ANTISTATIC NON-CROSSLINKED FOAMED POLYETHYLENE RESIN PARTICLES AND MOLDED NON-CROSSLINKED FOAMED POLYETHYLENE RESIN BODY

    公开(公告)号:EP2733164A1

    公开(公告)日:2014-05-21

    申请号:EP12814205.6

    申请日:2012-07-13

    Abstract: Provided are non-crosslinked foamed polyethylene resin particles that have a bulk density BD of 10 g/L or more and 100 g/L or less and are obtained by foaming polyethylene resin particles containing an antistatic agent in an amount of 0.1 part by weight or more and 3 parts by weight or less with respect to 100 parts by weight of a polyethylene resin and having a density of 0.920 g/cm 3 or more and less than 0.940 g/cm 3 , and the non-crosslinked foamed polyethylene resin particles have a shrinkage ratio of 3% or more and 30% or less determined in accordance with Formula (1). The non-crosslinked foamed polyethylene resin particles can simply afford an antistatic molded non-crosslinked foamed polyethylene resin body that has a small shrinkage ratio with respect to mold dimension, is deformed in a small degree, and has good surface stretch. Shrinkage ratio = (BD-VBD) x 100/VBD (1) In the formula, BD is a bulk density of the non-crosslinked foamed polyethylene resin particles at 23°C and 0.1 MPa (under standard atmospheric pressure), and VBD is a bulk density of the non-crosslinked foamed polyethylene resin particles at 23°C under a reduced pressure of 0.002 MPa or less.

    Abstract translation: 提供堆积密度BD为10g / L以上且100g / L以下的非交联发泡聚乙烯树脂粒子,其通过使含有0.1重量份抗静电剂的聚乙烯树脂粒子发泡得到,或者 相对于100重量份的聚乙烯树脂为3重量份以下,密度为0.920g / cm 3以上且小于0.940g / cm 3,非交联发泡聚乙烯树脂粒子具有 根据式(1)确定收缩率为3%以上且30%以下。 非交联发泡聚乙烯树脂颗粒可以简单地提供相对于模具尺寸具有小收缩率的抗静电成型非交联发泡聚乙烯树脂体,在很小程度上变形,并且具有良好的表面拉伸。 收缩率=(BD-VBD)×100 / VBD(1)式中,BD为23℃,0.1MPa(标准大气压)下非交联发泡聚乙烯树脂粒子的体积密度,VBD为 非交联发泡聚乙烯树脂颗粒的体积密度在23℃,0.002MPa或更低的减压下。

    PRE-EXPANDED POLYPROPYLENE RESIN PARTICLES, IN-MOLD FOAM MOLDED BODY OF POLYPROPYLENE RESIN, AND METHOD FOR MANUFACTURING SAME
    244.
    发明公开
    PRE-EXPANDED POLYPROPYLENE RESIN PARTICLES, IN-MOLD FOAM MOLDED BODY OF POLYPROPYLENE RESIN, AND METHOD FOR MANUFACTURING SAME 审中-公开
    PRE-拉伸聚丙烯树脂粒子,聚丙烯树脂成形FROM用于生产发泡模具与工艺

    公开(公告)号:EP2687559A1

    公开(公告)日:2014-01-22

    申请号:EP12758140.3

    申请日:2012-03-16

    Inventor: ITOI, Akihiro

    Abstract: Provided are pre-expanded polypropylene resin particles having a dimensional expansion coefficient of 1.5% or more determined with a thermomechanical analyzer at a constant compressive load of 1 mg during heating from 30°C to 100°C at a temperature increase rate of 10°C/min. Using the pre-expanded polypropylene resin particles can yield an in-mold foam molded product of polypropylene resin having few wrinkles and small dimensional shrinkage without pretreatment such as internal pressure application or compression packing during packing the pre-expanded particles in a mold for in-mold foam molding.

