Novel peroxyoxalates derived from hydroxy-hydroperoxides
    241.
    发明公开
    Novel peroxyoxalates derived from hydroxy-hydroperoxides 失效
    过氧草酸盐酸羟基氢过氧化物

    公开(公告)号:EP0850928A1

    公开(公告)日:1998-07-01

    申请号:EP97122765.7

    申请日:1997-12-23

    CPC classification number: C07C409/38

    Abstract: Novel peroxyoxalate compositions of Structure A ,
    and use of the novel monoperoxyoxalates of Structure A as initiators for polymerizing ethylenically unsaturated monomers and for curing of unsaturated polyester resins are disclosed.

    Abstract translation: 公开了结构A的新型过氧草酸酯组合物,< CHEM>以及使用结构A的新型单过氧化物作为用于聚合烯键式不饱和单体和不饱和聚酯树脂固化的引发剂。

    METHOD FOR COATING A SURFACE WITH A RESISTANT FACING BY CHEMICAL-VAPOR DEPOSITION
    243.
    发明授权
    METHOD FOR COATING A SURFACE WITH A RESISTANT FACING BY CHEMICAL-VAPOR DEPOSITION 失效
    方法用于涂覆表面的具有耐层。通过CVD

    公开(公告)号:EP0573645B1

    公开(公告)日:1998-04-01

    申请号:EP93902757.9

    申请日:1992-12-23

    CPC classification number: C23C16/405 C23C16/40

    Abstract: A substrate is provided with a resistant coating by the chemical-vapor deposition of hard material, by passing a gaseous mixture of a precursor of the material, an accelerant, an oxidant, and a carrier gas over the substrate surface, and then removing the by-products and unreacted materials; mixtures of hard materials are obtained by using a co-reagent in the gaseous mixture. The substrate is preferably heated. The figure shows a schematic of the apparatus which includes the precursor (102), the accelerant (104) which are vaporized and transferred to a reactor (120). A mixture of chromium oxide and tin oxide is the preferred coating material, obtained by decomposition of chromyl chloride and monobutyltintrichloride on the substrate surface in the presence of methylisobutylketone and air. Other metal mixtures can also be used.

    Catalyst for low temperature cure of blocked isocyanates
    244.
    发明公开
    Catalyst for low temperature cure of blocked isocyanates 失效
    on atur ert en atur atur atur atur atur atur atur atur atur atur

    公开(公告)号:EP0810245A1

    公开(公告)日:1997-12-03

    申请号:EP97108506.3

    申请日:1997-05-27

    CPC classification number: C08G18/246 C08G18/80 C08G63/85

    Abstract: The present invention comprises a polystannoxane catalyst, a curable composition containing the catalyst and a method of using the catalyst and curing the composition.
    The curable composition comprises:

    (i) a blocked isocyanate;
    (ii) a functional component containing reactive hydrogen;
    (iii) a polystannoxane catalyst for promoting the reaction of the blocked isocyanate with the functional component.
    A co-catalyst may also be employed based on Cu, Zn, Ni, Zr, Ce, Fe, Co, V, Sb and Bi and especially oxides, salts or chelates of said metals. The invention also relates to a method for curing a blocked isocyanate at a low reaction temperature which comprises combining the catalyst with the blocked isocyanate and functional component and heating to a temperature less than about 180°C to obtain a cured urethane.

    Abstract translation: 本发明包括聚锡氧烷催化剂,含有催化剂的可固化组合物和使用该催化剂并固化该组合物的方法。 可固化组合物包含:(i)封端异氰酸酯; (ii)含有反应性氢的功能组分; (iii)用于促进封端异氰酸酯与官能组分反应的聚锡氧烷催化剂。 还可以使用基于Cu,Zn,Ni,Zr,Ce,Fe,Co,V,Sb和Bi,特别是所述金属的氧化物,盐或螯合物的助催化剂。 本发明还涉及一种在低反应温度下固化封端异氰酸酯的方法,该方法包括将催化剂与封端的异氰酸酯和官能组分组合并加热至低于约180℃的温度以获得固化的聚氨酯。

