FLAME RETARDED STYRENIC POLYMER FOAMS AND FOAM PRECURSORS
    223.
    发明申请
    FLAME RETARDED STYRENIC POLYMER FOAMS AND FOAM PRECURSORS 审中-公开
    阻燃STYRENIC POLYMER FOAMS和FOAM PRECURSORS

    公开(公告)号:WO2007019120A1

    公开(公告)日:2007-02-15

    申请号:PCT/US2006/029814

    申请日:2006-08-01

    Abstract: Styrenic polymer foams, especially expanded and/or extruded styrenic polymer foams, are flame retarded by use of one or more flame retardant additives. These additives are i) a diether of tetrabromobisphenol-S, which ether groups do not contain bromine and wherein at least one of the ether groups is an allyl group; ii) a diether of tetrabromobisphenol-S, wherein at least one of the ether groups contains bromine; iii) a substituted benzene having a total of 6 substituents on the ring and wherein at least 3 of the substituents are bromine atoms and at least two of the substituents are C1-4 alkyl groups; iv) tribromoneopentyl alcohol; v) a tris(dibromoalkyl) benzenetricarboxylate in which each dibromoalkyl group contains, independently, 3 to 8 carbon atoms; vi) a brominated polybutadiene which is partially hydrogenated and/or aryl-terminated; vii) at least one brominated allyl ether of a novolac; viii) a brominated poly(l ,3-cycloalkadiene); ix) a brominated poly(4-vinylphenol allyl ether); x) a brominated N,TSP-phenylenebismaleimide; xi) a brominated N,N'-(4,4'-methylenediphenyl)bismaleimide; xii) a brominated N,N'-ethylenebismaleimide; xiii) ethylenebis(dibromonorbornane-dicarboxrmide) ; xiv) tetrabromobisphenol-A; or xv) a combination of any two or more of i) through xiv).

    Abstract translation: 苯乙烯类聚合物泡沫,特别是膨胀和/或挤出的苯乙烯类聚合物泡沫,通过使用一种或多种阻燃添加剂来阻燃。 这些添加剂是i)四溴双酚-S的二醚,其醚基不含溴,其中至少一个醚基是烯丙基; ii)四溴双酚-S的二醚,其中至少一个醚基含有溴; iii)在环上总共具有6个取代基的取代苯,其中至少3个取代基是溴原子,并且至少两个取代基是C 1-4烷基; iv)三溴新戊醇; v)三(二溴烷基)苯甲酸三甲酯,其中每个二溴烷基独立地含有3至8个碳原子; vi)被部分氢化和/或芳基终止的溴化聚丁二烯; vii)至少一种酚醛清漆的溴化烯丙基醚; viii)溴化聚(1,3-环烷二烯); ix)溴化聚(4-乙烯基苯酚烯丙基醚); x)溴化N,TSP-亚苯基双马来酰亚胺; xi)溴化N,N' - (4,4'-亚甲基二苯基)双马来酰亚胺; xii)溴化N,N'-亚乙基双马来酰亚胺; xiii)亚乙基双(二溴降冰片 - 二甲苯咪唑); xiv)四溴双酚A; 或xv)i)至xiv中的任何两个或更多个的组合)。

    METHOD FOR MANUFACTURING POLYETHYLENE RESIN FOAM MOLDED ARTICLE
    227.
    发明公开
    METHOD FOR MANUFACTURING POLYETHYLENE RESIN FOAM MOLDED ARTICLE 有权
    聚乙烯树脂泡沫模制品的制造方法

    公开(公告)号:EP3275928A1

    公开(公告)日:2018-01-31

    申请号:EP16772567.0

    申请日:2016-03-24

    Inventor: HAYASE, Yuki

    Abstract: A method of producing a polyethylene resin expanded molded product having a density of 0.017 g/cm 3 to 0.021 g/cm 3 and having a thickness of 10 mm to 40 mm, the method including the steps of: (a) filling a mold with expanded polyethylene resin particles; and (b) heating the expanded polyethylene resin particles so that the expanded polyethylene resin particles are fused to each other, to form the polyethylene resin expanded molded product, the expanded polyethylene resin particles, with which the mold is filled, containing a polyethylene resin, a cell nucleating agent, a polyhydric alcohol fatty acid ester, and a hydrophilic compound, the expanded polyethylene resin particles containing the cell nucleating agent in an amount of not less than 0.08 parts by weight and not more than 0.25 parts by weight, the polyhydric alcohol fatty acid ester in an amount of not less than 0.3 parts by weight and not more than 0.8 parts by weight, and the hydrophilic compound in an amount of not less than 0.01 parts by weight and not more than 10 parts by weight, relative to 100 parts by weight of the polyethylene resin, each of the expanded polyethylene resin particles having a weight of not less than 2.5 mg and not more than 3.5 mg, in the step (a), an internal pressure of 0.12 MPa to 0.16 MPa being applied to the expanded polyethylene resin particles.

    Abstract translation: 一种制造密度为0.017g / cm 3至0.021g / cm 3并且厚度为10mm至40mm的聚乙烯树脂发泡成型体的方法,该方法包括以下步骤:(a)用膨胀型聚乙烯 树脂颗粒; 和(b)将发泡聚乙烯树脂颗粒加热以使发泡聚乙烯树脂颗粒彼此熔合以形成聚乙烯树脂发泡成型体,填充模具的发泡聚乙烯树脂颗粒包含聚乙烯树脂, 细胞成核剂,多元醇脂肪酸酯和亲水性化合物,所述含有细胞成核剂的发泡聚乙烯树脂颗粒的量不小于0.08重量份且不大于0.25重量份,所述多元醇 脂肪酸酯为0.3重量份以上且0.8重量份以下,亲水性化合物的量为0.01重量份以上10重量份以下,相对于100重量份 重量份的聚乙烯树脂,在步骤(a)中,各个发泡聚乙烯树脂颗粒的重量不小于2.5mg且不大于3.5mg, 对发泡聚乙烯树脂颗粒施加0.12MPa至0.16MPa的内部压力。

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