公开(公告)号：WO1997003938A1

公开(公告)日：1997-02-06

申请号：PCT/US1996011868

申请日：1996-07-18

Applicant: ELF ATOCHEM NORTH AMERICA, INC.

Inventor： ELF ATOCHEM NORTH AMERICA, INC. ,  SILVERMAN, Gary, Stephen ,  MERCANDO, Paul

IPC: C07C45/00

CPC classification number: C07C45/50 ,  Y02P20/584 ,  C07C47/02

Abstract: Active Rhodium catalyst and impurities are separated from a hydroformylation process stream containing both active and inactive organo-rhodium catalyst by binding active catalyst and impurities to an acidic ion exchange resin containing an acidic group. The purified hydroformylation stream can be returned to the hydroformylation reactor. All or a portion of inactive rhodium can be reactivated before recycling purified hydroformylation process stream to the reactor. During regeneration of the resin, a neutral solvent is used first to remove impurities which are discarded, then an acidic solvent is used to remove active organic rhodium catalyst from the resin. Such active catalyst can be rehydrided and returned to the hydroformylation reactor. An ion exchange resin having at least one acid group disposed on a silica backbone and an active organo-rhodium complex from a hydroformylation process stream bound to the resin can be produced.

Abstract translation: 通过将活性催化剂和杂质结合到含有酸性基团的酸性离子交换树脂上，活性铑催化剂和杂质与含有活性和无活性有机铑催化剂的加氢甲酰化工艺流分离。 纯化的加氢甲酰化流可返回加氢甲酰化反应器。 在将纯化的加氢甲酰化工艺流再循环到反应器之前，全部或部分惰性铑可以再活化。 在树脂再生过程中，首先使用中性溶剂除去废弃的杂质，然后使用酸性溶剂从树脂中除去活性有机铑催化剂。 这种活性催化剂可以再水合并返回到加氢甲酰化反应器。 可以制备具有至少一个设置在二氧化硅骨架上的酸基的离子交换树脂和与该树脂结合的加氢甲酰化工艺流的活性有机 - 铑络合物。

公开(公告)号：EP0788471B1

公开(公告)日：2000-09-20

申请号：EP96926737.6

申请日：1996-07-18

Applicant: ELF ATOCHEM NORTH AMERICA, INC.

Inventor： SILVERMAN, Gary, Stephen ,  MERCANDO, Paul

IPC: C07C45/50 ,  B01J31/40

CPC classification number: C07C45/50 ,  Y02P20/584 ,  C07C47/02

Abstract: Active Rhodium catalyst and impurities are separated from a hydroformylation process stream containing both active and inactive organo-rhodium catalyst by binding active catalyst and impurities to an acidic ion exchange resin containing an acidic group. The purified hydroformylation stream can be returned to the hydroformylation reactor. All or a portion of inactive rhodium can be reactivated before recycling purified hydroformylation process stream to the reactor. During regeneration of the resin, a neutral solvent is used first to remove impurities which are discarded, then an acidic solvent is used to remove active organic rhodium catalyst from the resin. Such active catalyst can be rehydrided and returned to the hydroformylation reactor. An ion exchange resin having at least one acid group disposed on a silica backbone and an active organo-rhodium complex from a hydroformylation process stream bound to the resin can be produced.

公开(公告)号：EP0788471A1

公开(公告)日：1997-08-13

申请号：EP96926737.0

申请日：1996-07-18

Applicant: ELF ATOCHEM NORTH AMERICA, INC.

Inventor： SILVERMAN, Gary, Stephen ,  MERCANDO, Paul

IPC: C07C45 ,  C07C47

CPC classification number: C07C45/50 ,  Y02P20/584 ,  C07C47/02

Abstract: Active Rhodium catalyst and impurities are separated from a hydroformylation process stream containing both active and inactive organo-rhodium catalyst by binding active catalyst and impurities to an acidic ion exchange resin containing an acidic group. The purified hydroformylation stream can be returned to the hydroformylation reactor. All or a portion of inactive rhodium can be reactivated before recycling purified hydroformylation process stream to the reactor. During regeneration of the resin, a neutral solvent is used first to remove impurities which are discarded, then an acidic solvent is used to remove active organic rhodium catalyst from the resin. Such active catalyst can be rehydrided and returned to the hydroformylation reactor. An ion exchange resin having at least one acid group disposed on a silica backbone and an active organo-rhodium complex from a hydroformylation process stream bound to the resin can be produced.