公开(公告)号：WO1997027112A1

公开(公告)日：1997-07-31

申请号：PCT/US1997000879

申请日：1997-01-23

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： EASTMAN CHEMICAL COMPANY ,  SOMERS, Marc, Stacey

IPC: B65B63/08

CPC classification number: B65B63/08

Abstract: A process for packaging normally tacky amorphous polyolefins, and other materials having similar melt viscosities, is provided. The process entails flowing a heated material into a molded polyolefin container having a minimum wall thickness of about 0.1 mm to less than 0.24 mm at a temperature above the melting point of the container, followed by slowly cooling the filled container. The process is conducted at ambient conditions without the use of cooling fluids.

Abstract translation: 提供了用于包装通常粘性无定形聚烯烃的方法和具有相似熔体粘度的其它材料。 该方法需要在高于容器熔点的温度下将加热的材料流入具有约0.1mm至小于0.24mm的最小壁厚的模制聚烯烃容器中，随后缓慢冷却填充的容器。 该过程在环境条件下进行，而不使用冷却流体。

公开(公告)号：WO1997023569A1

公开(公告)日：1997-07-03

申请号：PCT/US1996020455

申请日：1996-12-13

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： EASTMAN CHEMICAL COMPANY ,  JONES, Allan, Scott ,  FLEISCHER, Jean, Carroll ,  WEAVER, Max, Allen

IPC: C08L67/02

CPC classification number: C08L67/02 ,  C08L77/12 ,  C08L67/06 ,  C08L69/00

Abstract: The present invention relates to blends of a polyester, polyamide or polyester/amide containing a copolymerizable fluorescence quenching compound and a second polymer. The blends of the present invention display reduced fluorescence. Specifically the blends comprise (a) a polyester/amide comprising: (1) a dicarboxylic acid component which comprises at least 0.1 mol % of a dicarboxylic acid selected from the group consisting of terephthalic acid and/or terephthalate ester; (2) a diol and/or diamine component; (3) 0.1 to 99.9 mol %, based on 100 mol % dicarboxylic acid and 100 mol % diol, of a copolymerizable fluorescence quenching compound; (b) a second polymer selected from the group poly(alkylene terephthalate) homo and copolyesters, poly(alkylene naphthalate) homo and copolyesters, poly(cycloalkylene terephthalate) homo and copolyesters, poly(alkylene 1,4-cyclohexanedicarboxylate) homo and copolyesters, and polycarbonate homo and copolymers.

Abstract translation: 本发明涉及含可共聚荧光淬灭化合物和第二聚合物的聚酯，聚酰胺或聚酯/酰胺的共混物。 本发明的共混物显示出降低的荧光。 具体地，共混物包含（a）聚酯/酰胺，其包含：（1）二羧酸组分，其包含至少0.1mol％的选自对苯二甲酸和/或对苯二甲酸酯的二羧酸; （2）二醇和/或二胺组分; （3）相对于100摩尔％二羧酸和100摩尔％二醇的可共聚荧光淬灭化合物为0.1〜99.9摩尔％ （b）选自聚（对苯二甲酸亚烷基酯）均聚和共聚酯，聚（萘二甲酸亚烷基酯）均聚和共聚酯，聚（对苯二甲酸亚烷基酯）共聚酯和共聚酯，聚（1,4-环己烷二羧酸亚烷基酯）均聚和共聚酯的第二聚合物， 和聚碳酸酯均聚物和共聚物。

公开(公告)号：WO1997023567A1

公开(公告)日：1997-07-03

申请号：PCT/US1996019693

申请日：1996-12-13

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： EASTMAN CHEMICAL COMPANY ,  HOFFMAN, Douglas, Claire

IPC: C08L67/02

CPC classification number: C08G63/80 ,  C08L67/02 ,  C08L2666/18

Abstract: The present application relates to a process comprising solid state polymerizing an immiscible polyester blend which has not been substantially melt esterified under conditions sufficient to produce a polyester blend which when remelted becomes clear. Polyester blends having good I.V., color and low acetaldehyde are also disclosed.

Abstract translation: 本申请涉及包含固态聚合不混溶的聚酯共混物的方法，其在足以产生聚酯共混物的条件下基本上不被熔融酯化，当重熔变得澄清时。 还公开了具有良好的I.V.，颜色和低乙醛的聚酯共混物。

公开(公告)号：WO1997023540A1

公开(公告)日：1997-07-03

申请号：PCT/US1996019692

申请日：1996-12-13

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： EASTMAN CHEMICAL COMPANY ,  JONES, Allan, Scott ,  FLEISCHER, Jean, Carroll ,  WEAVER, Max, Allen

IPC: C08G63/18

CPC classification number: C08G63/6886 ,  C08G63/18 ,  C08G63/189 ,  C08G63/6826 ,  C08L67/02 ,  C08L2666/18

Abstract: This invention relates to homopolyester compositions having fluorescence quenchers polymerized therein ("polyquenchers"). Specifically the "polyquencher" polymeric compositions comprise repeating units from (a) a dicarboxylic acid component and (b) a diol component, wherein at least one of (a) and (b) is comprised of at least one fluorescence polyquencher capable of reducing fluorescence of a polymer below the fluorescence displayed when said polyquencher is not included.