    Abstract translation: 提供了具有1.5%的尺寸膨胀系数预发泡聚丙烯类树脂颗粒或多个确定性以10℃的升温速度在加热过程中的1毫克的恒定压缩载荷使用热机械分析仪开采从30℃至100℃ /分钟。 使用预聚丙烯系树脂发泡粒子可以得到的模内发泡聚丙烯树脂的模制产品具有较少皱纹和小尺寸收缩无需预处理:例如在用于在 - 模具中的预发泡粒子时的内部压力的应用程序或压缩包装的包装 模内发泡成型。

    Method for manufacturing of foamed polystyrene boards
    245.
    发明公开
    Method for manufacturing of foamed polystyrene boards 有权
    Verfahren zur Herstellung von Polystyrolschaumplatten

    公开(公告)号:EP2679373A1

    公开(公告)日:2014-01-01

    申请号:EP12183966.6

    申请日:2012-09-12

    Abstract: A method for manufacturing of foamed polystyrene boards, whereby raw polystyrene grains are preliminarily expanded in an expander, and then seasoned, after which the seasoned grains are input to a mould, where under increased temperature and pressure, a block is formed, wherein the block is cut into boards of a desired shape and size, characterized in that the cut boards are sprayed with a bactericidal colloid consisting of 1% by weight of silver nanoparticles having a diameter of 50 nm in polymer shell, 93% to 97% of alcohol with average boiling point 65°C to 90°C, 0.1 % to 1% of surfacants, 0.2% to 2% of wetting agents, 0.5% to 1,5% of silanes, 0.2% to 1.5% of quelanting agents, 0.5% to 1.5% of substances with boiling point below 40°C and 0.1% to 0.5% of substances reducing viscosity of the whole colloid to a value below 1,0 cP, wherein the colloid is sprayed in the amount of 15 to 35 ml/m 2 , after which the board is dried until evaporation of the colloid solvent.

    Abstract translation: 一种发泡聚苯乙烯板的制造方法,其中在膨胀机中预先膨胀原料聚苯乙烯颗粒,然后进行调味,然后将调味颗粒输入到模具中,其中在升高的温度和压力下形成块体,其中块 被切成所需形状和尺寸的板,其特征在于,在聚合物壳体中,用1重量%的直径为50nm的银纳米颗粒和93%至97%的醇组成的杀菌胶体喷射切割板, 平均沸点65℃〜90℃,0.1〜1%表面活性剂,0.2〜2%润湿剂,0.5〜1.5%硅烷,0.2〜1.5%重量剂,0.5〜 1.5%的沸点低于40℃的物质和0.1%至0.5%的物质将整个胶体的粘度降低到低于10 cP的值,其中胶体喷涂量为15至35 ml / m 2 ,然后干燥板直到胶体溶剂蒸发。

    THERMOPLASTIC RESIN EXPANDED PARTICLES
    248.
    发明公开
    THERMOPLASTIC RESIN EXPANDED PARTICLES 审中-公开
    热塑性树脂膨胀颗粒

    公开(公告)号:EP3309196A1

    公开(公告)日:2018-04-18

    申请号:EP16807400.3

    申请日:2016-06-03

    Abstract: Thermoplastic resin foamed particles of the present invention including more than one functional additive selected from inorganic powder and inorganic fibers each includes a core layer formed of a thermoplastic resin and a coating layer in a foamed state formed of a thermoplastic resin, the mass ratio of the coating layer to the core layer is 99 : 1 to 50 : 50, the content (X) of the functional additive in the core layer is 5 to 90% by mass, and the content of the functional additive in the coating layer is smaller than the content (X) of the functional additive in the core layer. By this way, thermoplastic resin foamed particles from which a homogeneous foamed particle molding having excellent dimension stability, fusibility and appearance can be obtained while containing functional additive are provided.

    Abstract translation: 包含选自无机粉末和无机纤维​​中的多于一种功能添加剂的本发明的热塑性树脂发泡颗粒各自包括由热塑性树脂形成的芯层和由热塑性树脂形成的发泡状态的涂层, 所述芯层中的功能添加剂的含量(X)为99:1至50:50,所述芯层中的功能添加剂的含量(X)为5至90质量%,并且所述功能添加剂在所述涂层中的含量小于 芯层中功能添加剂的含量(X)。 通过这种方式,可以获得具有优异的尺寸稳定性,熔融性和外观的均质泡沫颗粒模制品,同时含有功能添加剂的热塑性树脂发泡颗粒。

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