    High current density zinc organosulfonate electrogalvanizing process and composition
    246.
    发明公开
    High current density zinc organosulfonate electrogalvanizing process and composition 失效
    高电流密度有机磺酸锌电镀锌工艺和组成

    公开(公告)号:EP0786539A3

    公开(公告)日:1997-08-20

    申请号:EP97100964.2

    申请日:1997-01-22

    CPC classification number: C25D3/22 C25D3/565

    Abstract: The inventors disclose a process for reducing high current density edge buildup dendrite formation, edge burn, controlling high current density roughness, grain size, and orientation of a zinc coating obtained from an aqueous zinc acidic electrogalvanic coating bath comprising passing a high density current from a zinc anode in the bath to a metal cathode in the bath for a period of time sufficient to deposit a zinc coating on the cathode. The bath contains greater than about 5g/l of a water soluble zinc organosulfonate. A random or block polyoxyalkylene glycol homopolymer or copolymer based on 2 to about 4 carbon atom alkylene oxides. The inventors employ current densities from about 250 to about 4,000 ASF, and optionally, a sulfonated condensation product of naphthalene and formaldehyde, a boron oxide compound, and a lignin compound. The invention also comprises bath compositions.

    Abstract translation: 本发明人公开了一种减少高电流密度边缘堆积枝晶形成,边缘烧伤,控制从含水锌酸锌电镀液获得的锌涂层的高电流密度粗糙度,晶粒尺寸和取向的方法,包括使高密度电流从 在浴中的锌阳极与浴中的金属阴极接触足以在阴极上沉积锌涂层的一段时间。 该浴含有大于约5g / l的水溶性有机磺酸锌。 基于2至约4个碳原子烯化氧的无规或嵌段聚氧化烯二醇均聚物或共聚物。 发明人采用约250至约4,000ASF的电流密度,以及任选的萘和甲醛的磺化缩合产物,氧化硼化合物和木质素化合物。 本发明还包含浴组合物。

    IMPROVED HYDROFORMYLATION PROCESS WITH SEPARATION AND RECYCLE OF ACTIVE RHODIUM CATALYST
    247.
    发明公开
    IMPROVED HYDROFORMYLATION PROCESS WITH SEPARATION AND RECYCLE OF ACTIVE RHODIUM CATALYST 失效
    分离及活性铑回收催化剂改进羰基化过程

    公开(公告)号:EP0788471A1

    公开(公告)日:1997-08-13

    申请号:EP96926737.0

    申请日:1996-07-18

    CPC classification number: C07C45/50 Y02P20/584 C07C47/02

    Abstract: Active Rhodium catalyst and impurities are separated from a hydroformylation process stream containing both active and inactive organo-rhodium catalyst by binding active catalyst and impurities to an acidic ion exchange resin containing an acidic group. The purified hydroformylation stream can be returned to the hydroformylation reactor. All or a portion of inactive rhodium can be reactivated before recycling purified hydroformylation process stream to the reactor. During regeneration of the resin, a neutral solvent is used first to remove impurities which are discarded, then an acidic solvent is used to remove active organic rhodium catalyst from the resin. Such active catalyst can be rehydrided and returned to the hydroformylation reactor. An ion exchange resin having at least one acid group disposed on a silica backbone and an active organo-rhodium complex from a hydroformylation process stream bound to the resin can be produced.

    Liquid methyltin halide compositions
    249.
    发明公开
    Liquid methyltin halide compositions 失效
    FlüssigeMethylzinnzusammensetzungen

    公开(公告)号:EP0745605A2

    公开(公告)日:1996-12-04

    申请号:EP96108248.4

    申请日:1996-05-23

    CPC classification number: C07F7/2216 C23C16/407

    Abstract: Liquid methyltin halide compositions and their use as intermediates in chemical synthesis and as precursors for forming tin oxide coatings on substrates are disclosed.

    Abstract translation: 公开了液体甲基锡卤化物组合物及其作为化学合成中的中间体和用于在基材上形成氧化锡涂层的前体的用途。

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