Abstract translation: 本发明涉及具有在其中聚合的荧光猝灭剂的均聚酯组合物（“聚合物”）。 具体地，“聚合物”聚合物组合物包含来自（a）二羧酸组分和（b）二醇组分的重复单元，其中（a）和（b）中的至少一个由至少一个能够降低荧光的荧光聚合物组成 的聚合物低于不包括所述聚合物时显示的荧光。

公开(公告)号：WO1997022042A1

公开(公告)日：1997-06-19

申请号：PCT/US1996020467

申请日：1996-12-13

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： EASTMAN CHEMICAL COMPANY ,  JESSEE, Ernest, Edward ,  MCLAUGHLIN, Michael, Ray ,  PINTO, Timothy, Martin ,  GRANT, James, Emmett, Jr.

IPC: G05B19/42

CPC classification number: G05B19/4207 ,  Y10T409/30084 ,  Y10T409/302968

Abstract: A numerically controlled milling machine is used to mill the surface of a coined spinnerette after punching and before broaching the holes in the spinnerette. A probe is mounted on the milling machine to obtain data points on the bumpy surface of the coined spinnerette. The low points in predetermined areas off of the protuberances on the bumpy surface of the coined spinnerette are detected. Splines connecting the low points in, e.g., concentric rings if the holes in the finished spinnerette will be in rings, are used to generate a representation of the finished surface. A spiral tool path is obtained using the representation of the finished surface and G-codes are generated to control the milling machine to move a tool along the tool path. After the coined spinnerette has been milled, conventional finishing, including broaching is performed.

Abstract translation: 数控铣床用于冲压冲压后的喷丝头表面，并在拉丝喷丝头之前的孔中。 探头安装在铣床上，以获得创造的喷丝板凹凸表面上的数据点。 检测到在喷墨喷丝板的凹凸表面上的突起中的预定区域的低点。 使用连接低点的花键，例如，如果完成的喷丝板中的孔将处于环中，则将其形成为例如同心环，以产生成品表面的表示。 使用最终表面的表示获得螺旋刀具路径，并生成G代码以控制铣床沿刀具路径移动刀具。 在精制喷丝头被研磨之后，进行包括拉削在内的常规精加工。

公开(公告)号：WO1997019974A1

公开(公告)日：1997-06-05

申请号：PCT/US1996018809

申请日：1996-11-21

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： EASTMAN CHEMICAL COMPANY ,  YAU, Cheuk, Chung ,  MOODY, Leslie, Shane

IPC: C08G63/82

CPC classification number: C08G63/82 ,  C08G63/68

Abstract: This invention relates to a polyester resin prepared by adding one or more dicarboxylic acid components to one or more glycol components containing 1,4-cyclohexanedimethanol equalling 100 mole %, the polyester resin having been prepared in the presence of a catalyst/stabilizer system consisting essentially of antimony compounds and phosphorous compounds and compounds selected from the group consisting essentially of zinc compounds, gallium compounds, and silicon compounds.

Abstract translation: 本发明涉及通过将一种或多种二羧酸组分加入到一种或多种含有等于100摩尔％的1,4-环己烷二甲醇的二醇组分中制备的聚酯树脂，所述聚酯树脂是在催化剂/稳定剂体系基本上组成的基础上制备的 的锑化合物和磷化合物以及选自基本上由锌化合物，镓化合物和硅化合物组成的组的化合物。

公开(公告)号：WO1997012927A1

公开(公告)日：1997-04-10

申请号：PCT/US1996015394

申请日：1996-09-26

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： EASTMAN CHEMICAL COMPANY ,  SUBLETT, Bobby, Jones

IPC: C08G63/199

CPC classification number: C08G63/189 ,  C08G63/199

Abstract: Disclosed are thermoplastic copolyesters having improved gas barrier properties and which can be produced having little or no acetaldehyde. These copolyesters are especially useful in the manufacture of food packaging products, foodtrays, film and beverage bottles which require good oxygen and carbon dioxide barrier properties. The copolyesters comprise repeat units from 10 to 100 mole percent repeat units from naphthalene dicarboxylic acid, 90 to 0 mole percent repeat units from terephthalic acid and repeat units from essentially 100 mole percent 1,4-cyclohexane-dimethanol, wherein said 1,4-cyclohexanedimethanol has a cis isomer content of at least 50 % said copolyester having an I.V. of 0.4-1.2.

