METHOD OF MAKING A FLUOROPOLYMER
    241.
    发明申请
    METHOD OF MAKING A FLUOROPOLYMER 审中-公开
    制备荧光体的方法

    公开(公告)号:US20070072985A1

    公开(公告)日:2007-03-29

    申请号:US11535249

    申请日:2006-09-26

    CPC classification number: C08F214/18 B01J41/05 C08F6/16

    Abstract: The present invention provides a method of making a fluoropolymer comprising: (i) providing an aqueous dispersion of fluoropolymer particles by polymerizing one or more fluorinated olefins and optionally one or more fluorinated or non-fluorinated comonomers in an aqueous emulsion polymerization whereby the polymerization is initiated in the absence of a fluorinated surfactant and whereby no fluorinated surfactant is added during polymerization; (ii) recovering the fluoropolymer from the aqueous dispersion thereby obtaining said fluoropolymer and waste water; and (iii) contacting said waste water with an anion exchange resin; or alternatively to steps (ii) and (iii), contacting said aqueous dispersion with an anion exchange resin and subsequently separating said anion exchange resin from said aqueous dispersion.

    Abstract translation: 本发明提供一种制备含氟聚合物的方法,其包括:(i)通过在水乳液聚合中聚合一种或多种氟化烯烃和任选的一种或多种氟化或非氟化共聚单体来提供含氟聚合物颗粒的水性分散体,由此引发聚合 在不存在氟化表面活性剂的情况下,在聚合过程中不加入氟化表面活性剂; (ii)从水分散体中回收含氟聚合物,从而得到所述含氟聚合物和废水; 和(iii)使所述废水与阴离子交换树脂接触; 或者选择步骤(ii)和(iii),使所述水性分散体与阴离子交换树脂接触,随后将所述阴离子交换树脂与所述水性分散体分离。

    Sulfate-selective anion exchange resins for use in combination with TRSS resins in feed water treatment
    243.
    发明申请
    Sulfate-selective anion exchange resins for use in combination with TRSS resins in feed water treatment 有权
    用于与饲料水处理中的TRSS树脂组合的硫酸盐选择性阴离子交换树脂

    公开(公告)号:US20060054561A1

    公开(公告)日:2006-03-16

    申请号:US11225942

    申请日:2005-09-13

    Abstract: An improved system of resins comprising a combination of a sulfate-specific strongly basic anion exchange resin and a heterogenous hybrid thermally regenerable salt sorbent (TRSS) resin is provided. The anion exchange resin contains triethylamine and/or tributylamine groups. The TRSS resin comprises a macroporous host copolymer and a crosslinked guest copolymer having, respectively, weak acid groups and weak base groups. The system is used to treat feed water containing dissolved ions, including sulfate ions, and is efficiently regenerated.

    Abstract translation: 提供了一种包含硫酸盐特异性强碱性阴离子交换树脂和异种混合可再热盐吸收剂(TRSS)树脂的组合的改进的树脂体系。 阴离子交换树脂含有三乙胺和/或三丁胺基团。 TRSS树脂包括分别具有弱酸基和弱碱基的大孔宿主共聚物和交联客体共聚物。 该系统用于处理含有溶解离子(包括硫酸根离子)的进料水,并有效地再生。

    Water treatment/remediation system
    246.
    发明申请
    Water treatment/remediation system 有权
    水处理/补救系统

