Improvements in the production of dyed fibres and foils of cellulose

    公开(公告)号:GB858737A

    公开(公告)日:1961-01-11

    申请号:GB1745659

    申请日:1959-05-22

    Applicant: BASF AG

    Abstract: Fibres and foils of cellulose are dyed or printed by applying a dyestuff of the formula: in which A represents a tetrazaporphin radical, E represents an aromatic radical containing a mono- or bi-cyclic nucleus, Z represents a radical of the formula: in which R1 and R2 represent hydrogen atoms, alkyl or hydroxyalkyl groups or halogen atoms and R3 represents a hydrogen or halogen atom or an alkyl, hydroxyalkyl or carboxyl group, m is a number from 1-8 and n is a number from 0-4, and also applying an acid-binding agent before, together with or after the dyestuff. Specified acid-binding agents are alkali-metal or alkaline-earth metal hydroxides, carbonates and bicarbonates and alkali-metal phosphates. If necessary, fixation of the dyestuff may be effected by heating or steaming. The dyestuffs may be prepared by acylating a tetrazaporphin derivative of the formula: with acrylic acid chloride, a - methylacrylic acid chloride, a - chloracrylic acid esters, maleic anhydride or acrylic anhydride. Specifications 827,569, 853,364 and 858,184 are referred to.

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