Abstract translation: 公开了具有改进的气体阻隔性能的热塑性共聚酯，其可以生产具有很少或没有乙醛。 这些共聚酯特别可用于制造需要良好的氧气和二氧化碳阻隔性能的食品包装产品，食品托盘，薄膜和饮料瓶。 共聚酯包含来自萘二甲酸的10至100摩尔％的重复单元，来自对苯二甲酸的90至0摩尔％的重复单元和基本上100摩尔％的1,4-环己烷二甲醇的重复单元的重复单元， 环己烷二甲醇具有至少50％的顺式异构体含量，所述共聚酯具有IV 为0.4-1.2。

公开(公告)号：WO1997009366A1

公开(公告)日：1997-03-13

申请号：PCT/US1996013759

申请日：1996-08-27

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： EASTMAN CHEMICAL COMPANY ,  MINNICK, Larry, Allen

IPC: C08G63/189

CPC classification number: C08G63/181 ,  C08G63/189 ,  Y10T428/13 ,  Y10T428/1334 ,  Y10T428/1352 ,  Y10T428/24

Abstract: Disclosed are terpolymers having improved barrier properties and tensile strength relative to PET comprising copolyesters derived from acid components comprising 45 to 85 mol % terephthalic acid; 10 to 40 mol % of at least one naphthalenedicarboxylic acid and 5 to 15 mol % of at least one aliphatic dicarboxylic acid having 1 to 6 carbon atoms and glycol component comprising ethylene glycol. The copolyesters of the present invention may be formed into a variety of articles such as blood tubes, serum vials, containers, films and sheeting.

Abstract translation: 公开了具有相对于PET具有改进的阻隔性和拉伸强度的三元共聚物，其包含衍生自包含45至85mol％对苯二甲酸的酸组分的共聚酯; 10至40摩尔％的至少一种萘二甲酸和5至15摩尔％的至少一种具有1至6个碳原子的脂族二羧酸和包含乙二醇的二醇组分。 本发明的共聚酯可以形成各种制品，如血管，血小瓶，容器，薄膜和薄片。

公开(公告)号：WO1997005186A1

公开(公告)日：1997-02-13

申请号：PCT/US1996012504

申请日：1996-07-31

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： EASTMAN CHEMICAL COMPANY ,  NELSON, Gregory, Wayne ,  NICELY, Vincent, Alvin

IPC: C08G63/90

CPC classification number: C08G63/88 ,  B29K2105/0002 ,  C08G63/90

Abstract: Disclosed is a process for producing molded polyester articles having a low acetaldehyde content comprising the steps of: a) reacting a glycol and a dicarboxylic acid in the melt phase to form a polyester having an I.V. of 0.65-0.85; b) solidifying and pelletizing said polyester; c) remelting said polyester in an extruder; and d) forming said polyester into shaped articles, wherein the polyester is devolatilized during or following said polymerization in the melt, while it is being remelted, after remelting, or any combination by passing a purge gas over said molten polyester.

Abstract translation: 公开了一种生产具有低乙醛含量的模制聚酯制品的方法，包括以下步骤：a）在熔融相中使二醇和二羧酸反应形成具有I.V.的聚酯。 为0.65-0.85; b）固化和造粒所述聚酯; c）在挤出机中重熔所述聚酯; 和d）将成形的所述聚酯制成成型制品，其中聚酯在熔融物中聚合过程中或之后脱挥发份，同时通过将清洗气体通过所述熔融聚酯进行重熔，再熔化或任何组合。

公开(公告)号：WO1997003949A1

公开(公告)日：1997-02-06

申请号：PCT/US1996011900

申请日：1996-07-17

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： EASTMAN CHEMICAL COMPANY ,  LIANG, Shaowo

IPC: C07C253/00

CPC classification number: C07C253/00 ,  C07C2601/02 ,  C07C255/46

Abstract: Disclosed is a novel process for the preparation and separation of cyclopropanecarbonitrile (CPCN) from cyclopropanecarboxaldehyde (CPCA) using a combination of three process steps. The process involves the steps of (1) reacting (CPCA) with hydroxylamine base in the presence of water to obtain CPCA oxime, (2) contacting the CPCA oxime of step (1) with formic acid to obtain CPCN, and (3) contacting the mixture comprising CPCN formed in step (2) with a base to obtain a mixture comprising an organic phase containing CPCN and an aqueous phase. The reactants and intermediates involved in each step are used within certain defined ratios.

Abstract translation: 公开了一种使用三个工艺步骤的组合从环丙烷甲醛（CPCA）制备和分离环丙烷腈（CPCN）的新方法。 该方法包括以下步骤：（1）在水存在下使（C）与羟胺碱反应得到CPCA肟，（2）使步骤（1）的CPCA肟与甲酸接触，得到CPCN，和（3）接触 所述混合物包含步骤（2）中形成的CPCN与碱，以获得包含含有CPCN和水相的有机相的混合物。 每个步骤中涉及的反应物和中间体在某些确定的比例内使用。