    公开(公告)号:US20050040111A1

    公开(公告)日:2005-02-24

    申请号:US10917255

    申请日:2004-08-12

    Applicant: Charles Dale

    Inventor: Charles Dale

    CPC classification number: C02F1/42 B01J41/05 B01J49/07 C02F2001/422

    Abstract: A treatment system passes feed water containing a contaminant such as perchlorate through a bed of strong base anion exchange resin that has been placed in a form (e.g., in sulfate form) to selectively capture the contaminant while passing other ions (e.g., nitrate) that may also be present in the water. The bed selectively removes the perchlorate with high efficiency, for example on a stoichiometric basis, until exhaustion. The bed operates robustly without spiking or displacement of more weakly-held or lower affinity ions as composition of the feed varies. The water may be further treated, if necessary, to produce a purified or potable product, in which case downstream processes may remove remaining contaminants and co-ions. Alternatively, the treated stream may be returned to or blended with the source to effect contaminant remediation, e.g., site clean-up. Contaminants such as uranium species, perchlorate or pertechnate may be treated by this method using ordinary (non-specialty) exchange resins. The bed may include a carousel, and the exhausted upstream portion of the resin may efficiently be disposed of by incineration, or may be rotated out for regeneration. Alternatively, the bed or the spent portion thereof may be periodically regenerated transferring perchlorate to a regeneration fluid waste. The concentrated waste may be disposed of by incineration, bioreaction or other suitable disposal process. The concentrated regen waste may also be passed through a smaller, sacrificial bed of ion exchange resin to capture its perchlorate, allowing re-use of the regen fluid and forming a lower-volume solid waste output. This second-bed re-transfer process operates efficiently at the high concentration present in spent regen fluid, and requires only a small fraction of the original bed volume.

    Abstract translation: 处理系统将含有诸如高氯酸盐的污染物的进料水通过已经以硫酸盐形式放置的形式(例如硫酸盐形式)的强碱性阴离子交换树脂床,以选择性地捕获污染物,同时通过其它离子(例如硝酸盐) 也可能存在于水中。 床以高效率,例如以化学计量的基础选择性地除去高氯酸盐,直到耗尽。 当床的组成不均匀时,床能够稳定地运行,而不会引起更多的弱固定或较低亲和力离子的尖峰或位移。 如果需要,水可以进一步处理,以产生纯化或可饮用的产品,在这种情况下,下游工艺可以除去剩余的污染物和共离子。 或者,经处理的物流可以返回或与源混合以实现污染物修复,例如现场净化。 铀类,高氯酸盐或高锝酸盐等污染物可以使用普通(非专业)交换树脂通过该方法进行处理。 床可以包括转盘,并且树脂的排出的上游部分可以有效地通过焚烧来处理,或者可以旋转出来用于再生。 或者,床或其废弃部分可以周期性地再生,将高氯酸盐转移到再生废液中。 浓缩的废物可以通过焚化,生物反应或其他合适的处理过程来处理。 浓缩的再生废物也可以通过较小的离子交换树脂的牺牲床捕获其高氯酸盐,允许重新使用再生流体并形成较小体积的固体废物输出。 这种第二床再转移过程在废再生流体中存在的高浓度下有效地操作,并且仅需要原始床体积的一小部分。

    Ion exchange purification of dielectric condensate precursor fluids and silicate esters such as tetraethylorthosilicate (TEOS)
    248.
    发明授权
    Ion exchange purification of dielectric condensate precursor fluids and silicate esters such as tetraethylorthosilicate (TEOS) 失效
    介电凝析物前体流体和硅酸酯的离子交换纯化,如原硅酸四乙酯(TEOS)

    公开(公告)号:US06660875B1

    公开(公告)日:2003-12-09

    申请号:US09327975

    申请日:1999-06-08

    CPC classification number: B01J47/026 B01J39/05 B01J41/05 B01J47/00

    Abstract: A method of removing inorganic contamination from dielectric condensate precursor fluids and silicate esters, such as tetraethylorthosilicate (TEOS), methyltriethoxyorthosilicate (MTEOS), hydrogen silsesquioxane (HSQ), methyl silsesquioxane (MSQ), polyarylene ether, benzocyclobutene (BCB), or OSG, includes obtaining a commercial grade fluid having up to 10,000 ppb individual metallic contaminants; converting the sodium form of one or more macroporous ion exchange resin beds to a hydrogen form; converting the chloride form of one or more macroporous ion exchange resin beds to a hydroxide form; drying the macroporous ion exchange resin beds to remove substantially all water from the ion exchange resin beds; passing fluids through the ion exchange resin beds one or more times by recirculating all or a portion of the fluid to obtain a purified fluid having less than 1 ppb of individual metallic contaminants, less than 10 ppb of boron contaminants, and less than 1 ppb of chloride contaminants; and collecting the purified fluid product within a container to prevent the subsequent addition of contaminants.

