤化镁的固体催化剂组分，钛化合物 具有至少一个Ti-卤键和至少两个电子给体化合物，其中一个选自1,3-二醚，另一个选自芳族单或二羧酸的酯，所述固体催化剂组分与烯烃预聚合 具有2至10个碳原子的烯烃预聚物的量等于或低于每克固体催化剂组分50克的程度。

公开(公告)号：US07820580B2

公开(公告)日：2010-10-26

申请号：US12270424

申请日：2008-11-13

Applicant: Zengquan Qin ,  Jason T. Poulton ,  Michael W. Hayes

Inventor： Zengquan Qin ,  Jason T. Poulton ,  Michael W. Hayes

IPC: B01J31/28 ,  B01J31/18 ,  B01J27/12 ,  B01J27/128

CPC classification number: B01J31/2282 ,  B01J31/0201 ,  B01J31/0202 ,  B01J31/0204 ,  B01J31/128 ,  B01J31/143 ,  B01J31/2265 ,  B01J2531/847 ,  B01J2531/90 ,  C08F136/06 ,  C08F4/7098

Abstract: A nickel-carbene polymerization catalyst system for preparing high cis polydienes is provided. The catalyst system comprises (a) a nickel N-heterocyclic carbene complex, (b) an organoaluminum compound, (c) a fluorine-containing compound, and (d) optionally, an alcohol. Also provided is a process for producing a polydiene comprising reacting a conjugated diene in the presence of a polymerization catalyst comprising (a) a nickel N-heterocyclic carbene complex, (b) an organoaluminum compound, (c) a fluorine-containing compound, and (d) optionally, an alcohol.

Abstract translation: 提供了制备高顺式聚二烯的镍 - 卡宾聚合催化剂体系。 催化剂体系包括（a）镍N-杂环卡宾络合物，（b）有机铝化合物，（c）含氟化合物和（d）任选的醇。 还提供了一种制备聚二烯的方法，包括在聚合催化剂存在下使共轭二烯反应，所述聚合催化剂包含（a）镍N-杂环卡宾络合物，（b）有机铝化合物，（c）含氟化合物和 （d）任选地，醇。

公开(公告)号：US07795168B2

公开(公告)日：2010-09-14

申请号：US11885414

申请日：2006-02-28

Applicant: Makoto Toba ,  Yuji Yoshimura ,  Nobuyuki Matsubayashi ,  Takashi Matsui

Inventor： Makoto Toba ,  Yuji Yoshimura ,  Nobuyuki Matsubayashi ,  Takashi Matsui

IPC: B01J27/20

CPC classification number: B01J23/882 ,  B01J23/88 ,  B01J27/22 ,  B01J31/0201 ,  B01J35/002 ,  B01J37/0203 ,  C10G2300/104 ,  C10G2400/02

Abstract: A porous inorganic oxide support comprising an oxygen-containing carbonaceous material supported thereon, preferably a porous inorganic oxide support wherein the oxygen-containing carbonaceous material is a carbide of an oxygen-containing organic compound, wherein the ratio of the supported carbon amount with respect to the mass of the support for preparing the catalyst is from 0.05 to 0.2, the atomic ratio of the supported hydrogen amount with respect to the supported carbon amount is from 0.4 to 1.0, and the atomic ratio of the supported oxygen amount with respect to the supported carbon amount is from 0.1 to 0.6; and a hydrotreating catalyst of catalytic cracking gasoline which comprises the support and a catalyst containing a Group 8 metal of the periodic table, molybdenum (Mo), phosphorus and sulfur which is supported on the support are useful as a desulfurization catalyst of, for example, catalytic cracking gasoline at a hyperdesulfurized level, because of having functions of suppressing the hydrogenation activity of olefins and minimizing the decrease in the octane number even under reaction conditions with a high desulfurization ratio.

Abstract translation: 一种多孔无机氧化物载体，其包含负载在其上的含氧碳质材料，优选多孔无机氧化物载体，其中所述含氧碳质材料是含氧有机化合物的碳化物，其中所述负载碳量相对于 用于制备催化剂的载体的质量为0.05至0.2，负载氢量相对于负载碳量的原子比为0.4至1.0，并且负载氧量相对于负载的碳原子比 碳量为0.1〜0.6; 和催化裂化汽油的加氢处理催化剂，其包含载体和含有周期表第8族金属的催化剂，负载在载体上的钼（Mo），磷和硫，可用作例如脱硫催化剂， 催化裂化汽油处于高脱硫水平，因为即使在高脱硫比的反应条件下也具有抑制烯烃的氢化活性和最小化辛烷值降低的作用。

公开(公告)号：US07615509B2

公开(公告)日：2009-11-10

申请号：US11974079

申请日：2007-10-11

Applicant: Chuansheng Bai ,  EL-Mekki El-Malki ,  Jeff Elks ,  Zhiguo Hou ,  Jon M. McConnachie ,  Pallassana S. Venkataraman ,  Jason Wu ,  Peter W. Jacobs ,  Jun Han ,  Daniel M. Giaquinta ,  Alfred Hagemeyer ,  Valery Sokolovskii ,  Anthony F. Volpe, Jr. ,  David M. Lowe

Inventor： Chuansheng Bai ,  EL-Mekki El-Malki ,  Jeff Elks ,  Zhiguo Hou ,  Jon M. McConnachie ,  Pallassana S. Venkataraman ,  Jason Wu ,  Peter W. Jacobs ,  Jun Han ,  Daniel M. Giaquinta ,  Alfred Hagemeyer ,  Valery Sokolovskii ,  Anthony F. Volpe, Jr. ,  David M. Lowe

IPC: B01J21/18

CPC classification number: B01J37/20 ,  B01J21/04 ,  B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J23/885 ,  B01J23/8873 ,  B01J23/8898 ,  B01J31/0201 ,  B01J31/0254 ,  B01J31/2234 ,  B01J31/2239 ,  B01J35/08 ,  B01J35/1019 ,  B01J35/1047 ,  B01J35/1061 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/08 ,  B01J37/084 ,  B01J2231/62 ,  B01J2531/64 ,  B01J2531/66 ,  B01J2531/845 ,  B01J2531/847 ,  C10G45/08

Abstract: Supported metallic catalysts comprised of a Group VIII metal, a Group VIB metal, and an organic additive, and methods for synthesizing supported metallic catalysts are provided. The catalysts are prepared by a method wherein precursors of both metals are mixed and interacted with at least one organic additive, dried, calcined, and sulfided. The catalysts are used for hydroprocessing, particularly hydrodesulfurization and hydrodenitrogenation, of hydrocarbon feedstocks.

Abstract translation: 提供了由VIII族金属，VIB族金属和有机添加剂组成的负载金属催化剂，以及用于合成负载型金属催化剂的方法。 催化剂通过其中两种金属的前体混合并与至少一种有机添加剂相互作用，干燥，煅烧和硫化的方法制备。 催化剂用于烃原料的加氢处理，特别是加氢脱硫和加氢脱氮。