Abstract:
An electrostatic dissipative, polypropylene-based resin expanded bead containing electrically conductive carbon black, having an apparent density of 10 to 120 kg/m 3 and formed of a base resin which includes a polypropylene resin forming a continuous phase, and a polyethylene resin forming dispersed phases dispersed in the continuous phase, with the carbon black being unevenly distributed to the dispersed phases side. The polyethylene resin is an ethylene homopolymer or a copolymer of ethylene and C 4 to C 6 α-olefinand a weight ratio of the polypropylene resin to the polyethylene resin is 99.5:0.5 to 65:35. A molded article obtained by in-mold molding of such expanded beads exhibits electrostatic dissipative properties with a surface resistivity in the range of 1×10 5 to 1×10 10 Ω in a stable manner.
Abstract:
In order to obtain a flame-retardant polyolefin resin expanding molded product which has excellent in-mold moldability and excellent surface appearance and satisfies the FMVSS flammability even if carbon black is added, polyolefin resin particles containing, with respect to 100 parts by weight of polyolefin resin, (i) 0.03 part by weight to 5 parts by weight of phosphorous flame retardant having a phosphorous content of 7% by weight or more, a melting point of 120°C or more, and a 5% by weight decomposition temperature within a range of 240°C to 320°C and (ii) 0.5 part by weight to 20 parts by weight of carbon black are expanded.
Abstract:
Provided are non-crosslinked foamed polyethylene resin particles that have a bulk density BD of 10 g/L or more and 100 g/L or less and are obtained by foaming polyethylene resin particles containing an antistatic agent in an amount of 0.1 part by weight or more and 3 parts by weight or less with respect to 100 parts by weight of a polyethylene resin and having a density of 0.920 g/cm 3 or more and less than 0.940 g/cm 3 , and the non-crosslinked foamed polyethylene resin particles have a shrinkage ratio of 3% or more and 30% or less determined in accordance with Formula (1). The non-crosslinked foamed polyethylene resin particles can simply afford an antistatic molded non-crosslinked foamed polyethylene resin body that has a small shrinkage ratio with respect to mold dimension, is deformed in a small degree, and has good surface stretch. Shrinkage ratio = (BD-VBD) x 100/VBD (1) In the formula, BD is a bulk density of the non-crosslinked foamed polyethylene resin particles at 23°C and 0.1 MPa (under standard atmospheric pressure), and VBD is a bulk density of the non-crosslinked foamed polyethylene resin particles at 23°C under a reduced pressure of 0.002 MPa or less.
Abstract translation:提供堆积密度BD为10g / L以上且100g / L以下的非交联发泡聚乙烯树脂粒子,其通过使含有0.1重量份抗静电剂的聚乙烯树脂粒子发泡得到,或者 相对于100重量份的聚乙烯树脂为3重量份以下,密度为0.920g / cm 3以上且小于0.940g / cm 3,非交联发泡聚乙烯树脂粒子具有 根据式(1)确定收缩率为3%以上且30%以下。 非交联发泡聚乙烯树脂颗粒可以简单地提供相对于模具尺寸具有小收缩率的抗静电成型非交联发泡聚乙烯树脂体,在很小程度上变形,并且具有良好的表面拉伸。 收缩率=(BD-VBD)×100 / VBD(1)式中,BD为23℃,0.1MPa(标准大气压)下非交联发泡聚乙烯树脂粒子的体积密度,VBD为 非交联发泡聚乙烯树脂颗粒的体积密度在23℃,0.002MPa或更低的减压下。
Abstract:
Provided are pre-expanded polypropylene resin particles having a dimensional expansion coefficient of 1.5% or more determined with a thermomechanical analyzer at a constant compressive load of 1 mg during heating from 30°C to 100°C at a temperature increase rate of 10°C/min. Using the pre-expanded polypropylene resin particles can yield an in-mold foam molded product of polypropylene resin having few wrinkles and small dimensional shrinkage without pretreatment such as internal pressure application or compression packing during packing the pre-expanded particles in a mold for in-mold foam molding.