    Abstract translation: 例如原硅酸四乙酯(TEOS),甲基三乙氧基原硅酸盐(MTEOS),氢倍半硅氧烷(HSQ),甲基倍半硅氧烷(MSQ),聚芳醚,苯并环丁烯(BCB)或OSG等的电介质凝析物前体流体和硅酸酯的去除无机污染物的方法, 包括获得具有高达10,000ppb个别金属污染物的商业级流体; 将一种或多种大孔离子交换树脂床的钠形式转化为氢形式; 将一种或多种大孔离子交换树脂床的氯化物形式转化成氢氧化物形式; 干燥大孔离子交换树脂床,以从离子交换树脂床中基本上除去所有的水; 将流体通过循环全部或部分流体使流体通过离子交换树脂床一次或多次,以获得具有小于1ppb的单独的金属污染物,小于10ppb的硼污染物和小于1ppb的 氯化物污染物; 并在容器内收集纯化的流体产品以防止随后添加污染物。

    Methods for the on-line, on-demand preparation of sterile, water-for-injection grade water
    249.
    发明申请
    Methods for the on-line, on-demand preparation of sterile, water-for-injection grade water 失效
    在线,按需准备无菌水注射级水的方法

    公开(公告)号:US20030173297A1

    公开(公告)日:2003-09-18

    申请号:US10099129

    申请日:2002-03-14

    Inventor: Peter Grandics

    Abstract: A new method is described to produce large volumes of low cost sterile, Water-for-Injection (WFI) grade water on-line, on-demand from potable water in order to meet the needs of dialysis therapies and other biological applications for sterile, injectable grade water. The source water is processed by a combination of membrane and column chromatographic methods including reverse osmosis, chemical sterilization, reduction of iodine sterilant to iodide, deionization, endotoxin-specific adsorption and polishing filtration in order to reduce contaminant levels below those specified by the US Pharmacopoeia.

    Abstract translation: 描述了一种新方法,以便从饮用水按需要生产大量低成本无菌水注射(WFI)级水,以满足透析治疗和其他生物应用的需要,用于无菌, 注射级水。 源水通过膜和柱层析方法的组合进行处理,包括反渗透,化学灭菌,碘灭菌剂与碘化物的还原,去离子,内毒素特异性吸附和抛光过滤,以降低低于美国药典规定的污染物水平 。

    Purification of organic solvent fluids
    250.
    发明申请
    Purification of organic solvent fluids 失效
    有机溶剂流体的净化

    公开(公告)号:US20030024883A1

    公开(公告)日:2003-02-06

    申请号:US10231547

    申请日:2002-08-29

    CPC classification number: B01J47/00 B01J39/05 B01J41/05 B01J47/026 B01J47/14

    Abstract: A chemical distribution system having improved organic solvent fluid purity and consistency includes a vessel containing ion-exchange media positioned within a fluid flow pathway such that the organic solvent fluid passes through the ion-exchange media, thereby effecting removal of undesired impurities. Different embodiments of the invention position the vessel at varying locations within the fluid flow pathway. The chemical distribution system also preferably includes a return chemical flow pathway that recirculates purified organic solvent fluid through the ion-exchange media-containing vessel and thereby enables the system operator to conduct incremental adjustment of the solvent purity until a desired overall purity is attained.

    Abstract translation: 具有改进的有机溶剂流体纯度和稠度的化学分配系统包括容纳位于流体流动路径内的离子交换介质的容器,使得有机溶剂流体通过离子交换介质,从而除去不需要的杂质。 本发明的不同实施例将容器定位在流体流动通路内的不同位置处。 化学分配系统还优选地包括返回化学流动路径,其将纯化的有机溶剂流体再循环通过含离子交换介质的容器,从而使得系统操作者能够进行溶剂纯度的增量调节,直到达到期望的全部纯度。

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