Abstract:
A method for manufacturing of foamed polystyrene boards, whereby raw polystyrene grains are preliminarily expanded in an expander, and then seasoned, after which the seasoned grains are input to a mould, where under increased temperature and pressure, a block is formed, wherein the block is cut into boards of a desired shape and size, characterized in that the cut boards are sprayed with a bactericidal colloid consisting of 1% by weight of silver nanoparticles having a diameter of 50 nm in polymer shell, 93% to 97% of alcohol with average boiling point 65°C to 90°C, 0.1 % to 1% of surfacants, 0.2% to 2% of wetting agents, 0.5% to 1,5% of silanes, 0.2% to 1.5% of quelanting agents, 0.5% to 1.5% of substances with boiling point below 40°C and 0.1% to 0.5% of substances reducing viscosity of the whole colloid to a value below 1,0 cP, wherein the colloid is sprayed in the amount of 15 to 35 ml/m 2 , after which the board is dried until evaporation of the colloid solvent.
Abstract translation:一种发泡聚苯乙烯板的制造方法,其中在膨胀机中预先膨胀原料聚苯乙烯颗粒,然后进行调味,然后将调味颗粒输入到模具中,其中在升高的温度和压力下形成块体,其中块 被切成所需形状和尺寸的板,其特征在于,在聚合物壳体中,用1重量%的直径为50nm的银纳米颗粒和93%至97%的醇组成的杀菌胶体喷射切割板, 平均沸点65℃〜90℃,0.1〜1%表面活性剂,0.2〜2%润湿剂,0.5〜1.5%硅烷,0.2〜1.5%重量剂,0.5〜 1.5%的沸点低于40℃的物质和0.1%至0.5%的物质将整个胶体的粘度降低到低于10 cP的值,其中胶体喷涂量为15至35 ml / m 2 ,然后干燥板直到胶体溶剂蒸发。
Abstract:
The expanded particles of the present invention have two melting peaks on a DSC curve and are made from polyethylene resin particles which (i) contain an antistatic agent, (ii) have a storage modulus of elasticity of 900 Pa or more and 5000 Pa or less at an angular frequency of 1 rad/sec and (iii) have a storage modulus of elasticity of 100000 Pa or less at an angular frequency of 100 rad/sec, in dynamic viscoelastic behavior measurement at 190°C. From this, it is possible to provide expanded polyethylene resin particles which have a broad temperature range in molding process, and are excellent in appearance of a molded product and in physical properties (such as an antistatic property), without impairing productivity of resin particles which are a raw material of expanded particles.
Abstract:
A method for providing a molded article comprising foamed pellets molded together is disclosed. Examples of molded articles include a cushioning element for footwear, a padding for protective equipment, or a clothing element. The method comprises the steps of: - infusing pellets of a thermoplastic elastomer having a maximum size in at least one dimension of 10 mm with a supercritical fluid in a pressurized container; - removing the pellets from the supercritical fluid; and - de-pressurizing and heating the de-pressurized pellets; either (i) by immersing the pellets in a heated fluid; or (ii) by irradiating the pellets with infrared or microwave radiation. Either the supercritical fluid or the heated fluid comprises a dye, whereby foamed pellets being dyed are provided. The dye is a nonionic or anionic dye. Further, the method comprises the step of: - molding foamed pellets of at least two different colors together, to provide a cushioning element for footwear, a padding for protective equipment, or a clothing element.
Abstract:
Thermoplastic resin foamed particles of the present invention including more than one functional additive selected from inorganic powder and inorganic fibers each includes a core layer formed of a thermoplastic resin and a coating layer in a foamed state formed of a thermoplastic resin, the mass ratio of the coating layer to the core layer is 99 : 1 to 50 : 50, the content (X) of the functional additive in the core layer is 5 to 90% by mass, and the content of the functional additive in the coating layer is smaller than the content (X) of the functional additive in the core layer. By this way, thermoplastic resin foamed particles from which a homogeneous foamed particle molding having excellent dimension stability, fusibility and appearance can be obtained while containing functional additive are provided.
Abstract:
The invention relates to the use of a mineral having perovskite structure in vinyl aromatic polymer foam, i) for decreasing the thermal conductivity, ii) for increasing the mechanical properties (namely compressive strength and bending strength), or iii) for improving the self-extinguishing properties of the foam. The polymer foam further comprises one or more athermanous additives selected from a) powder inorganic additive selected from powders of silica and calcium phosphate, b) powder carbonaceous additive selected from powders of graphite, carbon black, petroleum coke, graphitized carbon black, graphite oxides, and graphene, and c) powder geopolymer and powder geopolymer composite.